Arkema Inc.

Arkema France

David Shin-Ren Liu

Mark A Aubart

Gregory Scott O'Brien

David A Seiler

James J Henry

Jack J Reilly

William C Wolf

Thomas F Roland

Mark Anthony Aubart

Sara Reynaud

Azaz A Vahora

Mahendra Christopher Orilall

Marie Elizabeth Sullivan Malervy

Gregory S O'brien

Camille Khadraoui

Mary Elizabeth Sullivan Malervy

An acrylic alloy composition that can be 3-D printed by a material extrusion additive manufacturing process, an acrylic filament that has a very uniform diameter useful in the extrusion additive manufacturing process, acrylic articles made from the acrylic alloy composition by a material extrusion additive process, and a material extrusion additive manufacturing process for producing the acrylic articles. The acrylic alloy composition is an alloy of an acrylic polymer, and a low melt viscosity polymer, such as polylactic acid. The alloy may optionally be impact modified, preferably with hard core core-shell impact modifiers.

Dimensionally stable acrylic alloy for 3-d printing

The invention relates to 3D printed parts made with thermoplastic polymers having a low stiffening temperature. 3D printed parts of the invention have very good Z layer adhesion, have a high elongation at break in the Z direction, preferably of more than 50 percent, and have at least an 80 percent ratio of Z to XY stress at yield or at break. The resulting part may be nearly isotropic—having similar mechanical properties in the XY and Z print directions. The excellent layer adhesion makes the resultant printed part more robust—able to withstand many cycles of use. Certain polymers of the invention produce printed parts that have a very low haze, and are nearly transparent.

3-D printed semi-crystalline and amorphous polymer articles

The invention relates to thermoplastic filament for use in 3-D printers, in which the core of the filament is non-solid or mono-filament. The filament may contain a multitude of small micro-voids, (a micro foam), be a foam-core structure, be hollow, or have a monofilament core. The filament of the invention is especially useful with crystalline and semi-crystalline polymers, and reduces the negative effect of filament voids, formed by shrinkage during the cooling of the filament.

Non-solid core filament for 3-D printing

The invention relates to the use of a compatible thermoplastic material (film, sheet, or raft) as the base sheet or layer for 3-D printing an article. The use of the base film provides a means of printing a large article, and of reducing warpage by printing directly on the film. The printed article adheres to the film better than to traditional printer surfaces (glass, metal, glue, or reusable films), because the printed article and film weld together by forming chain entanglements, due to being compatible, miscible, or semi-miscible in the melt.

Material extrusion 3-D printing on compatible thermoplastic film

The invention relates to an acrylic alloy composition that can be 3-D printed by a material extrusion additive manufacturing process, to an acrylic filament that has a very uniform diameter useful in the extrusion additive manufacturing process, to acrylic articles made from the acrylic alloy composition by a material extrusion additive process, and to a material extrusion additive manufacturing process for producing the acrylic articles. The acrylic alloy composition is an alloy of an acrylic polymer, and a low melt viscosity polymer, such as polylactic acid. The alloy may optionally be impact modified, preferably with hard core core-shell impact modifiers.

Dimensionally stable acrylic alloy for 3-D printing

The invention relates to fluoropolymer filament for use in 3-D printing, and 3-D printed fluoropolymer articles having low warpage, excellent chemical resistance, excellent water resistance, flame resistance, and good mechanical integrity. Additionally, the articles of the invention have good shelf life without the need for special packaging. In particular, the invention relates to filament, 3-D printed polyvinylidene fluoride (PVDF) articles, and in particular material extrusion 3-D printing. The articles may be formed from PVDF homopolymers, copolymers, such as KYNAR&#xae; resins from Arkema, as well as polymer blends with appropriately defined low shear melt viscosity. The PVDF may optionally be a filled PVDF formulation. The physical properties of the 3-D printed articles can be maximized and warpage minimized by optimizing processing parameters.

3-D printed fluoropolymer structures

Embodiments described herein are directed to polymerization-induced phase-separating (PIPS) compositions for enhancement of impact resistance and rheological properties in photocurable resins for 3D printing, such as for inks, coatings and adhesives. Embodiments described herein are advantageous with respect to properties such as impact resistance, shear adhesion and cohesive strength. The PIPS compositions may include components X, Y and Z, wherein X includes an acrylic based monomer; Y includes a copolymer of block A and block B; and Z includes a multifunctional cross-linker. Methods of using the PIPS compositions are also described. Also described are methods of screening potential acrylic based monomeric or oligomeric additives that yield improved impact resistance.

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Bala Cynwyd, PA, United States of America

David Shin-Ren Liu