Geo Specialty Chemicals, Inc.

David B Heller, Jr

Arpad Savoly

Bennie Veal

Dawn P Elko

Michelle L McMahon

The present invention provides a sulfonated coal tar distillate salt polymer that is a condensation product of an aldehyde, preferably formaldehyde, and a sulfonated middle fraction obtained during coal tar distillation. The middle fraction includes from about 40% to about 95% by weight naphthalene and from about 5% to about 60% by weight of a plurality of compounds selected from the group consisting of quinoline, indene, biphenyl, indane, acenaphthene, anthracene, phenanthrene, methyl naphthalene, cresol, phenol, xylenol, and tetralin. The present invention also provides a method of forming a sulfonated coal tar distillate salt polymer. The method includes sulfonating the middle fraction to form a middle fraction sulfonic acid mass, optionally adding a first portion of water to the middle fraction sulfonic acid mass to form a mixture, reacting the mixture and an aldehyde to form a condensate, optionally adding a second portion of water to dilute the condensate, and adding a base to form a sulfonated middle fraction salt polymer. Sulfonated middle fraction salt polymers formed in accordance with the method of the invention are useful as dispersants and plasticizers in aqueous cementitious slurries.

Dispersant composition

A battery paste for a lead oxide battery plate comprising lead oxide, sulfuric acid and a naphthalene sulfonic acid formaldehyde condensate, the condensate being water soluble and having a molecular weight of about 9,000 to 15,000; methods for preparing the battery paste are also disclosed.

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North Wales, PA, United States of America

David B Heller, Jr