3m Innovative Properties Company

Daniel E Isaacson

Matthew H Frey

Adam D Miller

Jonathan E Janoski

William Blake Kolb

Guanglei Du

Bert T Chien

A photochromic article is provided, containing a structural component, a fluid in contact with the structural component, and a polyoxometalate complex in contact with the fluid. The polyoxometalate complex includes a counter cation complexed with either a polyoxometalate anion or a polyoxometalate derivative anion. The structural component includes a porous material, a plurality of cavities, or both. The article is photochromic. A method of changing a light transmission of a photochromic article is provided, as is a method of changing a light reflectance of a photochromic article. A method of forming a photochromic article is also provided.

Photochromic articles containing a polyoxometalate and methods of making and using same

A photochromic article is provided, containing a polymer and a polyoxometalate and counter cation complex distributed in the polymer. A method of forming a photochromic film is also provided, including forming a composition containing a polymer or a precursor of the polymer and a polyoxometalate and counter cation complex and preparing a film from the composition, the film containing the polyoxometalate and counter cation complex distributed in the polymer. Further, a precursor composition is provided, including a polymer or a precursor of the polymer and a polyoxometalate anion and a counter cation.

Photochromic articles containing a polyoxometalate and methods of making same

A photochromic article is provided, containing a polymer and a polyoxometalate derivative anion and counter cation complex distributed in the polymer. A method of forming a photochromic film is also provided, including forming a composition containing a polymer or a precursor of the polymer and a polyoxometalate derivative and counter cation complex and preparing a film from the composition, the film containing the polyoxometalate derivative and counter cation complex distributed in the polymer. Further, a precursor composition is provided, including a polymer or a precursor of the polymer and a polyoxometalate derivative anion and a counter cation.

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Maplewood, MN, United States of America

Daniel E Isaacson