Maumee Research & Engineering, Incorporated

Tek-kol Partnership

National Institute of Clean and Low-carbon Energy (nice)

Gas Research Institute

National Institute of Clean-and-low-carbon Energy

Shenhua Group Corporation Limited

C2o Technologies, LLC

Deane Avent Horne

Franklin G Rinker

Dennis W Coolidge

James Alan Thornton

Ronn G Smith

Valdis R Daiga

Ernest P Esztergar

Leslie C White

Thomas J Schultz

Daniel A Molnar

Timothy J Kuhn

James W Bender

Robert W Mueller

Thomas J Sack

James Darrell Kinder

Stephen J Sikirica

A continuous process and apparatus for treating dried coal and coal char to promote passivation of the reactive carbon particles by forming a protective oxide coating and simultaneously adding moisture to rehydrate said particles. The passivation process is conducted in a novel apparatus providing for the staged control of the reaction temperature and the staged introduction of both oxygen and moisture. The fluidized bed apparatus has internal in-bed cooling means embedded within the fluidized coal or coal char particles so as to remove the heat energy as it is released by virtue of the exothermic passivation reactions.

Coal char passivation process and apparatus

A method for upgrading coal and other carbonaceous fuels includes subjecting the carbonaceous fuel to a pyrolyzing process, thereby forming upgraded carbonaceous fuel and a flow of lean fuel gases. Auxiliary fuel is combusted in an auxiliary fuel combustor to produce auxiliary fuel combustion gases, and the lean fuel gases are heated with the auxiliary fuel combustion gases. The heated lean fuel gases are combusted in a lean fuel combustor, thereby producing a gas stream of products of combustion, and at least a portion of the gas stream of products of combustion are directed to the pyrolyzer.

Upgrading coal and other carbonaceous fuels using a lean fuel gas stream from a pyrolysis step

A method and apparatus for upgrading coal and other carbonaceous fuels includes subjecting the carbonaceous fuel to a pyrolyzing process, thereby forming upgraded carbonaceous fuel and a flow of lean fuel gases. Auxiliary fuel is combusted in an auxiliary fuel combustor to produce auxiliary fuel combustion gases, and the lean fuel gases are heated with the auxiliary fuel combustion gases. The heated lean fuel gases are combusted in a lean fuel combustor, thereby producing a gas stream of products of combustion, and at least a portion of the gas stream of products of combustion are directed to the pyrolyzer.

A method of treating untreated low calorific coal containing moisture and organic volatiles includes feeding untreated coal to a dryer, and drying the coal. The dried coal is subjected to a pyrolyzing step where oxygen-deficient gases are brought into contact with the coal, thereby lowering the volatile content of the coal and producing a stream of pyrolysis effluent gases. The pyrolysis effluent gases are subjected to a separation process to separate lean fuel gases from liquids and tars, wherein the separation process removes less than about 20 percent of the pyrolysis effluent gases as the liquids and tars, with the remainder being the lean fuel gases. The lean fuel gases are returned to the dryer combustor, the pyrolyzer combustor, or the pyrolyzer.

Coal processing to upgrade low rank coal having low oil content

A method of processing flue dust that contains one or more compounds from a first group of zinc, lead and cadmium compounds, and contains iron compounds, involves heating the flue dust to cause a substantial portion of one or more of the compounds of the first group to become gas-borne. A carbonaceous material is introduced to the remaining flue dust, and the flue dust/carbonaceous material mixture is heated to cause a substantial portion of the remaining compounds from the first group to become gas-borne while retaining a substantial portion of the iron in a non-gas-borne condition. The gas-borne compounds are separated from the non-gas-borne compounds.

Furnace flue dust processing method

A method of processing flue dust, where the flue dust contains one or more compounds from a first group of zinc, lead and cadmium compounds, and contains one or more compounds from a second group of iron, silicon, calcium, magnesium and aluminum compounds, includes mixing the flue dust with a carbonaceous material, heating the flue dust/carbonaceous material mixture under non-turbulent conditions to cause a substantial portion of the compounds from the first group to become gas-borne while retaining a substantial portion of the compounds of the second group in a non-gas-borne condition, and separating the gas-borne compounds from the non-gas-borne compounds.

A rotary hearth furnace for reducing a feed material is disclosed. The rotary hearth furnace includes a rotating hearth disposed in an enclosure and mounted for rotary movement. The enclosure includes an annular inner wall, an annular outer wall and a roof. The enclosure is sealed to the hearth and divided into a plurality of zones including at least a loading zone, a process zone and a discharge zone. The furnace further includes a plurality of burners positioned in at least the outer wall of the enclosure to provide a controlled temperature within the rotary hearth furnace and a flue positioned within the reduction zone of the furnace between the preheat zone and the discharge zone to exhaust combustion gases from the burners and gases resulting from the processing of the feed material. Said flue contains space for combustion and settling of the unburned particulates. A water spray quench reduces the temperature of the furnace off-gas so that subsequent combustion by the introduction of air or oxygen does not produce significant nitrogen oxides.

Method and apparatus for reducing a feed material in a rotary hearth furnace

A process for recovering iron from iron-bearing materials including steel mill waste and iron-bearing ores. The process includes the steps of providing a mixture of iron-bearing materials having iron oxides therein and carbonaceous material. Blending with the mixture an organic binder. The mixture is then agglomerated to form green compacts. The green compacts are then loaded into a preheated rotary hearth furnace void of compacts to form a layer of compacts no more than about two compacts high. The green compacts are heated for about 5-12 minutes at a temperature of between about 2200-2500&deg; F. to reduce the compacts and evolve undesirable oxides from the compacts. The reduced compacts are then discharged from the rotary hearth furnace whereupon they are soaked to provide additional time for reaction to achieve 99% or more reduction of the iron oxides. The metallized iron compacts may then be cooled or transported hot to a steel making operation.

Process for treating metal oxide fines

A discharge assembly for removing material from a hearth in a rotary hearth furnace including a discharge auger and a coolant spray. The discharge auger is positioned above the hearth of the rotary hearth furnace and includes a central shaft having at least one helical flight affixed to the exterior of the central shaft and the hood is disposed above the discharge auger. The coolant spray cools the discharge auger.

Spray cooled furnace discharge assembly

A process for treating iron-bearing material with a carbonaceous material to form a mixture, wherein the amount of carbonaceous material added exceeds the stoichiometric amount required to reduce the metal oxide to elemental metal. In one embodiment, the process also includes blending an organic binder with the mixture. The mixture is agglomerated using compaction to bond the mixture and form green compacts. The green compacts are loaded into a heated furnace and heated for about 5-12 minutes at a temperature of between about 2100.degree.-2500.degree. F. and at a CO/CO.sub.2 ratio of about 1.5-2.5 proximate the discharge area to reduce the iron oxide containing compacts to compacts containing elemental iron and an excess amount of carbonaceous material wherein the excess amount of carbonaceous material counteracts re-oxidation of the elemental iron. The reduced compacts are then discharged from the furnace. The furnace includes counterflow and co-flow exhaust to maintain the charge area and the discharge area of the furnace at a pressure about equal to atmospheric pressure.

Process for treating iron bearing material

A process for recovering iron from iron-bearing materials including steel mill waste and iron-bearing ores. The process includes the steps of providing a mixture of iron-bearing materials having iron oxides therein and carbonaceous material. The mixture is agglomerated to form green compacts. The green compacts are then loaded into a preheated rotary hearth furnace void of compacts to form a layer of compacts no more than about two compacts high. The green compacts are heated for about 5 to 12 minutes at a temperature of between about 2200.degree. F. to 2500.degree. F. to reduce the compacts and evolve undesirable oxides from the compacts. The reduced compacts are then discharged from the rotary hearth furnace whereupon they are soaked to provide additional time for reaction to achieve 99% or more reduction of the iron oxides. The metallized iron compacts may then be cooled or transported hot to a steel making operation.

A process for treating iron-bearing material with a carbonaceous material to form a dry mixture, wherein the amount of carbonaceous material added exceeds the stoichiometric amount required to reduce the metal oxide to elemental metal. In one embodiment, the process also includes blending an organic binder with the dry mixture. The dry mixture is agglomerated to bond the dry mixture and form green compacts. The green compacts are loaded into a heated furnace and heated for about 5-12 minutes at a temperature of between about 2100.degree.-2500.degree. F. to reduce the iron oxide containing compacts to compacts containing elemental iron and an excess amount of carbonaceous material wherein the excess amount of carbonaceous material counteracts re-oxidation of the elemental iron. The reduced compacts are then discharged from the furnace.

A continuous process for treating coal to form stable coal char by passivating the coal and then rehydrating and cooling the product thereof to prevent spontaneous ignition. The process includes the steps of pyrolyzing the coal to vaporize and remove low end volatile materials and to mobilize high end volatile materials and cooling to demobilize the high end volatile materials within the at least partially collapsed micropores of the coal char to pyrolytically passivate the coal char and form a char having about 14-22 wt % high end volatiles. The pyrolytically passivated coal char is then conveyed to a reaction vessel wherein a process gas having about 3%-21% by volume oxygen flows through the reaction vessel to at least partially fluidize the coal char and oxidatively passivate the coal by chemisorption of oxygen. The passivated coal char is then substantially simultaneously rehydrated and cooled to form a stable coal char having about 5-10 wt % moisture.

Process for passivation of reactive coal char

A process for recovering iron from iron-bearing materials including steel mill waste and iron-bearing ores. The process includes the steps of combining the iron-bearing materials, having metal oxides including iron oxides therein, with carbonaceous material to form a dry mixture. The dry mixture is agglomerated under conditions sufficient to mobilize volatile matter from the carbonaceous material to function as a binder and bond the dry mixture and form green compacts. The green compacts are then loaded into a preheated rotary hearth furnace void of compacts to form a layer of compacts no more than about two compacts high. The green compacts are heated for about 5 to 12 minutes at a temperature of between about 2150.degree. F. to 2350.degree. F. to reduce the compacts and evolve undesirable oxides from the compacts. The reduced compacts are then discharged from the rotary hearth furnace whereupon they are soaked to provide additional time for reaction to achieve 99% or more reduction of the iron oxides. The metallized iron compacts may then be cooled or transported hot to a steel making operation.

A continuous process for treating a noncaking coal to form stable char. The process includes the sequential steps of drying the coal to remove moisture therefrom and form a dry coal; pyrolyzing the dry coal by progressively heating substantially all of the coal to a temperature sufficient to vaporize and remove low end volatile materials from the coal to form char and sufficient to mobilize at least a portion of high end volatile materials within the char and at least partially collapse micropores within the char. The char is then cooled to a temperature sufficient to demobilize the volatile materials within the at least partially collapsed micropores of the char to pyrolytically passivate the char. The char is then conveyed to a reaction vessel wherein a process gas having about 3%-21% by volume oxygen flows through the reaction vessel to oxidatively passivate the coal by chemisorption of oxygen. The oxidatively passivated char is then substantially simultaneously rehydrated and cooled to form a char having about 5-10 wt % moisture and then conveyed to a final passivation vessel wherein a process gas having about 3%-21% by volume oxygen flows through the vessel to finally passivate the rehydrated char by chemisorption of oxygen.

Growing community of inventors

Toledo, OH, United States of America

Deane Avent Horne