Monsanto Technology LLC

Akzo Nobel N.v.

David R Eaton

David Z Becher

John W Hemminghaus

Michael E Seitz

Henry E Agbaje

Stephen D Prosch

Daniel R Wright

Eric A Haupfear

Jeffrey Alan Graham

Walter K Gavlick

Shawn Zhu

Peter E Rogers

Eduardo Aurelio Casanova

Giao Vinh Nguyen

Alberto Slikta

Mark D Scaia

Kha Nguyen

James P Coleman

Arnold Hershman

Denis Forster

Lowell R Smith

Donald D Soleta

Robert E Byrd

John Wagenknecht

Leonard Aynardi

Oliver Lerch

Carl Mumford

Alfredo Oba

Bart Roose

Roger J Hoekstra

Gary Klopf

John Hemminghaus

Jeffrey A Graham

A herbicidal composition comprises an aqueous solution of a plurality of salts of glyphosate wherein said glyphosate is in anionic form accompanied by low molecular weight non-amphiphilic cations, wherein a major amount but less than 100% of the low molecular weight non-amphiphilic cations are potassium cations, and wherein the composition has a measured pH of at least about 4.8.

Herbicide compatibility improvement

This invention relates generally to improved methods and herbicidal glyphosate compositions for use in controlling the growth of weeds and unwanted vegetation, and particularly for use in controlling weeds in a crop of transgenic glyphosate-tolerant cotton plants by over-the-top, foliar application of a herbicidal glyphosate formulation.

Mitigating necrosis in transgenic glyphosate-tolerant cotton plants treated with herbicidal glyphosate formulations

This invention relates to the preparation of N-(phosphonomethyl)glycine ('glyphosate') from N-(phosphonomethyl)iminodiacetic acid ('PMIDA'), and more particularly to methods for control of the conversion of PMIDA, for the identification of reaction end points relating to PMIDA conversion and the preparation of glyphosate products having controlled PMIDA content. One such method involves obtaining a series of Fourier transform infrared (&#x201c;FTIR&#x201d;) analyses of the PMIDA content of the aqueous reaction medium or a sample thereof during the course of the reaction. From a plurality of FTIR analyses, a projection is made of the batch reaction time or continuous oxidation residence time within the oxidation reaction zone at which a target conversion or end point may be anticipated to be attained or is attained.

Control of n-(phosphonomethyl)iminodiacetic acid conversion in manufacture of glyphosate

A process is provided for preparing a glyphosate salt solution that comprises potassium and IPA cations in a desired mole ratio, and that has a glyphosate a.e. concentration not less than about 400 g/l. The process includes adding glyphosate acid to a glyphosate potassium salt solution having a glyphosate assay of at least about 40% a.e. by weight, to form a slurry. The process also includes introducing isopropylamine, in an amount sufficient to neutralize the added glyphosate acid, to the slurry with mixing until all glyphosate is dissolved, to form a mixed glyphosate salt solution comprising potassium and IPA cations in the desired mole ratio.

Glyphosate salt herbicidal composition

The present invention generally relates to herbicidal compositions comprising a herbicide, an etheramine alkoxylate surfactant, an alkylamine alkoxylate surfactant having a high degree of alkoxylation and compatibilizer comprising, in some embodiments, an alkylamine alkoxylate surfactant having a low degree of alkoxylation or an alkylpolyglucoside surfactant. The herbicidal compositions are herbicidally efficacious and cause low eye irritation and low crop injury.

Herbicide formulations containing an etheramine and alkylamine alkoxylate surfactant system

A process for preparing an aqueous concentrate glyphosate salt composition comprises (i) neutralizing glyphosate acid with potassium hydroxide and a minor amount of a low molecular weight organic amine in presence of water to produce a glyphosate salt solution having a pH of about 4.8 to about 5.0, where the neutralizing operation comprises a first neutralization step in which a slurry or glyphosate salt solution having a pH of about 4.4 to about 4.7 is produced and a second neutralization step in which the pH is adjusted to about 4.8 to about 5.0; and (ii) after the first neutralization step and before, during or after the second neutralization step, adding further water if necessary and optionally at least one surfactant to produce a final composition having a total glyphosate a.e. concentration not less than about 360 g/l.

A herbicidal composition comprises in aqueous solution a mixture of salts of glyphosate at a total glyphosate a.e. concentration not less than about 360 g/l, wherein (a) said glyphosate is in anionic form accompanied by low molecular weight non-amphiphilic cations in a total molar amount of about 100% to about 120% of the molar amount of said glyphosate; (b) said cations comprise potassium and propylammonium (e.g., isopropylammonium) cations in a mole ratio of about 70:30 to about 90:10; and (c) said potassium and propylammonium cations together constitute about 90 to 100 molar percent of all of said low molecular weight non-amphiphilic cations in the composition.

The present invention generally relates to a process for preparing the alkoxylated alkylamines and/or alkyl ether amines. The process consists of three stages, and utilizes an alkali catalyst. The alkoxylated alkyl amines and alkoxylated alkyl ether amines prepared by the process possess the peaked distribution and contain less hazardous by-product.

Alkoxylated alkylamines/alkyl ether amines with peaked distribution

A herbicidal composition comprises an aqueous solution of one to a plurality of salts of glyphosate at a total glyphosate a.e. concentration not less than about 360 g/l, wherein (a) said glyphosate is in anionic form accompanied by low molecular weight non-amphiphilic cations in a total molar amount of about 110% to about 120% of the molar amount of said glyphosate; and (b) a major amount to substantially all of the low molecular weight non-amphiphilic cations are potassium cations. The composition exhibits improved tank-mix compatibility with a phenoxy-type herbicide salt formulation by comparison with an otherwise similar composition having a lower molar amount of said low molecular weight non-amphiphilic cations.

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Kirkwood, MO, United States of America

David R Eaton