Dow Corning Corporation

Other

Daniel F McMahon

Joan M Donatelli

Kent R Larson

Hideki Nakahara

Gnaneshwar R Baile

Peter Otto Bentz

David R Salverson

Edward Burton Scott

Jane A Crompton

Hydrosilylation reaction curable organosiloxane compositions containing a scavenger for radicals that participate in the free radical polymerization of styrene monomers, which yield upon cure a silicone elastomers having extended moldlife.

Hydrosilylation reaction curable organosilxane compositions

A stable dispersion of a finely divided solid such as a pigment in an organosiloxane composition can be prepared as a homogeneous thixotropic liquid, paste or gel by blending the solid with a finely divided, partially treated silica, a specified class of liquid diorganosiloxane/oxyalkylene copolymers and, as a diluent, at least one liquid organosiloxane oligomer having a density lower than the density of the dispersed solid. The gels and pastes convert to flowable liquids when subjected to shearing forces.

Storage stable dipsersions of finely divided solids in organosiloxane

Organosiloxane oligomers wherein at least a portion of the siloxane units contain a silicon-bonded phenyl or phenylalkyl radical are suitable diluents for organosiloxane/oxyalkylene copolymers when these copolymers are used as thixotropic agents in the crosslinking agent portion of multi-part moisture curable organosiloxane compositions.

Thixotropic organosiloxane compositions

Low concentrations of a liquid silanol terminated polydiorganosiloxane with a number average molecular weight less than about 1000 extend the working time of tin-catalyzed moisture curable organosiloxane compositions without substantially decreasing the cure rate of the composition or adversely affecting the physical properties of cured materials, particularly elastomers, prepared using these compositions.

Moisture curable organosiloxane compositions exhibiting extended

What is disclosed is a process for converting polydiorganosiloxanes to cyclopolydiorganosiloxanes with reduced cleavage of organic groups from silicon atoms. The process comprises (A) feeding a mixture of the polydiorganosiloxanes, a catalyst, and an organic solvent to a device in which water is formed as the polydiorganosiloxanes react in the presence of the catalyst and the organic solvent, the water formed being driven out of said device as a two-phase organic solvent/water azeotrope; (B) reacting the polydiorganosiloxane/catalyst/organic solvent mixture from (A), essentially free of water, to convert the polydiorganosiloxanes to the desired product cyclopolydiorganosiloxanes; and (C) recovery of the desired product cyclopolydiorganosiloxanes.

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Midland, MI, United States of America

Daniel F McMahon