Kimberly-clark Worldwide, Inc.

Kimberly-clark Corporation

David Michael Schertz

James Hongxue Wang

William S Pomplun

Dave Allen Soerens

Gregory James Wideman

Vasily Aramovich Topolkaraev

Michael Tod Morman

James Russell Fitts, Jr

Charles John Morell

Howard Martin Welch

Jay Sheldon Shultz

Hannong Rhim

Wilfred Eugene Riddell

Donald V Willitts

Jason K Wehner

Leslie D Dobbins

Jessica M Rawls

The present invention is a hydrolytically modified, biodegradable polymer and a method of making a hydrolytically modifiable a biodegradable polymer. In a preferred embodiment, the invention is a method of grafting polar groups onto biodegradable polymers and modified biodegradable polymer compositions produced by the method. The polymer compositions are useful as components in flushable and degradable articles. Water-sensitive polymer blends and method of making those polymer blends are also disclosed.

Grafted biodegradable polymer blend compositions

This invention relates, in general, to blend compositions of an unmodified poly vinyl alcohol and a thermoplastic elastomer and thermoplastic film and fiber structures comprising these blend compositions. More specifically, this invention relates to substantially water-free films and fibers comprising unmodified polyvinyl alcohol and a thermoplastic elastomer.

Blend compositions of an unmodified poly vinyl alcohol and a thermoplastic elastomer

The present invention discloses water-soluble compositions comprising a blend of poly(ethylene oxide) and poly(vinyl alcohol) that have improved ductility over water-soluble compositions comprising poly(vinyl alcohol) alone. In one desirable embodiment of the present invention, the poly(ethylene oxide) component of the blend is grafted. Grafted poly(ethylene oxide) resins have improved processability and improved blend compatibility with poly(vinyl alcohol). Films comprising a melt blend of poly(vinyl alcohol) and grafted poly(ethylene oxide) have improved melt processability as well as other improved properties. Films comprising compositions of the present invention have improved ductility over films comprising poly(vinyl alcohol) alone while retaining much of the high strength and water solubility exhibited by such poly(vinyl alcohol) films.

Method of making blends of poly(vinyl alcohol) and poly(ethylene oxide)

Water-responsive biodegradable polymer compositions and method of making same

New methods for and patterns of applying meltsprayed materials in single-layer web and laminate constructions so as to control various characteristics in the webs and laminates is provided. The patterns of adhesive produce scrim or cell-like patterns that allow for control of desirable characteristics. For example, the loft of a laminate may be enhanced, as well as strength properties.

Laminate and web characteristic control by varying bonding patterns

Breathable, flushable, porous films and articles made therewith and a process for making these films. The present invention is directed to composites comprising a polymer that is water-soluble or water-degradable and a filler. The films are made by extruding the composite materials into a precursor film and, preferably, stretching the precursor film to achieve the desired breathability and water-dispersibility of the finished film. In one embodiment, the composition of the invention comprises a polymer of ethylene oxide and a filler such as calcium carbonate.

Extruded poly (ethylene oxide) and filler composites and films having enhanced ductility and breathability

Blends of poly (vinyl alcohol) and poly (ethylene oxide) and articles made therewith

Melt processable, flushable polymer fibers and methods of making melt processable, flushable polymer fibers are disclosed. The fibers comprise poly(ethylene oxide). Preferably, the poly(ethylene oxide) is modified by grafting polar vinyl monomers, such as poly(ethylene glycol) methacrylate and 2-hydroxyethyl methacrylate, onto poly(ethylene oxide). The modified poly(ethylene oxide) has improved melt processability and can be used to melt process poly(ethylene oxide) fibers of thinner diameters.

Melt processable poly (ethylene oxide) fibers

A fiber composition which comprises a blend of modified polypropylene and modified poly(ethylene oxide). This fiber composition can be melt-processed to make fibers useful in flushable personal care products. A process for making this fiber composition is also provided.

Flushable fiber compositions comprising modified polypropylene and modified poly (ethylene oxide) and process for making the same

Selectively cold-water responsive compositions constructed of combinations of polymers including at least one hydrolytically degradable polymer and at least one cold-water soluble polymer are provided. Additionally, methods of making and using selectively cold-water sensitive compositions are described. In one embodiment, the method comprises combining a polylactide and a cold-water soluble polyvinyl alcohol at a temperature above the melting point of the polymer having the higher melting point, and below the decomposition point of the polymer having the lower decomposition point, to form a homogeneous polymer blend is also provided. The cold-water responsive properties of the compositions of the present invention may be varied include water dispersible, water disintegratable, and water weakenable.

Cold-water flushable compositions comprising polylactic acid dispersed in polyvinyl alcohol

Flushable fiber compositions comprising modified polypropylene and modified poly(ethylene oxide) and process for making the same

Reactive extrusion process for making modifiied biodegradable compositions

Method of making a polymer blend composition by reactive extrusion

The present invention is a water-responsive blend of a polylactide and a polyvinyl alcohol. The present invention includes films and personal care articles comprising a blend of a polyvinyl alcohol and a polylactide and includes a method of making such films and articles and a method of varying the water responsiveness of such films and articles. In a preferred embodiment, the compositions, films and articles comprise a blend of polyvinyl alcohol and modified polylactide. The compositions and films described herein are useful as a component in flushable and degradable articles.

Water-responsive, biodegradable compositions and films and articles comprising a blend of polylactide and polyvinyl alcohol and methods for making the same

Growing community of inventors

Roswell, GA, United States of America

David Michael Schertz