The Dow Chemical Company

Dow Global Technolgoies LLC

David P Denton

Joseph P Weller

Stuart Farquharson

Sandra V Lange

Jean P Chauvel, Jr

Mary Anne Leugers

Charles William Lipp

Harry D Ruhl, Jr

Chester R Norman

Mary Beth Seasholtz

Sarah L Martin

Barbara A Kirsch

Gregory A Winter

Bruce J Gertner

Bruce Gertner

Charles Lipp

Disclosed is a catalyst injection nozzle that comprises an outer tube with an open end, a nozzle tip with a diameter connected to the outer tube open end, an orifice connected to the nozzle tip internal to the outer tube, an internal mixing zone connected to the orifice internal to the outer tube, an inner tube residing within the outer tube further comprising an open end connected to the internal mixing zone, where a steady-state, uniform two-phase flow regime between an atomizing gas and at least one liquid catalyst feed does not form in the internal mixing zone at an atomizing gas to liquid catalyst feed flow ratio of about 0.05 to about 10.

Method for gas phase polymerization

A process control method for controlling a polyolefin polymerization process, such as a solution polyethylene process, which includes five steps. The first step is to flow a stream of a solvent into a polyolefin reactor, such as flowing a stream of heptane solvent into the reactor at essentially a constant rate. The second step is to add a principal monomer to the stream of solvent, such as by adding ethylene at a controllable rate to the stream of solvent. The third step is to add a co-monomer to the stream of solvent, such as by adding 1-octene at a controllable rate to the stream of solvent. The fourth step is to determine the concentration of the principal monomer and the concentration of the co-monomer in the stream of solvent by high resolution multi-wavelength vibrational spectroscopy analysis, such as by Fourier transform infrared spectroscopy system having a spectral resolution of 4 wavenumbers which analyzes at 1909 wavenumbers for ethylene, at 1829 wavenumbers for 1-octene and at 2120 wavenumbers for a reference signal. The fifth step is to control the rate of addition of the principal monomer, the rate of addition of the comonomer or preferably the rate of addition of both the principal monomer and the co-monomer according to the determination of the fourth step to obtain the desired concentration of ethylene and 1-octene in the solvent so that, for example, the density of the polyolefin product can be controlled.

Process control method for manufacturing polyolefin

A photometric probe or a photometric cell having separate windows and a metallic probe body or cell body. The window(s) are sealed to the probe or cell body by brazed or frit seals which are less likely to leak after extended use in high temperature and/or high pressure industrial applications than probes and cells having gasket sealed windows. The windows can be made of sapphire, cubic zirconia, diamond, ruby, glass or quartz and, in the case of the probe, can be in the shape of an Attenuated Total Reflectance prism. The probe or cell body can be Kovar alloy or stainless steel.

Photometric cell and probe having windows fusion sealed to a metallic

Growing community of inventors

Richwood, TX, United States of America

David P Denton