Nalco Company

David A Grattan

Peter D Hicks

Linda M Link

George T Totura

Xiaojun Dang

Bruce A Keiser

Amit Gupta

Martin R Godfrey

Shunong Yang

Narasimha M Rao

Raymond D Miller, Jr

Bruce R Bailey, Iii

Linda S Strysik

Jeffrey V Fox

Bhasker B Dave

Martin Godfrey

Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed or remove one or more active chemical species into or from the hot water system and further operable to change at least one system parameter.

Method and device for preventing corrosion in hot water systems

A method of stabilizing silica-containing anionic microparticles upon mixing of the silica-containing anionic microparticles with hard water comprising adding one or more hardness-abating additives to the hard water prior to mixing of the hard water and the silica-containing anionic microparticles; or adding an effective stabilizing amount of one or more hardness-abating agents to the silica-containing anionic microparticles prior to mixing of the hard water with the silica-containing anionic microparticles and a stabilized composition comprising silica-containing anionic microparticles and an effective stabilizing amount of one or more hardness-abating additives.

Method of stabilizing silica-containing anionic microparticles in hard water

Disclosed are systems and methods for monitoring and controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed or remove one or more active chemical species into or from the hot water system and further operable to change at least one system parameter.

Systems and methods for monitoring and controlling corrosion in hot water systems

This invention relates to a method and system for detecting contamination of boiler condensate and/or boiler feedwater in a papermaking process. The method includes measuring an oxidation-reduction potential at one or more locations in the boiler condensate and/or the boiler feedwater of the papermaking process with one or more corrosion stress monitoring devices. A controller is operable to assess whether the measured or a calculated oxidation-reduction potential is within an optimum range. The controller is operable to cause transmission of a signal to direct feeding an effective amount of one or more reductants and/or one or more pH-controlling chemicals into the boiler feedwater and/or one or more a satellite feed locations of the papermaking process.

Method of detecting and reducing contamination in papermaking boiler systems

Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system to inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which assesses and interprets the transmitted potential to determine whether it conforms to an oxidation-reduction potential setting. If the measured potential does not conform the oxidation-reduction potential setting, the controller is operable to feed one or more active chemical species into the hot water system.

Disclosed is a method of inhibiting and/or removing deposits from internal surfaces in a hot water system. The method includes controlling a real-time oxidation-reduction potential in a hot water system to alter the dynamic between deposit constituents and the bulk water of the system to inhibit deposition or initiate deposit removal. The method is equally effective for a system undergoing a wet layup sequence or in an online operational system. The invention further includes a multi-component deposit inhibition and/or removal device, including a receiver, a processor, and a transmitter that work in unison to alter the system dynamics to inhibit or remove deposits.

Method and device for cleanup and deposit removal from internal hot water system surfaces

Disclosed is a method of creating a real-time oxidation-reduction potential signature in a hot water system to detect REDOX stress and inhibit corrosion in the hot water system. The method includes defining one or more operational protective zones in the hot water system. One or more of the operational protective zones includes an oxidation-reduction potential probe that is operable to measure a real-time oxidation-reduction potential in the hot water system at operating temperature and pressure. The probe transmits the measured real-time potential to the controller, which analyzes and interprets the transmitted potential to create an oxidation-reduction potential signature for the hot water system. If the signature does not conform to an oxidation-reduction potential setting, the controller is operable to feed one or more active chemical species into the hot water system.

Method and device for creating and analyzing an at temerature and pressure oxidation-reduction potential signature in hot water systems for preventing corrosion

Disclosed is a method of controlling a real-time oxidation-reduction potential in a hot water system undergoing a wet layup sequence to inhibit corrosion in the hot water system. The method includes separating the wet layup sequence into a plurality of phases. Each phase is either short-term or long-term and a subset of the short-term phases is optionally transitional. The method further includes defining one or more zones in the hot water system. At least one of the defined zones is selected for each phase and one or more of the selected zones include at least one ORP probe operable to measure the real-time ORP and communicate with a controller. The ORP probe(s) either intermittently or continuously measure the real-time ORP at operating temperature and pressure at one or more of the selected zones in one or more of the phases and transmit the measured real-time ORP to the controller. The real-time ORP is assessed to determine whether it conforms to an ORP setting for that phase. The invention further includes a multi-component control device for a hot water system undergoing a wet layup sequence.

Method and device for preventing corrosion in hot water systems undergoing intermittent operations

A method of providing a continuous, sequential, and cyclic, if desired, liquid feed to a processor from a plurality of containers, which comprises feeding the liquid from a first of the containers through a first conduit to a reservoir having a float valve, to keep the level of the liquid in the reservoir high enough to maintain the float valve in an upper floating position that closes the float valve. The first conduit is uncontrolled by the float valve. The float valve controls a second conduit which connects with a second container. As liquid is withdrawn from the reservoir for processing, liquid from the first conduit and container replenishes the reservoir until it is exhausted. Then, the liquid level drops, and the float valve opens the second conduit for replenishing the reservoir with liquid from the second container. A crossover valve may be used so that the float valve controls flow from either container connected to the second conduit.

Continuous chemical feeder and method of use thereof

A method of monitoring and controlling hardness in an industrial water system is described and claimed. The method requires the use of a Compound that develops a separate detectable fluorescent signal in the presence of soluble hardness. A fluorometer is used to detect this separate detectable fluorescent signal of the Compound. The separate detectable fluorescent signal is used to ascertain the amount of soluble hardness present in the industrial water system.

Fluorometric monitoring and control of soluble hardness of water used in industrial water systems

A method of monitoring and controlling hardness in an industrial water system is described and claimed. The method requires the use of a Compound that develops a separate detectable fluorescent signal in the presence of soluble hardness. A fluorometer is used to detect this separate detectable fluorescent signal of the Compound. The separate detectable fluorescent signal is used to ascertain the amount of soluble hardness present in the industrial water system. Another aspect of the instant claimed invention is the ability to determine whether the soluble hardness is calcium or magnesium based.

Growing community of inventors

Bolingbrook, IL, United States of America

David A Grattan