Monsanto Company

Dean L Kavanagh

Robert H Simon

Robert C Clark

James R Moran

George E Cartier

A process for forming a shaped laminate for use in a safety glazing such as a vehicle window or the like which comprises lightly bonding at least one flexible, transparent, thermoplastic carrier layer having one or more adherent functional performance layers or coatings on its surface to at least one layer of ptasticized polyvinyl butyral to form a premolding composite, stretching the composite to impart compound curvature thereto and form a shaped, shrinkable laminate, subjecting the shaped laminate to elevated temperature while constraining its edges to relieve stresses in the carrier layer, and cooling the shaped laminate while maintaining its edges constrained.

Process forming a shaped laminate

Dimensionally stable, cured phenolic foams are described that have a thermal conductivity after 10-days below 0.0185 watts/m .degree.C., a density of 30 to 70 kg/cubic meter and a closed-cell content of at least 85%.

Cured phenolic foams

A method of dimensionally stabilizing a transparent, shrinkable thermoplastic layer, such as polyethylene terephthalate, in a draw-formed laminate with plasticized polyvinyl butyral which comprises heat setting the thermoplastic layer.

Dimensional stabilizing process

A flexible, draw-formed laminate for a safety glazing comprising a transparent, thermoplastic carrier film which is shrink-stable during laminating formation of such safety glazing bonded to at least one layer of plasticized polyvinyl butyral, such film having a greater tensile modulus than that of the layer of plasticized polyvinyl butyral. The carrier film is preferably flexible polyester such as polyethylene terephthalate having one or more functional performance coatings or layers on its surface such as a multi-layered solar radiation control stack.

Laminate for a safety glazing

A polymeric laminate for use with a glass layer in a laminated bilayer or anti-lacerative shield application comprises a first layer of moisture tolerant plasticized polyvinyl butyral containing (a) adhesion control agent(s) and (b) residual hydroxyl content which optimize glass adhesion and optical performance over a range of moisture contents in the first layer likely to be encountered in use, i.e. 0.2 to 0.5 weight % and 2 to 2.8 weight %, such first layer being in face to face contact with a second layer of a clear polymer film or coating having a combination of performance properties desirable for these applications. Preferred second layers are biaxially stretched polyester and thermoset aliphatic polyurethane.

Laminated safety glass and polymeric laminate for use therein

Phenolic foams having a cell structure that is resistant to rupture under pressure and a slow deterioration of thermal insulation value are claimed. These foams can be cured to achieve dimensional stability without substantial adverse affect on their structure.

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Longmeadow, MA, United States of America

Dean L Kavanagh