Lignol Innovations Ltd.

Fibria Innovations Inc.

Suzano Canada Inc.

Darwin Ortiz

Alex Berlin

Edward Kendall Pye

Mikhail Yurevich Balakshin

Humbert Thomas Dellicolli

Chadrick Adam Nathaniel Jordan Grunert

Vera Maximenko Gutman

Chadrick Adam Grunert

Raymond Ma

Mikhail Y Balakshin

The present invention provides derivatives of native lignin having a certain aliphatic hydroxyl content. Surprisingly, it has been found that consistent and predictable antioxidant activity may be provided by selecting for derivatives of native lignin having a certain aliphatic hydroxyl content.

Derivatives of native lignin

The present invention provides derivatives of native lignin having certain aliphatic hydroxyl content. Surprisingly, it has been found that consistent and predictable antioxidant activity may be provided by selecting for derivatives of native lignin having certain aliphatic hydroxyl content.

Derivatives of native lignin from annual fibre feedstocks

The present invention relates to softwood lignin derivatives having an aliphatic hydroxyl content of from about 2.5 mmol/g to about 7 mmol/g lignin, and the preparation method thereof. The preparation method comprises: pulping a fibrous biomass, heating the biomass, maintaining the elevated temperature for 1 minute or longer, separating the cellulosic pulp to form a lignin-rich material, and recovering derivatives of native lignin. The lignin derivatives have a desired antioxidant activity characterized by radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the softwood lignin derivative. Another aspect of the invention relates to a use of the softwood lignin derivatives comprising incorporating the softwood lignin derivatives into polymer compositions.

Method of producing a softwood lignin derivative

The present invention relates to softwood lignin derivatives having an aliphatic hydroxyl content of from about 2.5 mmol/g to about 7 mmol/g lignin, and the preparation method thereof. The lignin derivatives have a desired antioxidant activity characterized by radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the softwood lignin derivative. Another aspect of the invention relates to a use of the softwood lignin derivatives comprising incorporating the softwood lignin derivatives into polymer compositions.

Derivatives of native lignin from softwood feedstocks

The present disclosure relates to processes for recovery of derivatives of native lignin from lignocellulosic feedstocks wherein the derivatives have a certain aliphatic hydroxyl content. Surprisingly, it has been found that stable and predictable antioxidant activity is provided by selecting for derivatives of native lignin having a certain aliphatic hydroxyl content.

Processes for recovery of derivatives of native lignin

At least one embodiment of the present inventions relates to a method of producing a softwood lignin derivative softwood lignin derivative. The method includes steps of pulping a fibrous biomass, heating the biomass, maintaining the elevated temperature for 1 minute or longer, separating the cellulosic pulp to form a lignin rich material, and recovering derivatives of native lignin wherein the derivatives have an aliphatic hydroxyl content of from about 2.5 mmol/g to about 7 mmol/g. The derivatives can have a phenolic hydroxyl content of from about 2 mmol/g to about 8 mmol/g and a normalized RSI of 10 or greater. The method can be a kraft process or a modification thereof.

One aspect of the invention relates to lignin derivatives having an aliphatic hydroxyl content of 2.35 mmol/g lignin or less, and the preparation method thereof. The lignin derivatives have a desired antioxidant activity characterized by the normalized radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the lignin derivative. Another aspect of the invention relates to a use of the lignin derivatives comprising incorporating the lignin derivatives into polymer compositions.

One aspect of the invention relates to softwood lignin derivatives having an aliphatic hydroxyl content of from about 2.5 mmol/g to about 7 mmol/g lignin, and the preparation method thereof. The lignin derivatives have a desired antioxidant activity characterized by radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the softwood lignin derivative. Another aspect of the invention relates to a use of the softwood lignin derivatives comprising incorporating the softwood lignin derivatives into polymer compositions.

One aspect of the invention relates to annual fiber lignin derivatives having an aliphatic hydroxyl content of about 3.75 mmol/g lignin or less, or about 1.5 mmol/g lignin or more, and the preparation method thereof. The lignin derivatives have a desired antioxidant activity characterized by radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the annual fiber lignin derivative. Another aspect of the invention relates to a use of the annual fiber lignin derivatives comprising incorporating the annual fiber lignin derivatives into polymer compositions.

One aspect of the invention relates to hardwood lignin derivatives having an aliphatic hydroxyl content of from about 5.2 mmol/g to about 7 mmol/g lignin, and the preparation method thereof. The lignin derivatives have a desired antioxidant activity characterized by the normalized radical scavenging index (RSI). Another aspect of the invention relates to compositions comprising the hardwood lignin derivative. Another aspect of the invention relates to a use of the hardwood lignin derivatives comprising incorporating the hardwood lignin derivatives into polymer compositions.

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Delta, Canada

Darwin Ortiz