Camx Power LLC

Tiax LLC

Foster-miller, Inc.

David Ofer

Suresh Sriramulu

Adrian W Pullen

Jane Rempel

Kenan Sahin

Daniel Kaplan

Thomas Carney

Rahul Malik

Bindu R Nair

Robert F Kovar

Jennifer Anne Nelson

Leslie S Rubin

William A Stevenson

Christopher H McCoy

John D Larouco

Bookeun Oh

Emily J Stoler

Adrian Pullen

Provided are electrochemical secondary cells that exhibit excellent abuse tolerance, deep discharge and overcharge conditions including at extreme temperatures and remain robust and possess excellent performance. Cells as provided herein include: a cathode a polycrystalline cathode electrochemically active material including the formula LiMO, wherein −0.9≤x≤0.3, −0.3≤y≤0.3, and wherein M includes Ni at 80 atomic percent or higher relative to total M, an anode including an anode electrochemically active material defined by an electrochemical redox potential of 400 mV or greater vs Li/Li.

High power, extended temperature range-capable, highly abuse overcharge and discharge tolerant rechargeable battery cell and pack

Provided are compositions, systems, and methods of making and using pre-lithiated cathodes for use in lithium ion secondary cells as the means of supplying extra lithium to the cell. The chemically or electrochemically pre-lithiated cathodes include cathode active material that is pre-lithiated prior to assembly into an electrochemical cell. The process of producing pre-lithiated cathodes includes contacting a cathode active material to an electrolyte, the electrolyte further contacting a counter electrode lithium source and applying an electric potential or current to the cathode active material and the lithium source thereby pre-lithiating the cathode active material with lithium. An electrochemical cell is also provided including the pre-lithiated cathode, an anode, a separator and an electrolyte.

Pre-lithiated electrode materials and cells employing the same

Provided are electrochemically active secondary particles that provide excellent capacity and improved cycle life. The particles are characterized by a plurality of nanocrystals with small average crystallite size. The reduced crystallite size reduces impedance generation during cycling thereby improving capacity and cycle life. Also provided are methods of forming electrochemically active materials, as well as electrodes and electrochemical cells employing the secondary particles.

Nanocrystals of polycrystalline layered lithium nickel metal oxides

Provided are electrochemically active particles suitable for use as an active material in a cathode of a lithium ion electrochemical cell that include: a plurality of crystallites comprising a first composition comprising lithium, nickel, and oxygen; and a grain boundary between adjacent crystallites of the plurality of crystallites and comprising a second composition comprising lithium, nickel, and oxygen; wherein the grain boundary has a higher electrochemical affinity for lithium than the crystallites. The higher electrochemical affinity for Li leads to increased Li retention in the grain boundaries during or at charge relative to the bulk crystallites and stabilizes the structure of the grain boundaries and crystallites for improved cycling stability with no appreciable loss in capacity.

Stable cathode materials

Provided are electrochemical secondary cells that exhibit excellent abuse tolerance, deep discharge and overcharge conditions including at extreme temperatures and remain robust and possess excellent performance. Cells as provided herein include: a cathode a polycrystalline cathode electrochemically active material including the formula LiMO, wherein &#x2212;0.9&#x2264;x&#x2264;0.3, &#x2212;0.3&#x2264;y&#x2264;0.3, and wherein M includes Ni at 80 atomic percent or higher relative to total M, the cathode electrochemically active material comprising a non-uniform distribution of Co; an anode including an anode electrochemically active material of the formula LiTiOwherein &#x2212;0.3&#x2264;a&#x2264;3.3, &#x2212;0.3&#x2264;b&#x2264;0.3; and wherein the anode and the cathode each independently include a current collector substrate comprising aluminium.

Provided are electrochemical secondary cells that exhibit excellent abuse tolerance, deep discharge and overcharge conditions including at extreme temperatures and remain robust and possess excellent performance. Cells as provided herein include: a cathode a polycrystalline cathode electrochemically active material including the formula LiMO, wherein &#x2212;0.9&#x2264;x&#x2264;0.3, &#x2212;0.3&#x2264;y&#x2264;0.3, and wherein M includes Ni at 80 atomic percent or higher relative to total M, an anode including an anode electrochemically active material defined by an electrochemical redox potential of 400 mV or greater vs Li/Li.

Provided are electrochemical cells that include as a cathode active material within the cathode of the cell secondary particles that provide excellent capacity and improved cycle life. The particles are characterized by grain boundaries between adjacent crystallites of the plurality of crystallites and comprising a second composition having a layered &#x3b1;-NaFeO-type structure, a cubic structure, a spinel structure, or a combination thereof, wherein the electrochemically active cathode active material has an initial discharge capacity of 180 mAh/g or greater; and wherein the electrochemical cell has an impedance growth at 4.2V less than 50% for greater than 100 cycles at 45&#xb0; C.

Polycrystalline metal oxides with enriched grain boundaries

Provided are electrochemically active secondary particles that provide excellent capacity and improved cycle life. The particles are characterized by selectively enriched grain boundaries where the grain boundaries are enriched with Al and Co. The enrichment with Al reduces impedance generation during cycling thereby improving capacity and cycle life. Also provided are methods of forming electrochemically active materials, as well as electrodes and electrochemical cells employing the secondary particles.

A battery system including: a lithium-ion cell including a positive electrode including a first metal oxide, an electrolyte, and a negative electrode including a second metal oxide having an electrochemical redox potential of 0.5 volt to 3 volts versus lithium; and an electrical circuit including a switchable component connecting the positive electrode and the negative electrode, wherein the switchable component provides a shunt between the positive electrode and the negative electrode in a first switch position, and wherein the electrical circuit is configured to provide a voltage of 0.1 volt or less between the positive electrode and the negative electrode when the switchable component is in the first switch position.

Electrically restorable rechargeable battery, and methods of manufacture and methods of operating the battery

Provided are electrochemically active secondary particles that provide excellent capacity and improved cycle life. The particles are characterized by selectively enriched grain boundaries where the grain boundaries are enriched Al. The enrichment with Al reduces impedance generation during cycling thereby improving capacity and cycle life. Also provided are methods of forming electrochemically active materials, as well as electrodes and electrochemical cells employing the secondary particles.

A system for determining battery characteristics based on differential current monitoring includes a first battery; a second battery, the second battery being connected in parallel with the first battery; and a differential current measurement module comprising at least one current measuring device, the differential current measurement module being configured to determine a differential current associated with the first battery and the second battery. A method for determining battery characteristics based on differential current monitoring includes determining a differential current associated with a first battery and a second battery, the first battery being connected in parallel with the second battery.

Differential current monitoring for parallel-connected batteries

A particle, including: a plurality of crystallites including a first composition having a layered &#x3b1;-NaFeO-type structure and including lithium in an amount of about 0.1 to about 1.3 moles, per mole of the first composition, nickel in an amount of about 0.1 to about 0.79 mole, per mole of the first composition, cobalt in an amount of 0 to about 0.5 mole, per mole of the first composition, and oxygen in an amount of about 1.7 to about 2.3 moles, per mole of the first composition; and a grain boundary between adjacent crystallites of the plurality of crystallites and including a second composition having the layered &#x3b1;-NaFeO-type structure, a cubic structure, or a combination thereof, wherein a concentration of cobalt in the grain boundary is greater than a concentration of cobalt in the crystallites.

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Needham, MA, United States of America

David Ofer