Westinghouse Electric Corporation

David C Phillips

James D Smith

Joseph F Meier

William M Hickam

Luciano C Scala

Max Garbuny

William M Alvino

Emil M Fort

Gerald L Carlson

William R Gass

Thomas D Kaczmarek

Kenneth W Grossett

Thomas D Kaczmsrek

Scott L Anderson

Sandra Spewock

A composition is disclosed of a solution of a resinous carrier and at least two compounds which thermoparticulate at different temperatures between 60.degree. and 200.degree. C. A coating is made by applying the composition to a portion of an electrical apparatus exposed to a gas stream. As the temperature of the coating increases the compound therein thermoparticulate. The time between which the compounds thermoparticulate indicates the rate of rise of the temperature and analysis of the products of thermoparticulation indicates the location of the coating in the electrical apparatus. Alternatively, the coating can consist of several layers with a thermoparticulating compound in each layer which thermoparticulates at different temperatures.

Multiple signal thermoparticulating coating

Electrical apparatus cooled with a stream of hydrogen gas is protected from overheating by applying a coating to a portion of the apparatus which is exposed to the gas stream. The coating contains a compound which decomposes between 80.degree. and 200.degree. C. to produce a gas detectable by a monitor. The monitor detects gases heavier than hydrogen in the gas stream and sounds an alarm when they are present.

Protecting electrical apparatus with gas generating compounds

Stereo-regular polymers are produced by forming a moving stream of gaseous monomer having an electric dipole moment, irradiating the monomer with monochromatic light of a wavelength suitable for activating it, and orientating the activated monomer in an electric field. The activated, oriented monomer then polymerizes to form a stereo-regular polymer. Alternatively, a monomer of the general formula ##STR1## can be used, where at least one of the R groups, the resonating R group, forms an electric dipole moment with the remainder of the monomer. The monomer is then irradiated with a monochromatic light beam having a frequency which resonates with a harmonic frequency resulting from the bond between the resonating R group and the remainder of the monomer. Activation of that particular bond on that particular type of monomer results in a stereo-regular polymer. For best results, however, the two methods are combined.

Apparatus for producing stereo-regular polymers

Stereo-regular polymers are produced by forming a moving stream of gaseous monomer having an electric dipole moment, irradiating the monomer with monochromatic light of a wavelength suitable for activating it, and orientating the activated monomer in an electric field. The activated, orientated monomer then polymerizes to form a stereo-regular polymer. Alternatively, a monomer of the general formula ##STR1## can be used, where at least one of the R groups, the resonating R group, forms an electric dipole moment with the remainder of the monomer. The monomer is then irradiated with a monochromatic light beam having a frequency which resonates with a harmonic frequency resulting from the bond between the resonating R group and the remainder of the monomer. Activation of that particular bond on that particular type of monomer results in a stereo-regular polymer. For best results, however, the two methods are combined.

Apparatus and method for producing stereo-regular polymers

A composition is disclosed of a solution of a resinous carrier and at least two compounds which thermoparticulate at different temperatures between 60.degree. and 200.degree. C. A coating is made by applying the composition to a portion of an electrical apparatus exposed to a gas stream. As the temperature of the coating increases the compounds therein thermoparticulate. The time between which the compounds thermoparticulate indicates the rate of rise of the temperature and analysis of the products of thermoparticulation indicates the location of the coating in the electrical apparatus. Alternatively, the coating can consist of several layers with a thermoparticulating compound in each layer which thermoparticulates at different temperatures.

A composition is disclosed of an N-thiophthalimide, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats the N-thiophthalimide in the coating forms particles in the gas stream which are detected by a monitor.

N-thiophthalimide composition for forming thermoparticulating coating

A composition is disclosed of a non-metallic, non-ionic organo-sulfur compound, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats, the organo-sulfur compound in the coating forms particles in the gas stream which are detected by the monitor.

Organo-sulfur composition for forming thermoparticulating coating

A composition is disclosed of a cyanoethylated compound, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats, the cyanoethylated compound in the coating forms particles in the gas stream which are detected by a monitor.

Cyanoethylated composition for forming thermoparticulating coating

A composition is disclosed of a carboxylic acid, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats the carboxylic acid in the coating forms particles in the gas stream which are detected by the monitor.

Carboxylic acid composition for forming thermoparticulating coating

A composition is disclosed of malonic acid, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a fluid stream. The solvent in the composition is evaporated to produce a thermo-particulating coating. When the electrical apparatus overheats the malonic acid in the coating forms particles in the fluid stream which are detected by a monitor.

Method and apparatus for determining thermoparticulation temperature of

An on-line apparatus and method of using particulography as a technique for detecting and locating overheated material such as insulation within a gas-cooled dynamoelectric machine is disclosed. This technique detects the presence of and identifies the origin of thermoparticulates in a gas stream which are produced by thermal degradation of materials. The gas cooling system is continuously monitored by a gas stream monitor and upon the detection of thermoparticulates in the gas stream, the gas stream is diverted through a particulate collection chamber for entrapment of a sample of the thermoparticulates. The sample is then isolated from the gas cooling system and a flow of clean gas is forced through the sample while the collection chamber is heated at a predetermined rate. Heating the collection chamber will cause reparticulation of the thermoparticulates which are carried to a gas stream monitor located downstream by the flowing gas. The gas stream monitor will monitor the gas and will produce a signal that is proportional to the intensity of the thermoparticulates entrapped in the flowing gas stream. The signal from the gas stream monitor is applied to one axis of a recording device and a signal that is proportional to the temperature of the collection chamber is applied to the other axis producing a particulograph. A particulograph is unique to each kind of material that is present within the machine due to the unique thermoparticulation temperature of each material. Thus, by knowing where different types of materials are located within the machine, the location that is overheated can be identified.

Particulography as an on-line technique for detection and location of

A composition is disclosed of a urea compound, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats the urea compound in the coating forms particles in the gas stream which are detected by the monitor.

Urea composition for forming thermoparticulating coating

Malonic acid composition for thermoparticulating coating

A composition is disclosed of metallic carboxylate, a resinous carrier, and a solvent. The composition is applied to a portion of an electrical apparatus which is exposed to a gas stream. The solvent in the composition is evaporated to produce a thermoparticulating coating. When the electrical apparatus overheats the metallic carboxylate in the coating forms particles in the gas stream which are detected by a monitor.

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Pittsburgh, PA, United States of America

David C Phillips