International Coal Refining Company

Air Products and Chemicals, Inc.

David H Ying

Edwin N Givens

Wayne Thomas McDermott

Robert M Thorogood

Robert F Weimer

Wilman Tsai

The present invention involves an efficient process for separating selected components of a gas stream by integrating a cryogenic separation unit and a membrane separation unit. Two embodiments provide for the concurrent generation of an argon-rich stream in the gas or liquid phase, along with a nitrogen-rich product stream, both being produced from a stream normally comprising oxygen, nitrogen, and argon, e.g., air. Broadly, the novel system uses a membrane means to preferentially reject the oxygen component from the recycle stream of the cryogenic unit, concurrently accumulating the argon component to allow its separation as an argon-enriched product stream.

Hybrid membrane - cryogenic generation of argon concurrently with

A fired heater for a coal liquefaction process is operated under conditions to maximize the slurry slug frequency and thereby improve the heat transfer efficiency. The operating conditions controlled are (1) the pipe diameter and pipe arrangement, (2) the minimum coal/solvent slurry velocity, (3) the maximum gas superficial velocity, and (4) the range of the volumetric flow velocity ratio of gas to coal/solvent slurry.

Fired heater for coal liquefaction process

A fired heater for a coal liquefaction process is constructed with a heat transfer tube having U-bends at regular intervals along the length thereof to increase the slug frequency of the multi-phase mixture flowing therethrough to thereby improve the heat transfer efficiency.

There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a solvent, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals are separated from the condensed dissolver effluent. In accordance with the improved process, fresh hydrogen is fed to each dissolver and the entrained gas from each dissolver is separated from the slurry phase and removed from the reactor system before the condensed phase is passed to the next dissolver in the series. In accordance with another process, the feeds to the dissolvers are such that the top of each downstream dissolver is used as a gas-liquid separator.

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Macungie, PA, United States of America

David H Ying