Hrl Laboratories, LLC

Darby Laplant

Brennan D Yahata

Eric C Clough

Amber Sucich

Tobias A Schaedler

John Hunter Martin

Christopher Paul Henry

Julie Miller

Christopher Stephen Roper

Jacob Michael Hundley

Zak C Eckel

Christopher B Henry

Some variations provide an aluminum (Al) alloy containing at least 0.1 at % zirconium (Zr) and/or at least 0.1 at % chromium (Cr), wherein the aluminum alloy is in the form of an additively manufactured object. Other variations provide an aluminum-containing powder comprising Al particles, Cr particles, and Zr particles, wherein at least some of the Cr particles as well as at least some of the Zr particles are physically and/or chemically assembled on surfaces of the Al particles, and wherein the aluminum-containing powder contains at least 0.1 at % Zr and at least 0.1 at % Cr. In this invention, the combination of surface functionalization and additive manufacturing has fundamentally created a new composition space of valuable aluminum alloys. The disclosed Al alloys are strong, thermally stable, and corrosion-resistant.

Aluminum-chromium-zirconium alloys

Some variations provide an additively manufactured article comprising a first region and a second region, wherein the first region is a solid region or a porous region, wherein the second region has a pore size larger than the first-region pore size, and wherein the first-region average permeability is lower than the second-region average permeability. Some variations provide a co-sintering method of making an architected material with regions having different permeabilities, in which different additive-manufacturing process parameters are applied to distinct regions of the structure. Other variations provide a wall-pinning method of making an architected material with regions having different permeabilities, in which additive-manufacturing process parameters are selected to sinter pinned feedstock powder between solid walls. Engineered structures with controlled permeability, integrated manifolds, and arbitrary geometries are disclosed, without the requirement of complex manufacturing. Many uses are described for the disclosed additively manufactured articles.

Architected materials with controlled permeability and methods for making and using the same

This invention provides methods for fabricating a hard or soft magnet with tailorable magnetic and crystallographic orientations. Methods are disclosed to individually tailor three-dimensional voxels for selected crystallographic orientations and, independently, selected magnetic orientations with location specificity throughout a magnet. Some variations provide a method of making a magnet, comprising: providing a feedstock composition containing magnetic or magnetically susceptible materials; exposing the feedstock composition to an energy source for melting, thereby generating a first melt layer; solidifying the first melt layer in the presence of an externally applied magnetic field, thereby generating a magnetic metal layer containing a plurality of individual voxels; optionally repeating to generate a plurality of solid layers; and recovering a magnet comprising the magnetic metal layer(s), wherein the externally applied magnetic field has a magnetic-field orientation that is selected to control a magnetic axis and a crystallographic texture within the magnetic metal layer(s).

Methods for tailoring magnetism, and structures obtained therefrom

Some variations provide a method of tailoring the surface of a soft magnet, comprising: depositing an austenite-phase-stabilizing donor material on one or more first surface regions of a ferromagnetic receiver material; not depositing the austenite-phase-stabilizing donor material on one or more second surface regions of the ferromagnetic receiver material; laser melting the austenite-phase-stabilizing donor material into the first surface regions; and solidifying the molten austenite-phase-stabilizing donor material within the first surface regions, thereby selectively alloying the ferromagnetic receiver material in the first surface regions. Laser ablation may be utilized instead of laser melting. The first surface regions have a significantly higher magnetic permeability, following the selective alloying of the donor material, compared to the second surface regions. Soft magnets with surface-tailored magnetic permeability are provided by this technology, which is demonstrated using several examples. One commercial application is selectively alloyed soft magnets for a rotor in an electric motor.

Methods for tailoring the magnetic permeability of soft magnets, and soft magnets obtained therefrom

Some variations provide a permanent-magnet structure comprising: a region having a plurality of magnetic domains and a region-average magnetic axis, wherein each of the magnetic domains has a domain magnetic axis that is substantially aligned with the region-average magnetic axis, and wherein the plurality of magnetic domains is characterized by an average magnetic domain size. Within the region, there is a plurality of metal-containing grains characterized by an average grain size, and each of the magnetic domains has a domain easy axis that is dictated by a crystallographic texture of the metal-containing grains. The region has a region-average easy axis based on the average value of the domain easy axis within that region. The region-average magnetic axis and the region-average easy axis form a region-average alignment angle that has a standard deviation less than 30° within the plurality of magnetic domains. Many permanent-magnet structures are disclosed herein.

Permanent magnets with tailored texture and magnetic orientation

The present disclosure provides a methodology in which nanoparticle-coated microparticles are rapidly quality-checked for verification of surface functionalization of a commercial quantities of hierarchical powder. Some variations provide a method for inspecting surface-functionalized microparticles, comprising: selecting samples of hierarchical powders comprising microparticles and surface-coated nanoparticles; subjecting the hierarchical powders to a sample particle-size measurement; comparing the sample particle-size measurement to a baseline measurement; and determining the relative concentration of free nanoparticles, based on particle-size distributions. If the sample particle-size measurement is statistically equivalent to the baseline measurement, that is verification of complete surface functionalization. If the sample particle-size measurement is statistically different than the baseline measurement, then the baseline measurement is subtracted from the sample particle-size measurement, to determine the content of free nanoparticles. Optionally, the surface-coated nanoparticles are removed from the sample and additional particle-size distributions measured, to determine the content of original surface-coated nanoparticles, for additional quality control.

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Santa Monica, CA, United States of America

Darby Laplant