The Johns Hopkins University

US Government As Represented by the Secretary of the Army

Dajie Zhang

Konstantinos Gerasopoulos

Matthew W Logan

John M Brupbacher

Morgana M Trexler

Jennifer L Sample

Lisa A Kelly

Zachary B Zander

Michael C Brupbacher

Dennis Nagle

Brendan S DeLacy

The present invention is directed to methods for formation of refractory carbide, nitride, and boride coatings without use of a binding agent. The present invention is directed to methods of creating refractory coatings with controlled porosity. Refractory coatings can be formed from refractory metal, metal oxide, or metal/metal oxide composite refractory coating precursor of the 9 refractory metals encompassed by groups 4-6 and periods 4-6 of the periodic table; non-metallic elements (e.g. Si & B) and their oxides (i.e. SiO& BO) are also pertinent. The conversion of the refractory coating precursor to refractory carbide, nitride or boride is achieved via carburization, nitridization, or boridization in the presence of carbon-containing (e.g. CH), nitrogen containing (e.g. NH), and boron-containing (e.g. BH) gaseous species. Any known technique of applying the refractory coating precursor can be used. The porosity of resultant refractory coatings is controlled through compositional manipulation of composite refractory coating precursors.

Method for forming binder-free refractory carbide, nitride and boride coatings with a controlled porosity

Processes for preparing a niobate material are provided, in which the processes include the following steps: (i) providing a niobium-containing source; (ii) providing a transitional metal source (TMS), a post-transitional metal source (PTMS), or both; (iii) dissolving (a) the niobium-containing source, and (b) the TMS, the PTMS, or both in an aqueous medium to form an intermediate solution; (iv) forming an intermediate paste by admixing an inert support material with the intermediate solution; (v) optionally coating the intermediate paste on a support substrate; and (vi) removing the inert support material by subjecting the intermediate paste to a calcination process and providing a transition-metal-niobate (TMN) and/or a post-transition-metal-niobate (PTMN). Anodes including a TMN and/or PTMN are also provided.

Processes for making niobium-based electrode materials

Processes for preparing a niobate material include the following steps: (i) providing a niobium-containing source; (ii) providing a transitional metal source (TMS), a post-transitional metal source (PTMS), or both; (iii) dissolving (a) the niobium-containing source, and (b) the TMS, the PTMS, or both in an aqueous medium to form an intermediate solution; (iv) forming an intermediate paste by admixing an inert support material with the intermediate solution; (v) optionally coating the intermediate paste on a support substrate; and (vi) removing the inert support material by subjecting the intermediate paste to a calcination process and providing a transition-metal-niobate (TMN) and/or a post-transition-metal-niobate (PTMN). Anodes including a TMN and/or PTMN are also provided.

The present invention relates to a process for preparing high aspect ratio titanium dioxide (TiO) nanorods using a one-pot hydrothermal technique. Reaction additives of oxalic acid and sodium hydroxide (NaOH) are used to promote the conversion of titanium dioxide precursors, preferably tetraisopropoxide (TTIP), into a one-dimensional TiOmorphology.

Process for the preparation of titanium dioxide nanorods

A method includes producing an article having a substrate with a plurality of independent taggant layers that each include metal oxide nanocrystals doped with at least one Lanthanide element. Each taggant layer includes metal oxide nanocrystals doped with a different Lanthanide element than each other taggant layer.

Method of producing nanoparticle taggants for explosive precursors

An article includes a substrate with a plurality of independent taggant layers that each include metal oxide nanocrystals doped with at least one Lanthanide element. Each taggant layer includes metal oxide nanocrystals doped with a different Lanthanide element than each other taggant layer.

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Baltimore, MD, United States of America

Dajie Zhang