Ifp Energies Nouvelles

Cnrs

Centre National De La Recherche Scientifique

Universite Claude Bernard – Lyon1

Bats, Nicolas

Bazer-bachi, Delphine

Universite Claude Bernard De Lyon 1

David Farrusseng

Nicolas Bats

Delphine Bazer-Bachi

Vincent Lecocq

Marie Savonnet

Catherine Pinel

Antoine Fecant

Cecile Thomazeau

Pascal Raybaud

Yves Schuurman

Fabien Corvaisier

Claude Mirodatos

Michael Rebeilleau

André Van Veen

Simon Rushworth

Jean-Luc Rousset

The invention concerns a method for selectively hydrogenating a hydrocarbon charge containing at least two carbon atoms per molecule, having a final boiling point which is less than or equal to 250&#xb0; C., and comprising at least one polyunsaturated compound, wherein the charge, in the presence of hydrogen, is brought into contact with at least one catalyst comprising a carrier and an active metal phase deposited on the carrier, the active metal phase comprising iron and at least one metal selected from zinc and copper in a molar ratio of Fe:(Zn and/or Cu) of between 0.35 and 0.99.

Method for selective hydrogenation using a catalyst containing iron and at least one metal selected from between zinc or copper

The invention relates to a method for selective hydrogenation of a hydrocarbon feedstock that contains at least 2 carbon atoms per molecule and that has a final boiling point that is less than or equal to 250&#xb0; C. and that comprises at least one polyunsaturated compound, in which in the presence of hydrogen, said feedstock is brought into contact with at least one catalyst that comprises a substrate and an active metal phase deposited on said substrate; said active metal phase comprises copper and at least one metal that is selected from between nickel and cobalt in a molar ratio of Cu:(Ni and/or Co) of greater than 1.

Method for selective hydrogenation using a catalyst containing copper and at least one metal selected from between nickel or cobalt

A crystallized hybrid solid with an organic-inorganic matrix, of three-dimensional structure, containing an inorganic network of zinc-based metal centers connected to one another by organic ligands constituted by the entities &#x2014;OC&#x2014;CH&#x2014;N&#x2014;CO&#x2014; and CHN. Said solid is called DMOF-1-N, and has Zn(&#x2014;OC&#x2014;CH&#x2014;N&#x2014;CO&#x2014;)(CHN) for its base pattern.

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The invention describes a crystallized hybrid solid with an organic-inorganic matrix, of a three-dimensional structure, containing an inorganic network of indium-based metal centers that are connected to one another by organic ligands that consist of the entity &#x2014;OC&#x2014;CH&#x2014;N&#x2014;CO&#x2014;. Said solid is called IHM-2-Nand has an X-ray diffraction diagram as given below.

The invention describes a crystallized hybrid solid with an organic-inorganic matrix, of a three-dimensional structure, containing an inorganic network of aluminum-based metal centers that are connected to one another by organic ligands that consist of the entity &#x2014;OC&#x2014;CH&#x2014;N&#x2014;CO&#x2014;. Said solid is called MIL-53-Al&#x2014;Nand has an X-ray diffraction diagram as given below.

The invention describes a crystallized hybrid solid with an organic-inorganic matrix, of a three-dimensional structure, containing an inorganic network of aluminum-based metal centers that are connected to one another by organic ligands that consist of the entity &#x2014;OC&#x2014;CH&#x2014;N&#x2014;CO&#x2014;. Said solid is called CAU-1-Nand has an X-ray diffraction diagram as given below.

CAU-1-N3 organic-inorganic hybrid solid, equipped with an azide group, and process for its preparation

A process is described for the preparation of a functionalized hybrid solid with an organic-inorganic matrix, crystallized, bearing at least one reactive group based on a triazole ring, from a hybrid solid with an organic-inorganic matrix, MOF&#x2014;NH, comprising: i/ introduction, in a polar solvent S1, of said crystallized hybrid solid MOF&#x2014;NH, of at least one organic compound Q containing a nitride function Nand at least one intermediate reagent R containing a nitrite function NO, ii/ reaction of said reaction mixture, iii/ introduction in the reaction mixture of at least one reagent A bearing an alkyne function or an activated cyanide function, at least one Cu-based catalyst C and at least one polar solvent S2, iv/ reaction of said reaction mixture, v/ filtration and then washing and vi/ drying of said crystallized functionalized hybrid solid.

Method for preparing organic/inorganic hybrid functionalized solids having a triazole ring

A new crystallized hybrid material with an organic-inorganic matrix, called IHM-2, containing an inorganic network of metal centers based on the element indium that are connected to one another by organic ligands that are formed by the entity 2-aminoterephthalate &#x2014;OC&#x2014;CH&#x2014;N&#x2014;CO&#x2014; is described. Said material has an X-ray diffraction diagram as given below.

IHM-2 organic-inorganic hybrid material and processes for preparation

The invention relates to an oxygen conducting membrane includes a dense, mixed-conducting, multi-metallic oxide membrane having one surface which is coated with dispersed particles based on noble metals or magnesium oxide.

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Belmont d'Azegues, France

David Farrusseng