Chevron Phillips Chemical Company LP

Chevron Chemical Company LLC

Daniel P Hagewiesche

John V Heyse

Robert A Innes

Bernard F Mulaskey

Tin-Tack Peter Cheung

David C Kramer

William James Cannella

Scott H Brown

Baiyi Zhao

Paul M Spindler

Dennis L Holtermann

Gale L Hubred

Charles R Wilson

Steven Clay Moore

Robert L Hise

Steven E Trumbull

Hong Chiu Chen

Richard M Wolpert

Randall J Harris

Paul F Bryan

Alan G Kunze

A method of extending the life of an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst, and oxidizing the catalyst prior to reaching the RDT. A method of aromatizing a hydrocarbon comprising identifying a rapid deactivation threshold (RDT) for an aromatization catalyst, and operating an aromatization reactor comprising the catalyst to extend the Time on Stream of the reactor prior to reaching the RDT. A method of extending the life of an aromatization catalyst comprising predicting a rapid deactivation threshold (RDT) for an aromatization reactor by employing the catalyst in a reactor system under an accelerated fouling condition to identify a test rapid deactivation threshold (t-RDT), predicting the RDT for the aromatization reactor based upon the t-RDT, and oxidizing the catalyst prior to the predicted RDT to extend the Time on Stream of the aromatization catalyst.

Extending the life of an aromatization catalyst

A method of extending the life of an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst, and oxidizing the catalyst prior to reaching the RDT. A method of aromatizing a hydrocarbon comprising identifying a rapid deactivation threshold (RDT) for an aromatization catalyst, and operating an aromatization reactor comprising the catalyst to extend the Time on Stream of the reactor prior to reaching the RDT. A method of characterizing an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst. A method of extending the life of an aromatization catalyst comprising predicting a rapid deactivation threshold (RDT) for an aromatization reactor by employing the catalyst in a reactor system under an accelerated fouling condition to identify a test rapid deactivation threshold (t-RDT), predicting the RDT for the aromatization reactor based upon the t-RDT, and oxidizing the catalyst prior to the predicted RDT to extend the Time on Stream of the aromatization catalyst.

Carburization and metal-dusting while hydrodealkylating a hydrodealkylatable hydrocarbon are reduced even in the substantial absence of added sulfur.

Hydrodealkylation processes

A improved hydrocarbon conversion process, comprising applying a plating, cladding, paint or other coating to at least a portion of a hydrocarbon conversion reactor system which is used to convert hydrocarbons to products in the presence of steam, said coating being effective to reduce the amount of undesirable by-products in said process; and operating the hydrocarbon conversion process at a steam to hydrocarbon ratio that is lower than the steam to hydrocarbon ratio at which said process was operated prior to applying said coating. Preferred hydrocarbon conversion process includes steam cracking of hydrocarbons to produce ethylene and dehydrogenation of ethylbenzene to styrene.

Increasing production in hydrocarbon conversion processes

A method for reducing catalyst contamination in a hydrocarbon conversion reactor system, comprising the steps of contacting at least a portion of a metal-coated hydrocarbon conversion reactor system comprising a reactive metal with a getter to produce a movable metal; and fixating the movable metal.

Method for removing reactive metal from a reactor system

Disclosed is a method for reforming hydrocarbons comprising contacting the hydrocarbons with a catalyst in a reactor system of improved resistance to carburization and metal dusting under conditions of low sulfur.

Apparatus for hydrocarbon processing

A method of removing reactive metal from a metal-coated reactor system, comprising contacting at least a portion of a metal-coated reactor system containing reactive metal with a getter to produce movable metal, and fixating the movable metal, the getter, or both. The contacting is preferably done prior to catalyst loading. A preferred coating metal comprises tin and a preferred getter comprises HCl. The invention is also a method for reducing catalyst contamination from a metal which was used to coat a reactor system. The method comprises contacting a metal-coated reactor system, with a gaseous halogen-containing compound to produce movable metal; thereafter or simultaneously, at least a portion of the movable metal is removed from the reactor system. Then a halided catalyst is loaded into the reactor system.

A process for producing a metallic protective layer whereby a metal-containing plating, cladding, paint or other coating is applied to at least a portion of a reactor system and then contacted with a gaseous stream containing hydrocarbons, such as impure hydrogen, thereby producing a continuous and adherent metallic protective layer. The gaseous stream preferably comprises hydrogen, which may be recycled. A preferred embodiment of the invention is directed to touch-up procedures where a portion of an already protected reactor system is replaced or rewelded and the protective layer is formed as the replaced portion is brought on-stream.

Using hydrocarbon streams to prepare a metallic protective layer

Low-sulfur reforming process

Carburization and metal-dusting while hydrodealkylating a hydrodealkylatable hydrocarbon are reduced even in the substantial absence of sulfur.

Growing community of inventors

Oakland, CA, United States of America

Daniel P Hagewiesche