Sun Chemical Corporation

David Klein

Ramasamy Krishnan

Mark D Schneider

Christian Johnke

Jerome Bollard

Hiroyuki Sugiyama

Kenneth R Smith

Juanita M Parris

Richard R Durand, Jr

Michael J Jurek

Gary F Dandreaux

Thierry Frinault

Ilca Webster

Stephen Ordway

The present invention provides energy curable thixotropic compositions comprising low amounts of 2,2,4-trimethyl-1,3-pentanediol isobutyrate (Texanol); 2,2,4-trimethyl-1,3-pentanediol diisobutyrate (TXIB); or dipropylene glycol butyl ether (DPGBE mixes isomers), or combinations thereof. The addition of the selected solvents in amounts of about 0.5 wt % to 3 wt % reduced the low shear rate viscosity of the energy curable thixotropic compositions.

Viscosity modifiers for energy curable inks

The present invention provides water-based energy curable compositions that exhibit improved printability, adhesion, opacity, and wash-up properties. The compositions comprise one or more inert water-based polyurethane resins and one or more water-based phosphate esters. Addition of the inert polyurethane resins and phosphate esters improves adhesion of the energy curable compositions to a variety of substrates.

Adhesion promoters for UV flexographic inks and coatings

Described herein are compositions suitable for use as binder components for inclusion in printing inks and coatings, such as those used in the gravure and flexographic printing process and which are printed on substrates such as polyolefin (e.g., polyethylene, polypropylene) and poly(ethylene terephthalate) (PET). The compositions are non-aqueous dispersions in which an one or more ethylenically unsaturated acrylates or (meth)acrylates is polymerized with a polyurethane, polyurethane-urea or polyurea in a non-aqueous polymerization medium, such as esters, ketones, and mixtures thereof, forming polymeric hybrid resins in the polymerization medium, which are solvent-dispersible hybrid resins of polyurethane-polyacrylate, polyurethane-urea-polyacrylate, and polyurea-polyacrylate. Films of hybrid resins are also disclosed. These materials exhibit improved film adhesion and are suitable for flexographic and gravure printing inks, especially for printing applications where adhesive lamination bond strengths are required, especially plastic films packaging applications.

Polyurethane-polyacrylate hybrid systems for packaging inks and coatings

Provided are high viscosity essentially non-aqueous dispersions containing acrylic core/shell polymer particles in a non-aqueous solvent; sheetfed, heatset and coldset lithographic ink compositions containing the dispersions; and methods of printing with ink containing the dispersions to improve the setting and drying properties and rub resistance of sheet fed offset, heatset and coldset lithographic inks. The lithographic inks containing the dispersions set quickly enough to allow processing of printed sheets soon after printing.

Compositions and methods to improve the setting properties and rub resistance of printing inks

The use of non aqueous dispersions NADs has enabled the development of fast setting sheet fed inks, for example. However either due to residual monomers or fractions of initiators, these NAD's have an objectionable odor. A chemical means of dramatically reducing the odor of the NAD's is thus presented. In exemplary embodiments of the present invention, such a chemical treatment can include an amine/alkali mixture in a coupling solvent. In exemplary embodiments of the present invention, the coupling solvent can be one or more of an alcohol, glycol or glycol ether, such as, for example, isopropyl alcohol. In exemplary embodiments of the present invention the amine can be an alkyl amine, such as, for example, diethyl amine, or various other amines, whether alone or in combination. In exemplary embodiments of the present invention, the alkali can be one or more of sodium hydroxide, potassium hydroxide and ammonium hydroxide, whether alone or in any combination thereof.

Method for odor reduction of non-aqueous dispersions

A web offset heatset printing ink composition having less than about 2 wt. % of volatile organic compounds containing an aqueous polymer latex dispersed in an ink base of a resin, a non-volatile plasticizer, and a pigment and method for preparing same.

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Wayne, NJ, United States of America

David Klein