Nankai University

Other

Daxin Zhang

Jun Chen

Youxiao Chen

Huatang Yuan

Yunshi Zhang

Zuoxiang Zhou

Deying Song

Genshi Wang

Taoshi Zang

Xuejun Cao

Xeujun Cao

This invention relates to a hydrogen storage alloy electrode prepared from an active material comprising a magnesium based alloy and a Ni, P based metallic compound. The magnesium based alloy is coated while in powder form with a Ni, P based metallic compound and activated by heat. The hydrogen storage alloy electrode produced from this active material is able to absorb and desorb hydrogen even under normal temperature and pressure. The alkali battery assembled with the electrode prepared from the activated alloy material has high energy density and charge-discharge capacity and can be used in large scale electrical equipment, especially electrically operated vehicles.

Magnesium based hydrogen storage alloy electrode

This invention relates to an electrode composed of an active material. This electrode comprises a composition of a hydrogen storage alloy powder possessed of relatively high electrochemical capacity with a formula of MmNi5-x-y-z AxByCz and a hydrogen storage alloy powder possessed of catalytic activity with a formula of D2-uE1-vFuGv wherein Mm is the mischmetal, A=Co, Cr, V; B=Mn, Sn, Be; C=Al, Ca, Mg, Zr, Nb; D=Mg, Al; E=Cu, Zn; F=Ca, Be; G=Sn, Bi; 0.ltoreq.x.ltoreq.0.5, O.ltoreq.y.ltoreq.l.5, 0.ltoreq.z.ltoreq.0.5, 0.ltoreq.u.ltoreq.1, 0.ltoreq.v.ltoreq.0.5. The internal pressure of the alkali battery assembled with this electrode can be effectively lowered, the capacity and the cycle life of the sealed battery are improved, the activation period of the battery is shortened to 3-5 times, thus the crucial technical problem about industrial mass production of this kind of alkali batteries is surmounted.

Hydrogen storage alloy electrode

This invention relates to an active material of hydrogen storage alloy electrode. The composition of the active material has a formula: Mm Ni.sub.5-x-y-z-u A.sub.x B.sub.y C.sub.z D.sub.u ; wherein Mm is mischmetal; A=Mn, Sn, or V; B=Cr, Co, Ti, Nb, Zr, or Si; C=Al, Mg, or Ca; D=Li, Na, or K; 0.ltoreq..times..ltoreq.0.95; 0.ltoreq. y.ltoreq. 1; 0.ltoreq. z.ltoreq. 0.7; and 0.1.ltoreq. u.ltoreq. 0.9. Alternatively, the composition may be of the formula: Ti.sub.2 Ni.sub.1-u Du; wherein D=Li, Na, or K; and 0.04.ltoreq. u.ltoreq. 0.9. This active material can relieve the alkali metal ions M.sup.+ continuously in charge-discharge process of the alkali batteries, increase the concentration of MOH within the battery, take effect in protecting the cathode and the anode validly, and improve the cycle life and the discharge capacity of the battery.

Active material of hydrogen storage alloy electrode

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TianJin, China

Daxin Zhang