Commonwealth Scientific and Industrial Research Organisation

The Furukawa Battery Co., Ltd.

Daisuke Momma

Rosalie Louey

Jun Furukawa

Toshimichi Takada

Lan Trieu Lam

Nigel Peter Haigh

Yosuke Masuda

Yuichi Akasaka

Akira Dobashi

Trieu Lan Lam

Satoshi Shibata

Peter Nigel Haigh

Furukawa Jun

There is provided a method for producing a hybrid negative plate for a lead-acid storage battery which is improved in the production working efficiency and the productivity and enhances the quick charge and discharge characteristics and the discharge characteristics at a low temperature under PSOC of a lead-acid storage battery. A carbon mixture sheet produced by such a way that a carbon mixture prepared by mixing two types of carbon materials consisting of a first carbon material having electroconductivity and a second carbon material having capacitor capacitance and/or pseudocapacitor capacitance, and at least a binder, is adhered by pressure to the surface of a negative plate in a wet state, so that a hybrid negative plate is produced. The lead-acid storage battery provided with the hybrid negative plate is improved in the discharge characteristics.

Method for producing hybrid negative plate for lead-acid storage battery and lead-acid storage battery

[Problem] To provide a hybrid negative plate for a lead-acid storage battery, that inhibits decrease in hydrogen gas evolution potential and improves rapid discharge cycle characteristics in PSOC. [Means for Resolution] In a hybrid negative plate for a lead-acid storage battery, comprising a negative electrode active material-filled plate having formed on the surface thereof a coating layer of a carbon mixture comprising a carbon material for ensuring conductivity, activated carbon for ensuring capacitor capacity and/or pseudocapacitor capacity, and at least a binder, activated carbon modified with a functional group is used as the activated carbon. Preferably, activated carbon modified with an acidic surface functional group is used.

Hybrid negative plate for lead-acid storage battery and lead-acid storage battery

To provide a method for producing a lead-acid battery negative plate for use in a storage battery which provides improved deteriorated rapid discharge characteristics by preventing an interfacial separation between a negative active material-filled plate and a carbon mixture-coated layer, which is a problem in a negative plate having such a configuration that the carbon mixture coated layer is formed on the surface of the negative active material-filled plate. A coating layer of a carbon mixture is formed at least in a part of a surface of a negative active material-filled plate. The carbon mixture is prepared by mixing two kinds of carbon materials consisting of a first carbon material having conductive properties and a second carbon material having capacitive capacitance and/or pseudo capacitive capacitance and a binding agent. Subsequently, a sufficient amount of lead ions are generated enough to be moved from the negative active material-filled plate into the carbon mixture-coated layer. Thereafter, a formation treatment or an initial charge treatment is performed to precipitate lead so that the carbon mixture-coated layer and the negative plate are connected and integrated, at least in a part of a respective interfacial surface thereof, by the precipitated lead.

Process for producing negative plate for lead storage battery, and lead storage battery

Growing community of inventors

Fukushima, Japan

Daisuke Momma