Conocophillips Company

University of Kansas

Phillips Petroleum Company

The University of Bergen

David R Zornes

Ahmad Moradi-Araghi

Riley Bryan Needham

James H Hedges

Faye Lynn Scully

Cory Berkland

Jenn-Tai Liang

Min Cheng

Huili Guan

James P Johnson

Terry M Christian

Ying-Ying Lin

Dennis C Wegener

Michael L Fraim

Everett L Johnston

Daniel R Maloney

James C Stevens

Bernard A Baldwin

Donald D Bruning

Kelly B Fox

Michael E Vienot

Partha S Sarathi

James J Howard

Bjorn Kvamme

Arne Graue

Dave E Reese

Ahmad Moradiaraghi

Michael J Geier

The invention is directed to delayed gelation agents comprising a degradable polymeric cage containing therein one or more gelation agents. The cage degrades in situ, e.g, in an oil reservoir, thus releasing the gelation agent(s), which can then crosslink second polymers in situ to form a gel.

Delayed gelling agents

The disclosure is directed to polyelectrolyte complex nanoparticles that can be used to deliver agents deep into hydrocarbon reservoirs. Methods of making and using said polyelectrolyte complex nanoparticles are also provided.

The invention is directed to delayed gelation agents comprising a degradable polymeric cage containing therein one or more gelation agents. The cage degrades in situ, e.g., in an oil reservoir, thus releasing the gelation agent(s), which can then crosslink second polymers in situ to form a gel.

The invention is directed to stable crosslinked water-soluble swellable polymers and methods for making same. More particularly, the invention relates to a composition comprising expandable polymeric particles having anionic sites and labile crosslinkers and stable crosslinkers, said particle mixed with a fluid and a cationic crosslinker that is capable of further crosslinking the particle on degradation of the labile crosslinker and exposure of the anionic sites so as to form a gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into target zone and when the heat and/or suitable pH of the target zone cause degradation of the labile crosslinker and the particle expands, the cationic crosslinker crosslinks the polymer to form a gel, thus diverting water to lower permeability regions and improving oil recovery.

Swellable polymer with anionic sites

The invention is directed to stable crosslinked water-soluble swellable polymers, methods for making same, and their various uses in the hygiene and medical arts, gel electrophoresis, packaging, agriculture, the cable industry, information technology, in the food industry, papermaking, use as flocculation aids, and the like. More particularly, the invention relates to a composition comprising expandable polymeric microparticles having labile crosslinkers and stable crosslinkers, said microparticle mixed with a fluid and an unreacted tertiary crosslinker that is capable of further crosslinking the microparticle on degradation of the labile crosslinker so as to form a stable gel. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a well and when the heat and/or pH of the well cause degradation of the labile crosslinker and when the particle expands, the tertiary crosslinker crosslinks the polymer to form a stable gel, thus diverting water to lower permeability regions and improving oil recovery.

Crosslinked swellable polymer

The invention is directed to long lasting crosslinked water-soluble swellable polymers, methods for making same, and their uses. More particularly, the invention relates to a composition comprising expandable polymeric particles having cationic sites as well as labile crosslinkers and stable crosslinkers, said particle mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a target zones in the reservoirs and when the heat and/or a suitable pH in the reservoir cause degradation of the labile crosslinker and when the particle expands, the cationic sites in the polymer adsorb to negative sites of the rock in the formation, thus diverting water to lower permeability regions and improving oil recovery. However, many other uses are possible.

Swellable polymer with cationic sites

The invention is directed to crosslinked water-soluble swellable polymers, methods for making same and their various uses. More particularly, the invention relates to a composition comprising expandable polymeric particles being made with 0.1-5% hydrophobic monomers and labile crosslinkers and stable crosslinkers, said particles mixed with a fluid. A particularly important use is as an injection fluid in petroleum production, where the expandable polymeric particles are injected into a well and when the heat and/or pH of the target zones in the formation cause degradation of the labile crosslinker and when the particle expands, the hydrophobic groups associate to form a hydrophobically associative polymer, thus diverting water to lower permeability regions and improving oil recovery.

Swellable polymers with hydrophobic groups

A non-rigid carrier conveys a pump and/or the steam generator through a bore of the production tubing string to support enhanced oil recovery operations. An annular space separates the production tubing string and a wall of a wellbore intersecting a hydrocarbon-bearing subterranean formation. Using the non-rigid carrier, the steam generator is conveyed into the wellbore and operated to inject hot gases into the formation through the perforations in the casing. Afterwards, the steam generator is conveyed out of the cased wellbore and the pump is conveyed into the cased wellbore and operated to pump hydrocarbons to the surface. For cyclic injection operations, the pump may be retrieved to the surface and the steam generator may be returned into the well. The production tubing string, such as a production tubing, remains in the well while the pump and/or the steam generator are conveyed up and down the cased well. A base installed in the cased well receives either the pump or the steam generator.

Wireline retrievable dsg/downhole pump system for cyclic steam and continuous steam flooding operations in petroleum reservoirs

Growing community of inventors

Bartlesville, OK, United States of America

David R Zornes