Nippon Shokubai Co., Ltd.

The Procter Gamble Company

Daisuke Michitaka

Atsuro Yoneda

Brian Joseph Loughnane

Jeffrey Scott Dupont

Xiaoli Wang

Hirotaka Mizoguchi

Kenneth Nathan Price

Xiaoyan Liu

Akiko Hemmi

Mitsuaki Makino

Hikaru Takahashi

Makoto Saito

Koushik Mukherjee

Masami Hattori

Ryusuke Kanao

Tsuyoshi Nishikawa

Kenji Kuwada

Aki Tsukajima

Sachiko Nakanishi

The present invention provides a water-soluble film having high solubility in cold water and high extensibility. The present invention also provides a method for simply producing such a water-soluble film. One aspect of the present invention relates to a water-soluble film including a polyamine backbone-containing compound and a water-soluble resin. Another aspect of the present invention relates to a method for producing a water-soluble film containing a polyamine backbone-containing compound and a water-soluble resin including mixing the polyamine backbone-containing compound and the water-soluble resin.

Water-soluble film and manufacturing method therefor

The present invention provides a (poly)alkylene glycol-containing compound having higher detergency for composite stains of hydrophilic stains and hydrophobic stains than conventional (poly)alkylene glycol-containing compounds. The present invention relates to a (poly)alkylene glycol-containing compound including: a hydrophobic structural moiety (A); a (poly)alkylene glycol moiety (B); and one lactam ring-containing structural unit (C), in its structure, the hydrophobic structural moiety (A) being present in a proportion of 2.5 to 60% by mass in 100% by mass of the (poly)alkylene glycol-containing compound.

(Poly)alkylene glycol-containing compound

The present invention aims to provide a polymer capable of well dispersing hydrophobic particles. The present invention relates to a hydrophobic group-containing copolymer including a structural unit (A) derived from a hydrophobic group-containing monomer that is represented by the formula (1) and a structural unit (B) derived from a carboxylic acid-based monomer. The proportion of the structural unit (A) is from 16% by mass or more to 50% by mass or less based on 100% by mass of the structural units derived from all monomers constituting the copolymer, and the copolymer has a weight average molecular weight of 10,000 to 1,000,000. 

Hydrophobic group-containing copolymer

The present invention provides a water-soluble film having excellent solubility in cold water, high strength, and excellent hard-water resistance. The present invention also provides a method for simply producing such a water-soluble film. One aspect of the present invention relates to a water-soluble film including a polymer containing an anionic group other than a sulfonic acid (salt) group, and a water-soluble resin. The anionic group-containing polymer excludes an acrylic acid homopolymer. Another aspect of the present invention relates to a method for producing a water-soluble film that includes a polymer containing an anionic group other than a sulfonic acid (salt) group, and a water-soluble resin. The method includes mixing a polymer containing an anionic group other than a sulfonic acid (salt) group and a water-soluble resin.

Water-soluble film and method for manufacturing same

The present invention provides a carboxyl group-containing polymer and a composition containing the polymer which exhibit excellent anti-soil redeposition ability in fabric washing. The carboxyl group-containing polymer includes specific ratios of a structure unit (a) derived from an ether bond-containing monomer (A), a structure unit (b) derived from a sulfonic acid group-containing monomer (B), and a structure unit (c) derived from an acrylic acid-based monomer (C), and has a specific weight average molecular weight. The carboxyl group-containing polymer composition contains the carboxyl group-containing polymer and a specific amount of a hydrogen sulfite adduct of the acrylic acid-based monomer (C).

Carboxyl group-containing polymer and composition containing the same

Provided is a (meth)acrylic acid-based copolymer containing, as structural units, a structural unit derived from a sulfonic acid (salt) group-containing monomer and a structural unit derived from (meth)acrylic acid (salt), the copolymer being capable of expressing an excellent effect on the dispersion of hydrophobic particles. Also provided is a method of producing such (meth)acrylic acid-based copolymer. A (meth)acrylic acid-based copolymer of the present invention contains: 1 mass % to 20 mass % of a structural unit (a) derived from an ether bond-containing hydrophobic monomer (A) represented by a specific structure; 1 mass % to 50 mass % of a structural unit (b) derived from a sulfonic acid (salt) group-containing monomer (B) represented by a specific structure; and 30 mass % to 98 mass % of a structural unit (c) derived from (meth)acrylic acid (salt) (C).

(Meth)acrylic acid copolymer and method for producing same

The present invention aims to provide an amino group-containing polymer that is excellent in anti-soil redeposition property during washing and compatibility with surfactants, a method for producing thereof, and a detergent composition containing the amino group-containing polymer. The present invention is the amino group-containing polymer comprising a structural unit derived from an amino group-containing monomer having a specific structure and a structural unit derived from a nonionic monomer and/or an amino group-containing monomer other than the amino group-containing monomer described above.

Amino group-containing polymer, method for producing thereof, and detergent composition

The present invention relates to a laundry detergent or a cleaning composition, preferably a granular detergent product, comprising a carboxyl-group containing polymer, which is useful in improving whiteness and/or anti-soil redeposition. Processes for making and methods of using the laundry detergent or cleaning composition are also encompassed by the present invention.

Laundry detergents and cleaning compositions comprising carboxyl group-containing polymers

A composition is provided that contains an intermediate for a water-soluble monomer, wherein this intermediate is suitable for producing a water-soluble polyalkylene glycol-type monomer that has a polymerizable terminal double bond, and suitable for the production of water-soluble polymer, and moreover allows the high-yield production of water-soluble polymer. A process of producing this composition and a water-soluble monomer-containing composition obtained therefrom are also provided. A water-soluble monomer is also provided that can be used as a starting material for a water-soluble polymer that even at high hardnesses exhibits an excellent capacity to capture metal ions such as the calcium ion and magnesium ion, an excellent anti-gelation performance, an excellent anti-soil redeposition performance, a better anti-dye transfer performance than in the past, and also an excellent compatibility with surfactants. A production process is also provided that can produce such a water-soluble monomer at higher yields and higher selectivities (higher purities) than in the past. A composition containing an intermediate for a water-soluble monomer, that contains a compound (A) having a specified structure and that contains a specified amount of a compound (B) having a specified structure. Also, a water-soluble monomer having a specified structure is provided.

Composition containing intermediate for water-soluble monomer and process for production thereof, composition containing water-soluble monomer, intermediate for water-soluble monomer, and water-soluble monomer and process for production thereof

The present invention has an object to provide a polyalkylene glycol-based polymer having high anti-soil redeposition ability in washing treatment and having high compatibility with surfactants. The polyalkylene glycol-based polymer includes: a structure unit (a) derived from a polyalkylene glycol-based monomer (A) of a specific structure, and a structure unit (b) derived from a carboxyl group-containing monomer (B) at specific ratios.

Polyalkylene glycol-based polymer and process for producing the same

The present invention has an object to provide an amphoteric polymer having high anti-soil redeposition ability and solubility with surfactants, and a process for producing the same. The amphoteric polymer includes: a structure unit (a) derived from a cationic group-containing monomer (A); and a structure unit (b) derived from a carboxyl group-containing monomer (B). The structure unit (a) is present at a level of 1 to 99% by mass based on 100% by mass of all structure units derived from all monomers in the amphoteric polymer, and the structure unit (b) is present at a level of 1 to 99% by mass based on 100% by mass of all the structure units derived from all the monomers in the amphoteric polymer.

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Osaka, Japan

Daisuke Michitaka