Utc Fuel Cells, LLC

Audi Ag

United Technologies Corporation

Carrier Corporation

Otis Elevator Company

International Fuel Cells, LLC

Other

Ballard Power Systems Corporation

Utc Power Corporation

David A Condit

Richard D Breault

Ned Emidio Cipollini

Michael L Perry

Sergei F Burlatsky

Thomas D Jarvi

Thomas Harry Madden

James A Leistra

Margaret M Steinbugler

Jared B Hertzberg

Sathya Motupally

Albert P Grasso

Leslie L Van Dine

Wayde R Schmidt

Lei Chen

Francis S Galasso

Lesia V Protsailo

Michael E Gorman

Deliang Yang

Mallika Gummalla

Timothy W Patterson

Warren R Clough

H Harvey Michels

Daniel J Budnik

Carl Anthony Reiser

Mark R Jaworowski

Xia Tang

Michael Winter

Harry E Eaton

Charles Winston

Richard D Veltri

Timothy N Obee

John J Brennan

Lowell E Paige

Thomas J Garosshen

Gennady Resnick

Sunita Satyapal

Willard H Sutton

William A Faris

Richard R Grzybowski

Harold T Couch

Emily A Dykeman

Antonio Rinaldi

John Attanasio

Christopher M Pater

Emily A Ballinger

A membrane electrode assembly includes an anode, a cathode, a membrane disposed between the anode and the cathode, a catalyzed layer in at least one position selected from the group consisting of between the cathode and the membrane and between the anode and the membrane, and an edge seal positioned along an edge of the membrane electrode assembly, wherein the membrane and the catalyzed layer extends into the edge seal.

MEA seal structure containing catalyzed layer

A membrane electrode assembly is provided which includes an anode; a cathode; a membrane between the anode and the cathode; and a protective layer between the membrane and at least one electrode of the anode and the cathode, the protective layer having a layer of ionomer material containing a catalyst, the layer having a porosity of between 0 and 10%, an ionomer content of between 50 and 80% vol., a catalyst content of between 10 and 50% vol., and an electrical connectivity between catalyst particles of between 35 and 75%. A configuration using a precipitation layer to prevent migration of catalyst ions is also provided.

Protective and precipitation layers for PEM fuel cell

A membrane electrode assembly includes an anode including a hydrogen oxidation catalyst; a cathode; a membrane disposed between the anode and the cathode; and a peroxide decomposition catalyst positioned in at least one position selected from the group consisting of a layer between the anode and the membrane and a layer between the cathode and the membrane wherein the peroxide decomposition catalyst has selectivity when exposed to hydrogen peroxide toward reactions which form benign products from the hydrogen peroxide. The peroxide decomposition catalyst can also be positioned within the membrane. Also disclosed is a power-generating fuel cell system including such a membrane electrode assembly, and a process for operating such a fuel cell system. The assembly components contain ionomer material which can be perfluorinated or non-perfluorinated, high temperature, hydrocarbon, and the like.

Membrane electrode assemblies with hydrogen peroxide decomposition catalyst

A membrane electrode assembly includes an anode; a cathode; a membrane disposed between the anode and the cathode; and an extended catalyzed layer between the membrane and at least one electrode of the anode and the cathode. The extended catalyzed layer includes catalyst particles embedded in membrane material and preferably includes a first plurality of particles which are electrically connected to the at least one electrode. The extended catalyzed layer may further preferably have a second plurality of particles which are electrically disconnected from the at least one electrode.

Extended electrodes for PEM fuel cell applications

A cell stack assembly () coolant system comprises a coolant exhaust conduit () in fluid communication with a coolant exhaust manifold () and a coolant pump (). A coolant inlet conduit () enables transportation of the coolant to the coolant inlet manifold. The coolant system further includes a bypass conduit () in fluid communication with the coolant exhaust manifold and the coolant inlet manifold, while a bleed valve () is in fluid communication with the coolant exhaust conduit and a source of gas. Operation of the bleed valve enables venting of the coolant from the coolant channels, and through a shut down conduit (). An increased pressure differential between the coolant and reactant gases forces water out of the pores in the electrode substrates (). An ejector () prevents air form inhibiting the pump. Pulsed air is blown () through the coolant channels to remove more water.

Method and apparatus for the operation of a cell stack assembly during subfreezing temperatures

A membrane electrode assembly includes an anode including a hydrogen oxidation catalyst; a cathode; a membrane disposed between the anode and the cathode; and a peroxide decomposition catalyst positioned in at least one position selected from the group consisting of the anode, the cathode, a layer between the anode and the membrane and a layer between the cathode and the membrane wherein the peroxide decomposition catalyst has selectivity when exposed to hydrogen peroxide toward reactions which form benign products from the hydrogen peroxide. The peroxide decomposition catalyst can also be positioned within the membrane. Also disclosed is a power-generating fuel cell system including such a membrane electrode assembly, and a process for operating such a fuel cell system.

A direct antifreeze cooled fuel cell is disclosed for producing electrical energy from reducing and process oxidant fluid streams that includes an electrolyte secured between an anode catalyst and a cathode catalyst; a porous anode substrate secured in direct fluid communication with and supporting the anode catalyst; a porous wetproofed cathode substrate secured in direct fluid communication with and supporting the cathode catalyst; a porous water transport or cooler plate secured in direct fluid communication with the porous cathode substrate; and, a direct antifreeze solution passing through the porous water transport plate. A preferred direct antifreeze solution passing through the porous water transport plate remains essentially within the water transport plate and does not poison the catalysts.

Direct antifreeze cooled fuel cell

A fuel cell system is shut down by disconnecting the primary load, shutting off the air flow, and controlling the fuel flow into the system (including shutting off the fuel flow) and the gas flow out of the system in a manner that results in the fuel cell gases coming to equilibrium across the cells at a gas composition of at least 0.0001% hydrogen (by volume), and preferably between 1.0% and less than 4.0% hydrogen, by volume, with a balance of nitrogen and possibly other gases inert and harmless to the fuel cell, all the oxygen having been consumed by reacting with the hydrogen within the cell. That gas composition is maintained within the cells throughout shut-down, such as by adding hydrogen to replace any that is consumed by reaction with air leaking into the cells during the period of shut-down. This shut-down procedure causes virtually no cell performance losses.

Shut-down procedure for hydrogen-air fuel cell system

A coolant system is proposed for addressing temperature concerns during start-up and shut-down of a cell stack assembly. The coolant system comprises a coolant exhaust conduit in fluid communication with a coolant exhaust manifold and a coolant pump, the coolant exhaust conduit enabling transportation of exhausted coolant away from a coolant exhaust manifold. A coolant return conduit is provided to be in fluid communication with a coolant inlet manifold and a coolant pump, the coolant return conduit enabling transportation of the coolant to the coolant inlet manifold. The coolant system further includes a bypass conduit in fluid communication with the coolant exhaust conduit and the coolant return conduit, while a bleed valve is in fluid communication with the coolant exhaust conduit and a gaseous stream. Operation of the bleed valve enables venting of the coolant from the coolant channels, and through said bypass conduit.

The invention is a freeze tolerant fuel cell power plant that includes at least one fuel cell and a water transport plate secured within the fuel cell having a coolant inlet and a coolant outlet that direct a water coolant through the plate. A suction water displacement system includes a freeze tolerant accumulator secured to the coolant inlet and a vacuum separator secured to the coolant outlet having a suction generating eductor secured to the separator. Control valves and a coolant pump selectively direct either the water coolant, heated, or unheated water immiscible fluid to cycle from the accumulator, through the coolant inlet, water transport plate, coolant outlet, vacuum separator and back to the accumulator in order to permit operation and storage of the plant in sub-freezing ambient temperatures.

Freeze tolerant fuel cell power plant

The invention is a freeze tolerant fuel cell power plant that includes at least one fuel cell; a coolant loop having a coolant circulating device that directs a water coolant through a water transport plate within the fuel cell; and a water displacement system having a freeze tolerant accumulator that contains a water immiscible fluid and water coolant. The water displacement system also includes a water immiscible fluid pump, heater and displacement valves for directing the water immiscible fluid to flow from the accumulator into the coolant loop; for directing the water coolant in the coolant loop to flow into the accumulator; and, for directing heated water immiscible fluid to flow from the accumulator into the coolant loop and back into the accumulator.

A fuel cell with a direct antifreeze impermeable cooler plate is disclosed for producing electrical energy from reducing fluid and process oxidant reactant streams. The fuel cell includes an electrolyte secured between an anode catalyst and a cathode catalyst; an anode flow field secured adjacent the anode catalyst for directing the reducing fluid to pass adjacent the anode catalyst; a cathode flow field secured adjacent the cathode catalyst for directing the process oxidant stream to pass adjacent the cathode catalyst; a direct antifreeze impermeable cooler plate secured in heat exchange relationship with the cathode flow field; and a direct antifreeze solution passing through the cooler plate for controlling temperature within the fuel cell. The direct antifreeze solution is an organic antifreeze solution that is not volatile at cell operating temperatures. A preferred direct antifreeze solution is an alkanetriol selected from the group consisting of glycerol, butanetriol, and pentanetriol having favorable low volatility and high surface tension characteristics. The direct antifreeze impermeable cooler plate may be constructed of any material that is impermeable to liquid and compatible with a fuel cell operating environment such as plated metals, or in a preferred embodiment, the cooler plate may be a fine pore commercial graphite material.

Fuel cell with a direct antifreeze impermeable cooler plate

A direct antifreeze cooled fuel cell power plant is disclosed. The plant includes at least one fuel cell a thermal management system that directs flow of a cooling fluid for controlling heat within the plant, including a direct antifreeze solution passing through the water transport plate. The plant also integrates the direct antifreeze solution with a direct mass and heat transfer device, a water treatment system, and a steam injection system so that the direct antifreeze solution minimizes problems related to operation of the plant in sub-freezing conditions. A preferred antifreeze solution is an alkanetriol selected from the group consisting of glycerol, butanetriol, and pentanetriol. The direct antifreeze solutions minimize movement of the antifreeze as a vapor out of a water transport plate into contact with cathode or anode catalysts, and also minimize direct antifreeze solution loss from other power plant systems.

Direct antifreeze cooled fuel cell power plant

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Avon, CT, United States of America

David A Condit