Corning Incorporated

Corning Glass Works

Dale R Wexell

John L Stempin

James E Flannery

Ronald Leroy Stewart

Steven Bruce Dawes

Kenneth Chyung

George Edward Berkey

Gregory A Merkel

Cameron Wayne Tanner

Lin He

William H Dumbaugh, Jr

Yanxia Ann Lu

Robert D Shoup

Kathleen Ann Wexell

Elizabeth Margaret Wheeler

David C Boyd

Jaroslava M Nigrin

Louis M Holleran

Joseph F Mach

Alvin J Salkind

Ellen K Dominick

Sylvester R Sandor

M Grayson Alexander

Francis A Cantaloupe

Thomas N Gardner

A process for forming a silicon nitride-bonded silicon carbide honeycomb monolith by a) forming a plasticizable mixture which includes (1) about 60% to 85% by weight, powdered silicon carbide with a median particle size of about 10-40 micrometers; (2) about 15% to 40% by weight, powdered silicon metal with a median particle size of about 5-20 micrometers; and, (3) organic components; b) extruding the plasticizable mixture to form a green honeycomb monolith; c) drying the green honeycomb monolith; and, d) heating the honeycomb monolith to 1450&deg; C. with a hold of 1 hour in an atmosphere of argon; and, e) nitriding the honeycomb monolith between 1450&deg; C. to 1600&deg; C. for a time sufficient to obtain a silicon nitride-bonded silicon carbide body.

Method of making silicon nitride-bonded silicon carbide honeycomb filters

A filter for trapping and combusting diesel exhaust particulates and method of making the same. The filter comprises a monolithic substrate coated with a refractory oxide material which at a frequency of 2.45 GHz heats up said filter from room temperature to about 600&deg; C. in 5 minutes or less, and wherein said refractory oxide material has a loss tangent which decreases with increasing temperature such that an equilibrium in said filter temperature is reached at no greater than 1100&deg; C. The microwave-absorbing material having a composition selected from the group consisting of A,M,B,M&prime;,O,, where A and M are selected from the group consisting of Na, K, Rb, Ag, Ca, Sr, Ba, Pb, La, Pr, Nd, Bi, Ce, Th and combinations thereof; where B and M&prime; are selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Rh, Ru, Pt, Zn, Nb, Ta, Mo, W and combinations thereof; wherein, the chemical formula is electrostatically balanced; (A&prime;,R,M&Prime;,)(Z),(X),O,, where A&prime; is from Group IA metals; where R is selected from Group IIA metals; where M&Prime; is selected from the group consisting of Mn, Co, Cu, Zn, Y, lanthanides and combinations thereof; where Z is selected from the group consisting of Zr, Hf, Ti, Nb, Ta, Y, lanthanides, Sn, Fe, Co, Al, Mn, Zn, Ni, and combinations thereof; where X is selected from the group consisting of P, Si, As, Ge, B, Al, and combinations thereof.

Microwave regenerated diesel particular filter and method of making the same

A filter for trapping and combusting diesel exhaust particulates comprising a microwave-absorbing filter body formed from a ceramic material having a general formula selected from the group consisting of A,M,B,M&prime;,O,, where A and M are selected from the group consisting of Na, K, Rb, Ag, Ca, Sr, Ba, Pb, La, Pr, Nd, Bi, Ce, Th and combinations thereof; where B and M&prime; are selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Rh, Ru, Pt, Zn, Nb, Ta, Mo, W and combinations thereof; wherein, the chemical formula is electrostatically balanced; (A&prime;,R,M&Prime;,)(Z),(X),O,, where A&prime; is from Group IA metals; where R is selected from Group IIA metals; where M&Prime; is selected from the group consisting of Mn, Co, Cu, Zn, Y, lanthanides and combinations thereof; where Z is selected from the group consisting of Zr, Hf, Ti, Nb, Ta, Y, lanthanides, Sn, Fe, Co, Al, Mn, Zn, Ni, and combinations thereof; where X is selected from the group consisting of P, Si, As, Ge, B, Al, and combinations thereof; wherein, the chemical formula is electrostatically balanced.

Diesel exhaust filters

A battery construction and a method of producing the construction. The construction comprises a ceramic separator having a honeycomb structure in which cells run lengthwise of the honeycomb and are separated by porous walls, and internal positive and negative electrodes positioned in part at least within the honeycomb structure.

Method of making a honeycomb battery structure

Honeycomb battery structure

A tubular, rigid, porous, ceramic separator for a rechargeable, deep-discharge battery assembly, the separator having a porosity greater than 40%. A plurality of battery cells, each embodying such separators, are assembled with a common terminal to form the positive electrode in a motive traction battery.

Deep-discharge battery separator

A battery assembly comprising a separator, spaced metal/metal oxide electrodes and a liquid electrolyte, the improvement comprising a rigid, porous, ceramic separator that is wettable by the liquid electrolyte, that has a porosity of 40-90 volume %, an average pore size in the range of 0.1-25 microns, a thickness of 1-12 mm, and a weight loss of not more than about 5% when exposed to H.sub.2 SO.sub.4 having a specific gravity of 1.28 for 72 hours at 70.degree. C.

Method of preparing a battery separator

The invention relates to a process of eliminating high chloride-containing incinerator ash and incinerator ash-residue mixtures, without generating excessive heavy metal-containing effluents during the actual vitrification of the ash. The process involves first pretreating the incinerator ash or ash-residue mixture, if needed, whereby the resultant ash contains less than about 3% halogen by weight and less than about 3% C.. Following the pretreatment, the ash is dried and then mixed with any additives needed to make up a vitrifiable batch mixture which will, when subsequently vitrified, form a glass possessing an excellent acid durability. A durability whereby such that the weight loss of the glass in 5% HCl solution at 95.degree. C. is 2.0 mg/cm.sup.2 or less in 24 hours. This durability results in minimal or non-detectable leaching of hazardous heavy metal or non-metallic specie and is sufficient enough durability such that the vitrified glass will easily pass the EPA's test for leachability. A suitable glass meeting the requirements is comprised of, expressed in terms of weight percent, about 47-76% SiO.sub.2 ; 8-29% Al.sub.2 O.sub.3, 3.4-33.0% CaO; and optionally 0-25% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of Na.sub.2, Li.sub.2 O, and K.sub.2 O; 0-5% Fe.sub.2 O.sub.3 ; 0-18% B.sub.2 O.sub.3 ; 0-7% ZrO.sub.2 ; 0-7% TiO.sub.2 ; 0-10% MO, wherein MO is selected from the group consisting of MgO, BaO, ZnO or SrO; 0-8% of at least one member selected from the group consisting of PbO, CdO, Cr.sub.2 O.sub.3, CuO, and NiO; and 0-4% SO.sub.3 with 0-4% Cl+F as batched.

Process for vitrifying incinerator ash

This invention is directed to the production of spontaneous essentially non-crystalline opal glasses exhibiting a very dense, milky-white appearance and excellent resistance to weathering and attack by alkaline detergents consisting essentially, expressed in weight percent on the on the basis, of 1.9-3.6% K.sub.2 O, 4.2-7.3% Na.sub.2 O, 0.2-3% Li.sub.2 O, 0-1.2% MgO, 0-4.9% CaO, 0-12.5% BaO, 0-0.1% NiO, 0.4-4% ZnO, 5.3-9.6% B.sub.2 O.sub.3, 8.8-13.5% Al.sub.2 O.sub.3, 57.2-64.4% SiO.sub.2, and 1.0-2.2% F., where the sum of (MgO+CaO+BaO) is preferably in the range of 4.5-12.5%.

Phase-separated, non-crystalline opal glasses

An elongated, rigid, porous, ceramic separator for a rechargeable battery assembly, the separator having a honeycomb structure in which open cells are separated from adjacent cells by thin, porous, ceramic walls, the open cells and separating walls running lengthwise of the honeycomb, the cell walls being porous and the open cells and wall pores being adapted to be filled with an electrolyte to permit ion flow between electrodes in a battery.

Honeycomb battery separator

A battery assembly comprising a separator, spaced metal/metal oxide electrodes and a liquid electrolyte, the improvement comprising a rigid, porous, ceramic separator that is wettable by the liquid electrolyte, that has a porosity of 40-90 volume %, an average pore size in the range of 0.1-25 microns, a thickness of 1-12 mm, and a weight loss of not more than about 5% when exposed to H.sub.2 SO.sub.4 having a specific gravity of 1.28 for 72 hours at 70.degree.C.

Battery separator

Inorganic reinforcing fibers comprising hybrid BN--C protective coatings containing up to 12% by weight of hexagonal (graphitic) carbon dissolved in the BN matrix but being essentially free of undissolved pyrolytic and graphitic carbon secondary phases, and fiber-reinforced ceramic matrix composite products incorporating the protectively-coated fibers, are disclosed. The fibers resist oxidation and provide good bonding interface characteristics when disposed in ceramic encapsulating materials, such that the composite products exhibit excellent resistance to high temperature embrittlement.

B-N-C.sub.x hydrid coatings for inorganic fiber reinforcement materials

Novel oxide coatings which can be conveniently applied to reinforcing fibers such as silicon carbide fibers, and which when introduced as a fiber coating into fiber reinforced ceramic matrix composites provide composites exhibiting improved resistance to embrittlement at high temperatures, are described. Oxides effective to provide the improved composites in accordance with the invention include CeO.sub.2 and ZrO.sub.2.

Fiber reinforced ceramic matrix composites exhibiting improved

Inorganic reinforcing fibers provided with a multi-layer protective coating comprising a boron nitride sublayer and an oxide-based overcoating of alumina or synthetic mica, and fiber-reinforced ceramic matrix composite products incorporating the protectively-coated fibers, are disclosed. The fibers offer improved oxidation resistance and good compatibility with oxide-based glass and glass-ceramic composite matrix materials.

Coated inorganic fiber reinforcement materials and ceramic composites

Silicon nitride reinforcing fibers provided with a protective surface coating comprising a boron nitride base layer and, optionally, an alumina overcoating, and fiber-reinforced ceramic matrix composite products incorporating the protectively-coated fibers, are disclosed. The composites offer significantly improved high temperature strength in combination with low dielectric constant and low dielectric loss characteristics.

Growing community of inventors

Corning, NY, United States of America

Dale R Wexell