Exxonmobil Chemical Patents Inc.

Exxonmobil Research and Engineering Company

Exxonmobil Chemicals Patents, Inc.

Exxonmobile Chemical Patents Inc.

David B Spicer

George Stephens

Richard Charles Stell

Robert David Strack

James M Frye

Thomas T Hirst

ChangMin Chun

James N McCoy

Subramanian Annamalai

Arthur R DiNicolantonio

William A Aslaner

James L Kendall

James Mitchell Frye

Changmin Chun

Arthur R Di Nicolantonio

Jeffrey P Jones

Mark Bury

Steven M Slack

Philippe J Le Roy

Caleb M Scherer

Robert Trimble

You Fang

Victor K Wei

James Richardson Lattner

Peter J Loftus

Roberto O Pellizzari

Kurt Kraus

Mark A Rooney

Gary F Janda

Reyyan Koc-Karabocek

James Edward Feather

Gregory E Yeo

Gautam Gauba

D Samuel Deutsch

James C Slonaker

Stephen R Phillips

Bharath Krishnamoorthi

Wallace L Ottersbach

James H Belt

Christopher C Penney

Mark E Bury

Processes and systems for quenching an effluent. In certain embodiments, the process can include contacting a pyrolysis effluent and a first quench medium to produce a first quenched effluent. A bottoms stream that can include tar and an overhead stream that can include ethylene and propylene can be obtained from the first quenched effluent. The first quench medium can include a first portion of the bottoms stream that can include a first portion of the tar. In certain embodiments, the process can also include hydroprocessing a second portion of the bottoms stream that can include a second portion of the tar to produce a hydroprocessed product. A hydroprocessed bottoms stream can be obtained from the hydroprocessed product. In certain embodiments, the process can also include contacting at least a portion of the hydroprocessed bottoms stream and the first portion of the bottoms stream to produce the first quench medium.

Processes and systems for quenching pyrolysis effluents

An exhaust steam stream having an absolute pressure from 200 kPa to 1,050 kPa and shaft power are produced from an extraction turbine and/or a back-pressure turbine. The exhaust steam stream can be supplied to an amine regenerator of an amine COseparation process. The shaft power can be utilized to drive equipment in a hydrocarbon processing plant such as an olefins production plant.

Amine COseparation process integrated with hydrocarbons processing

Conduits for cooling a hydrocarbon stream and processes for using same. The conduit can include a first inner wall defining a first bore, a second inner wall defining a second bore, and an outer wall disposed about the first and second inner walls. The conduit can also include an annular support wall connected to an inner surface of the outer wall. An end of the second inner wall and an end of the annular support wall can define a perimeter opening that can be in fluid communication with the second bore. An annular flexible ring can be bonded to the annular support wall and can flexibly contact the first inner wall. A substantially annular cavity can be disposed between the second inner and the outer walls and in fluid communication with the perimeter opening. A quench fluid introduction port can be configured to introduce a quench fluid into the cavity.

Conduits for cooling a hydrocarbon gas-containing stream and processes for using same

Furnace systems and methods for steam cracking hydrocarbons to produce ethylene and other light olefins are provided herein. A furnace system for cracking hydrocarbons includes a radiant firebox containing a plurality of burners and an injection nozzle, a primary transfer line exchanger fluidly coupled to and downstream of the radiant firebox, and a flow restrictor fluidly coupled to and downstream of the primary transfer line exchanger. The furnace system also includes a decoke vessel containing an effluent inlet, a fluid outlet, and a coke outlet, where the effluent inlet is fluidly coupled to and downstream of the flow restrictor and the fluid outlet is fluidly coupled to and upstream of the injection nozzle of the radiant firebox, and a coke collection bin is coupled to the coke outlet of the decoke vessel.

Furnace systems and methods for cracking hydrocarbons

Systems and methods are provided for performing ethane steam cracking at elevated coil inlet pressures and/or elevated coil outlet pressures in small diameter furnace coils. Instead of performing steam cracking of ethane at a coil outlet pressure of ˜22 psig or less (˜150 kPa-g or less), the steam cracking of ethane can be performed in small diameter furnace coils at a coil outlet pressure of 30 psig to 75 psig (˜200 kPa-g to ˜520 kPa-g), or 40 psig to 75 psig (˜270 kPa-g to ˜520 kPa-g). In order to achieve such higher coil outlet pressures, a correspondingly higher coil inlet pressure can also be used, such as a pressure of 45 psig (˜310 kPa-g) or more, or 50 psig (˜340 kPa-g) or more.

High pressure ethane cracking with small diameter furnace tubes

An H-rich fuel gas production plant comprising a syngas production unit can be advantageously integrated with an olefins production plant comprising a steam cracker in at least one of the following: (i) fuel gas supply and consumption; (ii) feed supply and consumption; and (iii) steam supply and consumption, to achieve considerable savings in capital and operational costs, enhanced energy efficiency, and reduced COemissions, compared to operating the plants separately.

Integration of hydrogen-rich fuel-gas production with olefins production plant

An H-rich fuel gas stream can be advantageously produced by reforming a hydrocarbon/steam mixture in to produce a reformed stream, followed by cooling the reformed stream in a waste-heat recovery unit to produce a high-pressure steam stream, shifting the cooled reformed stream a first shifted stream, cooling the first shifted stream, shifting the cooled first shifted stream to produce a second shifted stream, cooling the second shifted stream, abating water from the cooled second shifted stream to obtain a crude gas mixture stream comprising Hand CO, and recovering a COstream from the crude gas mixture stream. The H-rich stream can be advantageously combusted to provide thermal energy needed for residential, office, and/or industrial applications including in the H-rich fuel gas production process. The H-rich fuel gas production process can be advantageously integrated with an olefins production plant comprising a steam cracker.

Production of hydrogen-rich fuel-gas with reduced COemission

A high-pressure steam stream produced from the waste heat recovery system of a syngas producing unit may be superheated and then supplied to a steam turbine in a hydrocarbon production plant to produce an expanded steam stream and shaft power. A portion of the expanded stream can be fed into the reforming reactor in the syngas producing unit. The shaft power can be used to drive compressors and pumps in an olefins production plant. Considerable energy efficiency and capital investment savings can be realized by such steam integration compared to running the olefins production plant separately.

Hydrocarbon reforming processes with shaft power production

The invention relates weldments useful as heat transfer tubes in pyrolysis furnaces. The invention relates to tubes that are useful in pyrolysis furnaces. The weldments include a tubular member and at least one mixing element. The tubular member comprises an aluminum-containing alloy. The mixing element comprises an aluminum-containing alloy. The mixing element's aluminum-containing alloy can be the same as or different from the tubular member's aluminum-containing alloy. Other aspects of the invention relate to pyrolysis furnaces which include such weldments, and the use of such pyrolysis furnaces for hydrocarbon conversion processes such as steam cracking.

Pyrolysis furnace tubes

A burner sub-system, a furnace comprising the same, a fuel combustion process and steam cracking process carried out in the furnace. The burner sub-system comprises a barrier wall segment between the burner tip and the flue-gas recirculation ('FGR') duct, effectively blocking direct gas flow between the burner tip and the FGR duct opening, but without encircling the whole burner tip. The presence of the partial barrier wall has the advantage of preventing the temperature inside the FGR duct from becoming too high, while achieving low NOx emissions from the combustion process without overheating the burner tip because of reduced amount of heat reflection to the burner tip compared to an annular barrier wall. The invention is particularly useful in furnaces where hydrogen-rich fuel gas is combusted.

Burner, furnace, and steam cracking processes using the same

The present disclosure relates to a heat transfer tube including an inner surface and an outer surface. The heat transfer tube further includes a first mixing element and a second mixing element disposed on the inner surface of the tube and projecting inwardly toward a central longitudinal axis of the tube. Adjacent mixing elements are separated by a gap arc distance of about 0.5 inches (1.27 cm) or greater. The first helical row has an angle (&#x398;) from about 15 degrees to about 85 degrees relative to the central longitudinal axis of the tube. The tube has an inner diameter of about 1.85 inches (4.7 cm) or less.

Heat transfer tube for hydrocarbon processing

A method and apparatus of reducing thermal shock in one or more radiant tubes of a pyrolysis furnace is provided. The apparatus is a furnace comprising a blower and blower bypass conduit providing separate fluid communication paths for flue gas from the convection section to a natural draft flue gas stack. The method comprises the steps of: redirecting at least a portion of the flue gas through the blower bypass conduit when a blower shut-off event is indicated as well as reducing the firing rate of the furnace.

Process and apparatus for reducing thermal shock in a hydrocarbon steam cracking furnace

Growing community of inventors

Houston, TX, United States of America

David B Spicer