USA As Represented by Secretary of the Navy

Other

Daniel Joseph Gibson

Jasbinder Singh Sanghera

Shyam S Bayya

Ishwar Dayal Aggarwal

Vinh Q Nguyen

Frederic Hau Kung

Mikhail Kotov

Leslie Brandon Shaw

Woohong Kim

L Brandon Shaw

Rafael R Gattass

Jason D Myers

Gryphon A Drake

Colin C Baker

Darryl A Boyd

Daniel L Rhonehouse

Guillermo R Villalobos

Pablo C Pureza

Robert E Miklos

Geoff Chin

Rajesh Thapa

Jesse A Frantz

Kenneth J Ewing

Jay N Vizgaitis

Dean A Scribner

Patrick R Patten

Holly S Gibson

Nia A Pollard

Frederic H Kung

A polymer comprising one or more chalcogenide elements and one or more crosslinking moieties. The crosslinking moieties may be organic, inorganic, or both. Also disclosed is the related method for making a polymer comprising purifying a chalcogenide polymer powder comprising one or more chalcogenide elements, melting the purified chalcogenide polymer powder, adding one or more crosslinking moieties to the melted chalcogenide polymer, and curing the modified chalcogenide polymer at a temperature between 150 and 200° C.

Organically modified chalcogenide polymers

A bonded optical assembly comprising infrared-transparent materials. The assembly comprises two or more infrared transparent optical elements and a polymer comprising at least one chalcogenide element and crosslinking moieties between the infrared-transparent optical elements. The crosslinking moieties may be organic, inorganic, or both.

Organically modified chalcogenide polymers for use as optical adhesive materials

This application relates generally to an optical fiber for the delivery of infrared light where the polarization state of the light entering the fiber is preserved upon exiting the fiber and the related methods for making thereof. The optical fiber has a wavelength between about 0.9 μm and 15 μm, comprises at least one infrared-transmitting glass, and has a polarization-maintaining (PM) transverse cross-sectional structure. The infrared-transmitting, polarization-maintaining (IR-PM) optical fiber has a birefringence greater than 10and has applications in dual-use technologies including laser power delivery, sensing and imaging.

Infrared-transmitting, polarization-maintaining optical fiber and method for making

A method for bonding infrared transparent materials by placing a polymer comprising at least one chalcogenide element and crosslinking moieties between infrared-transparent optical elements and applying heat, pressure, or both. The crosslinking moieties may be organic, inorganic, or both. Also disclosed is the related bonded assembly comprising infrared transparent optical elements.

The present invention provides for synthesizing high optical quality multicomponent chalcogenide glasses without refractive index perturbations due to striae, phase separation or crystal formation using a two-zone furnace and multiple fining steps. The top and bottom zones are initially heated to the same temperature, and then a temperature gradient is created between the top zone and the bottom zone. The fining and cooling phase is divided into multiple steps with multiple temperature holds.

Manufacturing process for striae-free multicomponent chalcogenide glasses via multiple fining steps

A method for making high optical quality multicomponent chalcogenide glasses without refractive index perturbations due to striae, phase separation or crystal formation using a sealed ampoule with chemical components enclosed inside, a two-zone furnace, a convection heating/mixing step, and multiple fining steps. Initially, the sealed ampoule is oriented vertically within the two-zone furnace and heated to melt the chemical components contained within, and a temperature gradient is created between the top zone and the bottom zone such that the bottom zone has a higher temperature. This temperature gradient causes convection currents within the viscous liquid until it is sufficiently mixed due to the convective flow. Then the temperature gradient is reversed such that the top zone now has a higher temperature and the convective flow ceases. The furnace temperatures are then reduced over a period of time, with holds at multiple temperatures for fining and cooling to form a solid glass.

Manufacturing process for striae-free multicomponent chalcogenide glasses via convection mixing

The present invention is generally directed to a device comprising multiple specialty glass optical fibers that combines several different mid-infrared optical signals from multiple optical fibers into one signal in a single optical fiber. In addition, the present invention provides for a method of making the device.

Fiber-based mid-IR signal combiner and method of making same

An optical fiber with multiple openings made from the steps comprising fabricating an extrusion die using at least one additive manufacturing technique such that the extrusion die has a first set of plurality of channels that combine inside the die into a second set of plurality of channels with a different set of shapes and sizes, extruding a glass through the extrusion die, forming a fiber optic preform having a plurality of longitudinal openings that run the entire length of the fiber optic preform, attaching a barrier layer to the fiber optic preform to form a series of channels to which pressure can be applied by a gas, wherein each channel has a pressure that is independently controlled, and stretching the fiber optic preform at an elevated temperature into an optical fiber with multiple openings.

Optical fibers with multiple openings from additive manufacturing

The present invention is directed to a method for making infrared transmitting graded index optical elements by selecting at least two different infrared-transmitting materials, each with a different refractive index, having similar thermo-viscous behavior; assembling the infrared-transmitting materials into a stack comprising one or more layers of each infrared-transmitting material resulting in the stack having a graded index profile; and forming the stack into a desired shape. Also disclosed is the related optical element made by this method.

Infrared (IR) transmitting graded index (GRIN) optical elements and method for making same

Systems and methods are disclosed for splicing crystal fibers to silica glass fibers. Embodiments of the present disclosure provide mechanically stable bonds with negligible optical transmission loss by splicing fibers through a thermally enhanced reaction bonding process at lower temperatures than the melting point of the crystal. In an embodiment, mixing of the materials at elevated temperatures forms a stable intermediary material which enhances strength and reduces the transmission losses.

Splicing of crystal fiber to silica fiber with reaction bonding

A method of making an optical fiber with multiple openings comprising the steps of fabricating an extrusion die using additive manufacturing such that the extrusion die has a plurality of channels that combine inside the die into another set of channels, extruding a glass, forming a fiber optic preform having a plurality of longitudinal openings that run the entire length, attaching a barrier layer for pressure application, and stretching the preform into an optical fiber with multiple openings. An extrusion die comprising an additive manufactured material, having a proximal side having openings and having a distal side having openings, wherein the openings of the proximal side are of feed channels, wherein the openings of the distal side are of forming channels, and wherein in side the body of the die, two of the feed channels combine the forming channels.

Method of making optical fibers with multiple openings

A method for making a gradient index infrared transmitting optic by thermally treating a preform, where the preform comprises two or more infrared transmitting glasses having different compositions and optical properties, where there is an interface between adjacent glasses, where during the thermal treatment one or more chemical elements from the glasses diffuses through one or more interface resulting in a diffused gradient index optical element comprising a gradient in the chemical element concentration, and where the optical element has a gradient in refractive index and dispersion. Also disclosed is the related infrared transmitting optical element made by this method.

Gradient index infrared transmitting optics and method for making same

The present invention provides a method for synthesizing high optical quality multicomponent chalcogenide glasses without refractive index perturbations due to striae, phase separation or crystal formation using a two-zone furnace and multiple fining steps. The top and bottom zones are initially heated to the same temperature, and then a temperature gradient is created between the top zone and the bottom zone. The fining and cooling phase is divided into multiple steps with multiple temperature holds.

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Cheverly, MD, United States of America

Daniel Joseph Gibson