Centre National De La Recherche Scientifique

Bostik Sa

Université De Rennes 1

Cyril Chauveau

Guillaume Michaud

Sophie Guillaume

Stephane Fouquay

Frederic Simon

Jean-François Carpentier

Stéphane Fouquay

Frédéric Simon

The invention relates to a monoethylenically unsaturated monomer of formula (I), and to the use thereof for producing a polymer. The invention also relates to the polymer obtained by polymerising said monomer, and to the use thereof in a composition for producing coatings.

Monoethylenically unsaturated monomers and uses thereof

1) Hydrocarbon-based copolymer comprising two end groups preceded by an ester function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, an exo-vinylene cyclocarbonate and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II)  in which Ris notably a methyl radical; and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol. 2) Process for preparing said copolymer, comprising: (i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then (ii) a step of heating the product formed, in the presence of a chain-transfer agent. 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.

Liquid hydrocarbon-based copolymers bearing two cyclocarbonate ester end groups

1) Hydrocarbon-based copolymer comprising two end groups preceded by an ether function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II)  2) Process for preparing said copolymer, comprising: 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.

Liquid hydrocarbon copolymers having two cyclocarbonate ether end groups

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Rennes, France

Cyril Chauveau