Union Carbide Chemicals & Plastics Technology Corporation

David Merrill Rebhan

Kiu H Lee

Fathi David Hussein

John Roberts Parrish

Ronald Steven Eisinger

Ping P Cai

Roger B Painter

Gary Harry Williams

Ronald Irvin Raether

David Nunn Jones

Thomas Walter Pilgram

Harvey Gene Kocian

David Albin Wibbenmeyer

Joseph Patrick Welch

William Jene Price

There is provided a post-reactor process for a polymer, especially an elastomeric polymer, prepared by a gas phase polymerization in the presence of an inert particulate material comprising: introducing the polymer containing inert particulate material into a polishing vessel in the presence of a fluidizing gas under polishing conditions.

Post-reactor process for treating polymers prepared in a gas phase polymerization in the presence of an inert particulate material

The present invention teaches a process for controlling a continuous gas phase (exothermic) process operating in condensing mode (e.g. polymerization) with a selected temperature for the reactor bed or outlet and with a temperature differential between the reactor inlet and the reactor bed or outlet by controlling the heat transfer provided by the heat exchanger in the recycle line to maintain the selected reactor bed temperature or outlet temperature while simultaneously controlling a condensable liquid feed rate to maintain the temperature differential.

Control of gas phase polymerization reactions

A process for the production of polypropylene comprising continuously contacting liquid propylene or a mixture comprising liquid propylene and one or more other alpha-olefins in one or more reaction zones, under gas phase polymerization conditions, with a catalyst system comprising (i) a solid particulate catalyst precursor, which includes magnesium; titanium; a halogen which is chlorine, bromine, or iodine, or mixtures thereof; and, as an inside electron donor, a carboxylic acid ester; (ii) a hydrocarbylaluminum cocatalyst; and (iii) as an outside electron donor, a silicon compound containing at least one silicon-oxygen-carbon linkage, the particles of precursor being carried into the reaction zone(s) via a portion of the liquid propylene, the flow rate of said portion having a Reynolds number greater than about 15,000.

Process for the production of polypropylene

A improved process is provided for polymerization of olefin and/or diolefin polymer, using sonic cleaning devices, with optimum design and operation, to eliminate or reduce reactor fouling and/or sheeting.

Gas phase fluidized bed polymerization process using sonic cleaner with

A process for the polymerization of propylene or a mixture comprising propylene and one or more alpha-olefins and, optionally, one or more diolefins comprising contacting the propylene or the mixture of olefins in at least one reaction zone, under polymerization conditions, with a catalyst system comprising (i) a solid catalyst precursor, which includes magnesium; titanium; a halogen which is chlorine, bromine, or iodine, or mixtures thereof; and a mono- or polycarboxylic acid ester; (ii) a hydrocarbylaluminum cocatalyst; and (iii) a mixture of selectivity control agents comprising a mono- or polycarboxylic acid ester and a silicon compound containing at least one silicon-oxygen-carbon linkage with the proviso that (a) the atomic ratio of aluminum to titanium is in the range of about 5 to about 300; and (b) the molar ratio of the ester to silicon compound in the mixture of selectivity control agents is at least about 1.5:1.

A process for terminating or retarding the rate of polymerization of propylene or a mixture comprising propylene and one or more other olefin monomers, in a gas phase reactor, in the presence of a catalyst system comprising (i) a solid catalyst precursor composition which includes magnesium, titanium, halogen, and carboxylic acid ester; (ii) hydrocarbyl aluminum cocatalyst; and (iii) a silicon compound containing at least one silicon-oxygen-carbon linkage, which comprises introducing a phthalate compound at a rate and in a sufficient quantity to substantially retard or terminate the said polymerization reaction.

Growing community of inventors

Alum Creek, WV, United States of America

David Merrill Rebhan