Columbian Chemicals Company

Cities Service Company

David Crabbe

James M Watson

Thomas S Coursen, Jr

George A Joyce

Jorge A Ayala

Wilfred A Pabst

Stable K.sub.2 Fe.sub.22 O.sub.34 in the form of lamellar platelets useful as a dehydrogenation catalyst and a method of manufacturing the same, including the steps of mixing iron oxide and a potassium compound, such as potassium carbonate, preferably in a molar ratio of Fe to K of from 3 to 6 and calcining the mixture at a temperature of at least about 900.degree. C. for at least 15 minutes.

Stable K.sub.2 FE.sub.22 O.sub.34 potassium ferrite phase and method of

Stable K.sub.2 Fe.sub.22 O.sub.34 in the form of lamellar platelets useful as a dehydrogenation catalyst and a method of manufacturing the same, including the steps of mixing iron oxide and a potassium compound, such as potassium carbonate, preferably in a molar ration of Fe to K of from 3 to 6 and calcining the mixture at a temperature of at least about 900.degree. C. for at least 15 minutes.

Stable k.sub.2 fe.sub.22 o.sub.34 potassium ferrite phase

There is provided a pigment concentrate dispersible in plastics and having a substantially improved characteristic extrusion screen life, comprising a dispersion in a resin carrier of an inorganic pigment of the type having a hydrophilic surface, having on its surface in an effective amount a surfactant of the type characterized by an attached polar terminus, in relation to the surface of the pigment, and an unattached nonpolar terminus, in relation to the carrier resin, or of the type characterized by a high molecular weight surface blocking agent. Such pigments include iron oxide pigments, red iron oxide pigment, yellow iron oxide pigment, black iron oxide pigment, divalent ferrite pigments, zinc ferrite pigment, and magnesium ferrite pigment. Such surfactants include dimethyl polysiloxane, isopropyl triisostearoyl titanate, trimethylol propane, trimethylol ethane, and low molecular weight polyethylene. In a preferred concentrate, pigment loading is about 50%, the pigment comprises red iron oxide, the carrier comprises low density polyethylene, and the surfactant comprises trimethylol propane or trimethylol ethane with a treatment level of 0.5% by weight of pigment.

Pigment dispersion in resin

This process reduces the soluble iron found in the final effluent of a plant making iron oxide by the Penniman-Zoph scrap process. The finished oxide product slurry is separated from the scrap iron, and the slurry is aerated while the pH is maintained between about 3.0 and 5.0. As the soluble iron is converted to product oxide, the pH of the system rises toward the higher value.

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St. Louis, MO, United States of America

David Crabbe