Agfa-gevaert Ag

Danuta Eva Allen

Raimund J Faust

Silvia Lutz

A graft copolymer of recurring units of (C.sub.6 -C.sub.18)alkyl (meth)acrylate (A), N-vinylpyrrolidone (B), glycidyl (meth)acrylate (C), and glycidyl (meth)acrylate units esterified with (meth)acrylic acid (D) onto which polymeric side chains of units of N-vinylpyrrolidone, (C.sub.1 -C.sub.3)alkyl acrylate and, if appropriate, (C.sub.1 -C.sub.3)alkyl methacrylate are grafted. The polymer is suitable as a binder for colorless, negatively chargeable liquid toners, in particular in combination with graft copolymers of (C.sub.1 -C.sub.6)alkyl (meth)acrylate, (C.sub.6 -C.sub.18)alkyl (meth)acrylate and units in which chains of N-vinyl-pyrrolidone units are grafted onto one of the units mentioned, as a charge control agent. After fixing of the electrophotographically produced toner image, the toners give colorless resist masks or printing screens with a high resistance toward etching agents and solvents.

Graft copolymers and colorless, transparent electrophotographic toners

A graft copolymer of recurring units of (C.sub.6 -C.sub.18)alkyl (meth)acrylate (A), vinylpyridine (B), glycidyl (meth) acrylate (C), and glycidyl (meth) acrylate units esterified with (meth)acrylic acid (D) onto which polymeric side chains of units of vinylpyridine, (C.sub.1 -C.sub.3)alkyl acrylate, and optionally (C.sub.1 -C.sub.3)alkyl methacrylate are grafted. The polymer is suitable as a binder for colorless, positively chargeable liquid toners, in particular in combination with a copolymer of (C.sub.6 -C.sub.18)alkyl (meth) acrylate and hydroxyalkyl (meth)acrylate as charge control agents. After fixing of the electrophotographically produced toner image, the toners give colorless resist masks or printing screens with a high resistance toward etching agents and solvents.

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Wiesbaden, Germany

Danuta Eva Allen