Chevron U.s.a. Inc.

Chevon U.s.a. Inc.

Darrell Lynn Gallup

Sujin Yean

Dennis John O'Rear

Lyman Arnold Young

Russell Evan Cooper

Brian Christopher Llewellyn

Matthew Bernard Zielinski

Mark Anthony Emanuele

Dennis John O'rear

Christopher Henry Spurrell

Methods and systems relate to the in-situ removal of heavy metals such as mercury, arsenic, etc., from produced fluids such as gases and crudes from a subterranean hydrocarbon-bearing formation. A sufficient amount of a fixing agent is injected into formation with a dilution fluid. The fixing agent reacts with the heavy metals forming precipitate, or is extracted heavy metals into the dilution fluid as soluble complexes. In one embodiment, the heavy metal precipitates remain in the formation. After the recovery of the produced fluid, the dilution fluid containing the heavy metal complexes is separated from the produced fluid, generating a treated produced fluid having a reduced concentration of heavy metals. In one embodiment, the dilution fluid is water, and the wastewater containing the heavy metal complexes after recovery can be recycled by injection into a reservoir.

In-situ method and system for removing heavy metals from produced fluids

Trace amount levels of non-volatile mercury in crude oil are reduced by contacting the crude oil with a water stream containing at least a monatomic water-soluble sulfur species such as sulfides and hydrosulfides. The non-volatile mercury is extracted into the water phase forming a mercury rich wastewater, yielding a treated crude oil having at less than 50% of the original non-volatile mercury level. The wastewater can disposed or recycled by injection into a reservoir. In one embodiment, the water stream consists essentially of produced water.

Process, method, and system for removing mercury from fluids

Trace levels of mercury in a natural gas are reduced by scrubbing the natural gas in an absorber with an aqueous solution comprising a water-soluble sulfur compound. The water-soluble sulfur compound reacts with a least a portion of the mercury in the natural gas to produce a treated natural gas with a reduced concentration of mercury, and a mercury containing sulfur-depleted solution which can be disposed by injection into a (depleted) underground formation. The produced water extracted with the natural gas from the underground formation can be recycled for use as the scrubbing solution. In one embodiment, a fresh source of water-soluble sulfur compound as feed to the absorber can be generated on-site by reacting an elemental sulfur source with a sulfur reagent in produced water.

Trace element levels of heavy metals in crude oil are reduced by contacting the crude oil with an oxidizing agent, extracting heavy metals into a water phase for subsequent separation from the crude oil. The oxidizing agent is selected from the group of hydroperoxides, organic peroxides, inorganic peracids and salts thereof, organic peracids and salts thereof, and ozone. In one embodiment, the oxidizing agent converts heavy metals into the heavy metal cations in a water-oil emulsion, which can be subsequently separated from the crude oil, for a treated crude oil having reduced levels of heavy metals. In one embodiment, at least a complexing agent can be added to facilitate the removal by forming soluble heavy metal complexes in the water phase.

Process, method, and system for removing heavy metals from fluids

Trace element levels of heavy metals such as mercury in crude oil are reduced by contacting the crude oil with an iodine source, generating a water soluble heavy metal complex for subsequent removal from the crude oil. In one embodiment, the iodine source is generated in-situ in an oxidation-reduction reaction, by adding the crude oil to an iodine species having a charge and a reductant or an oxidant depending on the charge of the iodine species. In one embodiment with an iodine species having a positive charge and a reducing reagent, a complexing agent is also added to the crude oil to extract the heavy metal complex into the water phase to form water soluble heavy metal complexes which can be separated from the crude oil, for a treated crude oil having reduced levels of heavy metals.

Trace element levels of heavy metals such as mercury in crude oil are reduced by contacting the crude oil with an oxidant such as oxyhalites, converting elemental mercury into heavy metal cations for subsequent separation from the crude oil. In an improved method for the removal of mercury, at least a complexing agent is added to convert the heavy metal cations into soluble heavy metal complexes in a water phase, which can be separated from the crude oil, for a treated crude oil having reduced levels of heavy metals. In one embodiment, the complexing agent is selected from the group of metal halides.

Trace element levels of heavy metals in crude oil are reduced by contacting the crude oil with an oxidizing agent, converting heavy metals into heavy metal cations for subsequent separation from the crude oil. At least a complexing agent is added to convert the heavy metal cations into soluble heavy metal complexes in a water phase, which can be separated from the crude oil, for a treated crude oil having reduced levels of heavy metals. In one embodiment, the complexing agent is selected from the group of metal halides, and the oxidizing agent is selected from the group of organic peracids, inorganic peracids and salts thereof.

Trace levels of heavy metals in fluids such as crude oil are reduced by contacting the crude oil with a composition comprising a compound of Formula (I), wherein X is an anion of valency n, the number of phosphonium cations present. In one embodiment, the composition further comprises a complexing additive comprising an amine or corresponding ammonium derivative. Upon contact with the crude oil, the heavy metals form soluble complexes with the compound of Formula (I) for subsequent removal from the crude oil via phase separation.

The present invention is directed to a method and system for treating a well having a wellbore extending from a ground surface or subsea surface downhole to an oil producing formation. Oil producing formations are capable of generating formation fluids into a wellbore. Formation fluids are comprised of at least an oil fraction and an aqueous fraction. Emulsions may form during oil production, and such emulsions may be comprised of oil and water. Inhibitor compositions may be employed to break such emulsions.

Methods and systems for treating subterranean wells

A method and device for detecting mercury or other material deposits on an inner surface of an enclosed passage are provided. The device includes a detection unit that is adapted to be transported through the passage, and the detection unit includes a radiation source and an x-ray fluorescence detector. The radiation source is configured to emit a radiation emission toward the inner surface of the passage to excite a portion of the inner surface, and the x-ray fluorescence detector is configured to detect a resulting x-ray emission from the portion of the inner surface to identify a material deposit on the inner surface. The detection unit can identify material deposits at successive positions along a length of the passage and thereby generate a plurality of data points, each data point providing an indication of a material deposit existence for a corresponding position along the length of the passage.

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Meridian, ID, United States of America

Darrell Lynn Gallup