The Goodyear & Tire Rubber Company

Ashland Oil, Inc.

Goodyear Aerospace Corporation

Ashland, Inc.

Daniel A Chung

John P Lawrence

Laurence G Dammann

Paul E Liggett

Thomas G Rabito

Raymond Benjamin Roennau

Shirish Rasikchandra Jasani

Richard L Cline

Scott V Nolletti

This invention is a method of making a laminated untreated fiberglass reinforced polyester substrates and a cured polyureaurethane adhesive composition. The prepolymer component of the adhesive is the reaction product of a slowly reacting polyisocyanate and a polyol.

Polyureaurethane primerless adhesive

A two part structural polyurethane adhesive composition and a method of making that adhesive. The adhesive is useful for adhering unprimed fiberglass reinforced polyester substrates and combines an isocyanate terminated prepolymer, and aliphatic polyisocyanate and a curative made of polyol and diamine.

Primerless adhesive for fiberglass reinforced polyester substrates

A curative for a two part structural primerless urethane adhesive for fiberglass reinforced polyester substrates curable at 240.degree. F. (116.degree. C.).

Curative for structural urethane adhesive

A polyurethane essentially free of gel formed by reaction of a reactive hydrogen material such as the polyether glycol or polyester polyol or their mixtures, an organic polyisocyanate such as aliphatic or alicycloaliphatic ones and meta-tetramethyl xylene diamine useful for forming water dispersions, 100% solids castings or solvent casting of films or other polyurethane articles.

Meta-tetramethyl xylene diamine polyurethane compositions and process of

These low viscosity polyesters and their products, such as urethanes produced with organic polyisocyanate(s) alone or plus a reactive diluent, such as a glycol or polyester glycols are uniquely useful for coatings, liquid coatings and as an adhesive for films and rubbers. These copolyesters are highly viscous at 24.4.degree. C. but at 40.degree. to 60.degree. C. they are thin enough to be intimately mixed with reactants such as an organic polyisocyanate or epoxy resin and diluents without need to use solvents which pollute the atmosphere.

Unique low viscosity polyesters and their products

A laminated fiberglass reinforced polyester (FRP) substrate made using a primerless adhesive and the process of making the laminated FRP substrate. The primerless adhesive combines a prepolymer, an aliphatic polyisocyanate and a curative.

A primer composition for use on fiberglass reinforced polyester substrates combining an ether type low molecular weight epoxy resin, an amino functional silane and halogenated hydrocarbon solvent.

Bonding method employing primer for fiberglass reinforced polyester

There is disclosed a method for the treatment of yarn which comprises applying an aqueous emulsion of a polyester/epoxy adhesive to the yarn. The polyester/epoxy adhesive comprises a water emulsifiable polyester capped with an isocyanate group and an epoxide which is dispersed in water to fYorm an emulsion.

Aqueous polyester/epoxy emulsion treatment for yarn, method of

A method for preparing a polyurethane suitable for lining fuel tanks, said polyurethane having good, fuel resistance and improved hydrolysis resistance by using a ketimine of an aliphatic diamine as a curing agent in a three-component system composed of a prepolymer solution, a cement solution and a curing agent solution.

Reducing the speed of aliphatic diamine curing agents in polyurethane

A polyester polyurethane compound is formed by reacting trans-1,4-cyclohexanediisocyanate with a mixed polyester. The mixed polyester can be the copolymerization condensation product of an aliphatic dicarboxylic acid or an aromatic dicarboxylic acid, or a separate physical blend thereof reacted with a polyol. The polyurethane can also contain small amounts of non-extractable epoxies and carbodiimides. The urethane has very good hydrolytic stability in comparison with prior art polyurethane systems and also very good fuel resistance and anti-icing resistance. A preferred area of use is an aircraft fuel tanks and anti-icing components.

Fuel and hydrolysis resistant polyurethane

A polyurethane prepared by reacting specifically identified substituted aromatic diamines with isocyanate-terminated prepolymer. Prepolymer is prepared by reacting polyisocyanate with polymeric polyol. Diamines are required to be selected from specified substituted butylbenzoates, benzonitriles or benzoates. The diamine curative is taught to enhance the processing of the prepolymer/diamine mixture for commercial application.

Polyurethane prepared from diamine and prepolymer

Shock absorbing unit which comprises a shaped resilient polyurethane composition characterized by being able to withstand compressive cycling and particularly being characterized by retaining a high degree of rebound after a multitude of compressive cycling cycles. The unit is suitable for use in a railroad draft gear. Such polyurethane composition for said shock absorbing unit is prepared by reacting specifically selected polyols with a corresponding balance of 1,5-naphthalene diisocyanates in combination with mixtures of certain polymeric polyols with a manipulation of their molecular weights.

Polyurethane shock absorbing unit and said polyurethane

The invention relates to substituted aromatic diamines and polyurethanes cured thereby. The diamines are individually selected from 3,5-diamino-4-tert-alkylbenzoates, 3,5-diamino-4-tert-alkylbenzonitriles and alkylene bis(3-amino-4-tert-alkylbenzoate).

Aromatic diamines and polyurethanes cured thereby

A polyester urethane fuel cell having at least one layer of a reaction product of an organic polyisocyanate and a mixed polyester and a curative. In the preferred embodiment the fuel cell has a barrier layer composed of a polyester urethane formed from reacting bis(4-cyclohexyl isocyanate) with 10 to 90 mol percent of polyhexamethylene ortho phthalate and 90 to 10 mol percent of a polycaprolactane and curative. The mixed polyesters are either a blend or co-condensation product of a monomeric polyol of less than 5 carbon atoms with an aromatic dicarboxylic acid and an aliphatic dicarboxylic acid.

Growing community of inventors

North Canton, OH, United States of America

Daniel A Chung