Nippon Shokubai Co., Ltd.

Daijo Tomihisa

Akio Naka

Hideyuki Nishibayashi

Toshiaki Kuriyama

Tadahiro Yoneda

Tomiyasu Ueta

Yoshitomo Nakata

Nobuyuki Harada

Masaya Yoshida

Tetsuya Yamamoto

Yuuji Shimasaki

Shigefumi Kuramoto

Satoshi Ishida

Ichiro Namura

Yukiko Hori

The present invention provides: a vinylpyrrolidone polymer which exhibits good heat resistance and storage stability; a composition containing the vinylpyrrolidone polymer; a stabilization process for the vinylpyrrolidone polymer, and a preservation process for a vinylpyrrolidone polymer by which: even when the vinylpyrrolidone polymer is preserved for a long time or at high temperature, the physical properties such as molecular weight (K value) of the vinylpyrrolidone polymer can be prevented from changing, therefore the vinylpyrrolidone polymer can stably be preserved. To enhance the heat resistance and the storage stability, a vinylpyrrolidone polymer is mixed with a certain amount of antioxidant, and the oxygen concentration is suppressed to not higher than 50,000 ppm in a gas phase that contacts with the vinylpyrrolidone polymer when preserving.

Vinylpyrrolidone polymer and its stabilization and preservation processes

The present invention provides a production process for a vinylpyrrolidone polymer which process prevents the polymerization reaction of N-vinylpyrrolidone from being hindered by by-products (as formed by nucleomethylation of N-vinylpyrrolidone) or &ggr;-butyrolactone, and therefore enables to obtain a vinylpyrrolidone polymer that has a desired molecular weight and involves only a small amount of residual monomers, wherein the vinylpyrrolidone polymer can display excellent properties even if the vinylpyrrolidone polymer is, for example, crosslinked to convert it into a water-absorbent resin. The production process for a vinylpyrrolidone polymer comprises the step of polymerizing a polymerizable monomer component or components which include N-vinylpyrrolidone, wherein: the N-vinylpyrrolidone as used is N-vinylpyrrolidone having a &ggr;-butyrolactone content of not more than 500 ppm; and/or the N-vinylpyrrolidone as used is N-vinylpyrrolidone obtained without using acetylene as a raw material.

Production process for vinylpyrrolidone polymer

A surface treatment composition which can form a coating having excellent gas barrier properties, transparency and flexibility, contains at least one silane compound component selected from the group consisting of a silane compound (A) having amino groups and hydrolytic condensation groups in their molecules, a hydrolytic condensation product (B) of the silane compound (A), and a co-hydrolytic condensation product (D) of the silane compound (A) and an organometallic compound (C); a compound (E) having at least two functional groups which can react with an amino group in its molecule; and solvent (F).

Surface treatment composition and surface-treated resin molding

Compound fine particles include inorganic fine particles and an organic polymer bound to surfaces of the inorganic fine particles, and have an average particle diameter of 5 to 200 nm and a particle diameter variation coefficient of 50% or less. The compound fine particles are obtainable by hydrolyzing and condensing an organic polymer, wherein the organic polymer has, per molecule, at least one polysiloxane group containing at least one Si--OR.sup.1 group, wherein R.sup.1 denotes a hydrogen atom, an unsubstituted or substituted alkyl group, or an unsubstituted or substituted acyl group. A compound fine particle dispersion includes the compound fine particles and a dispersion medium. A composition for forming a film includes this dispersion.

Compound fine particles and composition for forming film

Growing community of inventors

Moriguchi, Japan

Daijo Tomihisa