Baker Hughes Corporation

Petrolite Corporation

David R Gentry

Jerry J Weers

Gerald T Pancio

Andrew J McCallum

Mark P Stehlin

Weldon J Cappel, Jr

A fuel composition of improved lubricity comprises a lubricity-increasing amount of a lubricity aid dissolved in low sulfur diesel fuel and spark ignition fuels. The lubricity aid is an alkanolamide of a fatty acid, an alkanolamide of a modified fatty acid or a mixture thereof. If the lubricity aid is other than an alkanolamide of an aryl-substituted fatty acid, the composition further necessarily comprises a haze-inhibiting amount of a dehazer. The lubricity of such fuels may be enhanced without acceptably increasing the tendency of the fuel to become hazy upon contact with water.

Fatty acid amide lubricity aids and related methods for improvement of lubricity of fuels

It has been discovered that compositions which are blends or mixtures including a monomeric fatty acid component can serve as stable lubricity additives in distillate fuels, including gasoline. The compositions may include saturated or unsaturated, monomeric fatty acids having from 12 to 22 carbon atoms; a synthetic monomeric acids having from 12 to 40 carbon atoms; and saturated or unsaturated, oligomeric fatty acids having from 24 to 66 carbon atoms. Where a saturated monomeric fatty acid is used, a hindered and/or tertiary amine may be present as a stabilizer.

Composition and method to improve lubricity in fuels

A method for scavenging mercaptans in a hydrocarbon fluid is disclosed. According to the method, an effective mercaptan-scavenging amount of an aqueous scavenging composition is added to the fluid. The composition comprises a quaternary ammonium hydroxide of the formula R.sup.1 R.sup.2 R.sup.3 R.sup.4 NOH. R.sup.1 and R.sup.2 are, independently, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. R.sup.3 is an alkyl group of from two to about eighteen carbon atoms, an aryl group of from two to about eighteen carbon atoms or an alkylaryl group of from four to about eighteen carbon atoms. R.sup.2 and R.sup.3 may be joined to form a heterocyclic ring including the N and optionally an oxygen atom. R.sup.4 is --(CH.sub.2 CH.sub.2 O).sub.n H, wherein n is an integer from one to about eighteen, or --CHR.sup.5 CHR.sup.6 Y, wherein R.sup.5 and R.sup.6 are, independently, hydrogen, alkyl groups of from one to about eighteen carbon atoms, aryl groups of from six to about eighteen carbon atoms or alkylaryl groups of from seven to about eighteen carbon atoms. Y is a non-acidic group. Related compositions and methods are also disclosed.

Quaternary ammonium hydroxides as mercaptan scavengers

A method for scavenging sulfur species from a petroleum-derived medium is disclosed. The method comprises contacting the medium with sulfur species scavenging amount of an imine of the formula ##STR1## wherein x is an integer from 1 to 10, R' is an organic moiety having a number of valences equal to x, R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In an alternative embodiment, the imine is produced by a condensation reaction between an amine having at least one primary amino group and a carbonyl of the formula ##STR2## wherein R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In yet other embodiments, the imine is produced by a condensation reaction between an amine having at least one primary amino group and an aldehyde having at least one alpha-hydrogen in an aldehyde to primary amino group molar ratio of at least about 2:1, are also disclosed.

Use of olefinic imines to scavenge sulfur species

A method for scavenging sulfur species from a petroleum-derived medium is disclosed. The method comprises contacting the medium with sulfur species scavenging amount of an imine of the formula ##STR1## wherein x is an integer from 1 to 10, R' is an organic moiety having a number of valences equal to x, R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In an alternative embodiment, the imine is produced by a condensation reactionic between an amine having at least one primary amino group and a carbonyl of the formula ##STR2## wherein R.sub.1 is hydrogen or a mono-valent organic moieties and R is a mono-valent olefin moiety, provided that R and R.sub.1 contain a total of from about four to about forty carbon atoms. In yet other embodiments, the imine is produced by a condensation reaction between an amine having at least one primary amino group and an aldehyde having at least one alpha-hydrogen in an aldehyde to primary amino group molar ratio of at least about 2:1, are also disclosed.

Growing community of inventors

St. Louis, MO, United States of America

David R Gentry