Wilson Greatbatch Ltd.

Greatbatch Ltd.

Wilson Greatbatch Technologies, Inc.

David M Spillman

Esther S Takeuchi

Hong Gan

Robert S Rubino

Marcus J Palazzo

Joseph M Lehnes

Ho-Chul Yun

Christine A Frysz

Paul T Hallifax

Tina L Urso

Steven Davis

Harvey A Hornung, Ii

Bruce Meyer

William D Clark

Steve J Ebel

An electrochemical cell having a casing housing an electrode assembly of a separator residing between a lithium anode and a cathode comprising silver vanadium oxide and fluorinated carbon is described. The electrode assembly is activated with a nonaqueous electrolyte comprising a lithium salt dissolved in a solvent system of propylene carbonate mixed with 1,2-dimethoxyethane, dibenzyl carbonate (DBC), lithium bis(oxalato)borate (LiBOB), and fluoroethylene carbonate (FEC). Preferably DBC is present in an amount ranging from about 0.005 moles (M) to about 0.25M, LiBOB is present in an amount ranging from about 0.005 wt. 5 to about 5 wt. %, and FEC is present in an amount ranging from about 0.01 wt. % to about 10 wt. %. This electrolyte formulation is more conductive than the conventional or prior art binary and ternary solvent system electrolytes while being chemically and electrochemically stable toward Li/SVO cells, Li-SVO/CFmixture cells, and Li-SVO/CFsandwich cathode primary electrochemical cells.

Lithium electrochemical cell activated with an electrolyte containing DBC, LiBOB and FEC additives

An electrochemical cell having a casing housing an electrode assembly of a separator residing between a lithium anode and a cathode comprising silver vanadium oxide and fluorinated carbon is described. The electrode assembly is activated with a nonaqueous electrolyte comprising a lithium salt dissolved in a solvent system of propylene carbonate mixed with 1,2-dimethoxyethane, lithium bis(oxalato)borate (LiBOB), and fluoroethylene carbonate (FEC). Preferably LiBOB is present in an amount ranging from about 0.005 wt. 5 to about 5 wt. %, and FEC is present in an amount ranging from about 0.01 wt. % to about 10 wt. %. This electrolyte formulation is more conductive than the conventional or prior art binary and ternary solvent system electrolytes while being chemically and electrochemically stable toward Li/SVO cells, Li-SVO/CFmixture cells, and Li-SVO/CFsandwich cathode primary electrochemical cells.

Lithium electrochemical cell activated with an electrolyte containing LiBOB and FEC additives

The present invention is directed to providing a lithium carbonate passivation layer on lithium through exposure of the active material to gaseous carbon dioxide prior to cell assembly. This results in an electrochemical cell which possesses improved safety and voltage delay characteristics in comparison to prior art cells comprising unexposed lithium. The preferred cell is of a lithium oxyhalide chemistry.

Lithium oxyhalide cell with improved safety and voltage delay characteristics

The invention includes a method of using a cell, such as a battery. In a method according to the invention, the cell is charged, discharged, and a voltage of the cell is measured after the discharge period. The measured voltage is compared to a standard voltage, and then the cell is charged again.

Method of using a cell

An electrochemical cell comprising a medium rate electrode region intended to be discharged under a substantially constant drain and a high rate electrode region intended to be pulse discharged, is described. Both electrode regions share a common anode and are activated with the same electrolyte.

Electrochemical cell having multiplate electrodes with differing discharge rate regions

It has been discovered that the connection between a current collector and a molybdenum terminal pin can be improved by roughening the terminal pin. However, a roughened terminal pin detracts from the integrity of the glass-to-metal seal. To overcome this, a sleeve or couple surrounds that portion of the roughened terminal pin that will be sealed to the insulating glass. The sleeve or couple is welded at each end to the terminal pin, and a glass-to-metal seal is formed between the sleeved terminal pin, the insulating glass, and the metallic lid. The resulting assembly contains a portion of the terminal pin that has a roughened surface and is suitable for making a high strength connection to a current collector of a primary or secondary lithium ion battery.

Glass to metal seal

A lithium ion secondary battery having an irregular shape with a unitary anode and unitary cathode that are spirally wound and that provide a high energy density for an implantable biomedical device.

Electrochemical lithium ion secondary cell having a scalloped electrode assembly

A secondary electrochemical cell comprising a medium rate electrode region in a side-by-side electrode plate configuration intended to be discharged under a substantially constant drain and a high rate electrode region disposed in a jellyroll wound configuration intended to be pulse discharged, is described. Both electrode regions share a common anode and are activated with the same electrolyte.

Electrochemical lithium ion secondary cell having multiplate and jellyroll electrodes with differing discharge rate regions

In primary cells, the addition of gaseous carbon dioxide to the nonaqueous electrolyte has beneficial effects in terms of minimizing or eliminating voltage delay and reducing Rdc build-up when the cell is subjected to pulse current discharge conditions. For secondary systems, carbon dioxide provided in the electrolyte benefits cycling efficiency. The problem is that carbon dioxide readily degases from an electrolyte prepared under an ambient atmosphere. To prevent this, the carbon dioxide-containing electrolyte is prepared and stored in a carbon dioxide atmosphere. Also, the thusly prepared electrolyte is filed into the casing in a carbon dioxide-containing atmosphere. This prevents degassing of the additive from the electrolyte.

Manufacturing process for improved discharge of lithium-containing electrochemical cells

An alkali metal secondary electrochemical cell, and preferably a lithium ion cell, provided with a removable gas relief valve, is described. The gas release valve is positioned on the casing, in fluid flow communication between the inside thereof and the exterior. This gas release valve serves to eliminate cell gases that build up inside the casing during the cell's formation stage. Once the lithium-ion cell has completed formation, the gas release valve is removed and replaced with a hermetic closure. Removal of the gas release valve and sealing of the cell takes place in an environment in which no outside gas is capable of being introduced inside the casing. The cell can also be provided in a tank filled with inert gas and a filter which separates the cell gas from the inert gas. When cell formation is completed, the cell hermetically sealed.

Apparatus for releasing gases from rechargeable lithium electrochemical cells during the formation stage of manufacturing

alkali metal electrochemical cell capable of discharge at elevated pressure and temperature is described. To help increase the cell's pressure tolerance, the cell header has an internal groove surrounding the glass-to-metal seal.

Electrochemical cell with novel header assembly

A secondary electrochemical cell comprising a medium rate electrode region intended to be discharged under a substantially constant drain and a high rate electrode region intended to be pulse discharged, is described. Both electrode regions share a common anode and are activated with the same electrolyte.

Electrochemical lithium ion secondary cell having multiplate electrodes with differing discharge rate regions

An alkali metal electrochemical cell, and particularly a lithium oxyhalide cell, is described. The oxyhalide cell also exhibits superior restart characteristics by the provision of a MANNIGLASS 1200 separator.

High temperature lithium oxyhalide electrochemical cell

A rechargeable alkali metal electrochemical cell, and preferably a lithium-ion secondary cell, constructed of low magnetic susceptibility materials, is described. The non-magnetic characteristics enable the secondary cell to be used within the confines of a Magnetic Resonance Imaging system. The cell includes an electrolyte solution comprising ethylene carbonate, dimethyl carbonate, ethylmethyl carbonate and diethyl carbonate.

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Tonawanda, NY, United States of America

David M Spillman