Uop Lcc

Ensyn Renewables, Inc.

Daniel N Myers

Paolo Palmas

David Nathan Myers

Sathit Kulprathipanja

Paul Alvin Sechrist

Laura Elise Leonard

Patrick D Walker

Steven Niewiedzial

Stanley Joseph Frey

Xin X Zhu

Barry A Freel

Brian W Hedrick

Richard A Johnson, Ii

Ismail B Cetinkaya

Aziz A Sattar

Wolfgang A Spieker

Rusty M Pittman

Yunbo Liu

Sid Kulprathipanja

Mikhail Tretyak

Bryan K Glover

David A Lomas

David A Wegerer

Joseph Edward Zimmermann

Jeffrey A Sexton

Harold U Hammershaimb

Zhihao Fei

Adam J Kanyuh

Carlos A Cabrera

Lawrence A Lacijan

James W Althoff

Todd P Mitchell

Nitin Prabhakar Chitgopekar

Andrew W Broerman

Brandon Scott Carpenter

John F Hill, Jr

Michael C Newman

Agnieszka Ziolkiewicz-Dydak

Barry Freel

Pyrolysis methods and apparatuses that allow effective heat removal, for example when necessary to achieve a desired throughput or process a desired type of biomass, are disclosed. According to representative methods, the use of a quench medium (e.g., water), either as a primary or a secondary type of heat removal, allows greater control of process temperatures, particularly in the reheater where char, as a solid byproduct of pyrolysis, is combusted. Quench medium may be distributed to one or more locations within the reheater vessel, such as above and/or within a dense phase bed of fluidized particles of a solid heat carrier (e.g., sand) to better control heat removal.

Heat removal and recovery in biomass pyrolysis

Embodiments of apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material are provided herein. The apparatus comprises a reactor, a reheater for forming a fluidized bubbling bed comprising an oxygen-containing gas, inorganic heat carrier particles, and char and for burning the char into ash to form heated inorganic particles. An inorganic particle cooler is in fluid communication with the reheater. The inorganic particle cooler comprises a shell portion and a tube portion. The inorganic particle cooler is configured such that the shell portion receives a portion of the heated inorganic particles and the tube portion receives a cooling medium for indirect heat exchange with the portion of the heated inorganic particles to form partially-cooled heated inorganic particles.

Apparatuses for controlling heat for rapid thermal processing of carbonaceous material and methods for the same

A rapid thermal processing system includes an inorganic heat carrier particles reheater coupled to an inorganic particle cooler. For example. inorganic heat carrier particles may be cooled in a shell and tube inorganic particle cooler by indirect heat exchange with a cooling medium. The cooled inorganic heat carrier particles may then be supplied to a reactor to transfer heat to carbonaceous material.

A catalyst cooler for cooling regenerated catalyst in a regenerator associated with a fluid catalytic cracking unit. The catalyst cooler includes a first passage for transporting hot regenerated catalyst away from the regenerator and a second passage for returning cooled regenerated catalyst to the regenerator. The catalyst cooler also includes at least one heat exchanger. The second passage may be disposed within the first passage, or the first and second passage may each occupy a portion of a horizontal cross section of the catalyst cooler.

Catalyst cooler for regenerated catalyst

One exemplary embodiment can be a process for regenerating catalyst in a fluid catalytic cracking unit. Generally, the process includes providing a feed to a riser of a reaction vessel, and providing a stream to a distributor positioned within a void proximate to an inlet receiving unregenerated catalyst in a regenerator. The feed can include at least one of a gas oil, a vacuum gas oil, an atmospheric gas oil, a coker gas oil, a hydrotreated gas oil, a hydrocracker unconverted oil, and an atmospheric residue.

Process for regenerating catalyst in a fluid catalytic cracking unit

Char-handling processes for controlling overall heat balance, ash accumulation, and afterburn in a reheater are provided. Carbonaceous biomass feedstock is pyrolyzed using a heat transfer medium forming pyrolysis products and a spent heat transfer medium. The spent heat transfer medium is separated into segregated char and char-depleted spent heat transfer medium. The char-depleted spent heat transfer medium is introduced into a dense bed of heat transfer medium fluidized by a stream of oxygen-containing regeneration gas. All or a portion of the segregated char is combusted in the dense bed using the stream of oxygen-containing regeneration gas. A portion of the segregated char may be exported out of the pyrolysis system to control the overall heat balance and ash accumulation.

Char-handling processes in a pyrolysis system

A process for improving the yield of ethylene and propylene from a light naphtha feedstock includes obtaining light naphtha feedstock from a primary cracking zone having a cracking catalyst. The light naphtha feedstock is contacted with an olefin catalyst in an olefin producing zone to produce an ethylene- and propylene-rich stream. After reacting with the olefin catalyst, the ethylene- and propylene-rich stream is separated from the olefin catalyst from in a separator zone. At least a portion of the olefin catalyst is regenerated by combusting coke deposited on a surface of the olefin catalyst in an oxygen-containing environment, and at least a portion of the olefin catalyst is heated. These portions could be the same one or they could be different. In some embodiments, at least a portion of the olefin catalyst could be neither regenerated nor heated. The olefin catalyst is returned to the olefin producing zone.

Dual riser catalytic cracker for increased light olefin yield

Hydrocarbon feed to a catalytic reactor can be heat exchanged with flue gas from a catalyst regenerator. This innovation enables recovery of more energy from flue gas thus resulting in a lower flue gas discharge temperature. As a result, other hot hydrocarbon streams conventionally used to preheat hydrocarbon feed can now be used to generate more high pressure steam.

Process for feed preheating with flue gas cooler

The apparatus herein provide a catalyst cooler with a vent that communicates fluidizing gas to a lower chamber of a regenerator. Air that is used as fluidizing gas can then be consumed in the regenerator without promoting after burn in the upper chamber.

Apparatus for venting a catalyst cooler

A process for the production of propylene from a propane rich hydrocarbon source is presented. The process converts a propane rich stream and uses less equipment and energy for the separation and production of propylene. The process uses a non-noble metal catalyst and utilizes a continuous reactor-regeneration system to keep the process on line for longer periods between maintenance.

Propane dehydrogenation process utilizing fluidized catalyst system

The process herein provide a catalyst cooler with a vent that communicates fluidizing gas to a lower chamber of a regenerator. Air that is used as fluidizing gas can then be consumed in the regenerator without promoting after burn in the upper chamber.

Process for venting a catalyst cooler

An apparatus and process are presented for drying a catalyst in a reactor-regenerator system. The process includes a continuous operating system with catalyst circulating between a reactor and regenerator, and the catalyst is dried before returning the catalyst to the reactor. The process uses air that is split between the drying stage and the combustion stage without adding equipment outside of the regenerator, minimizing energy, capital cost, and space requirements.

For drying regenerated catalyst in route to a propane dehydrogenation reactor

Method for drying regenerated catalyst in route to a propane dehydrogenation reactor

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Arlington Heights, IL, United States of America

Daniel N Myers