University of Science and Technology Beijing

Cuiwei Du

Xiaogang Li

Chaofang Dong

Xuequn Cheng

Dawei Zhang

Kui Xiao

This disclosure relates to a preparation method of a low-pH controlled-release intelligent corrosion inhibitor. The low-pH controlled-release intelligent corrosion inhibitor comprises a hydrogel with low pH responsiveness and a corrosion inhibiting substance having the capacity of corrosion inhibition. That is, a corrosion inhibiting substance is wrapped in a low-pH sensitive hydrogel. The swelling degree of the pH sensitive hydrogel may be changed according to the amounts of monomers and crosslinking agents so as to control the releasing speed of the corrosion inhibiting substance. By the soaking experiment and the measurements of electrochemical polarization curves and alternating impedance spectra, the sensitive and long-lasting features of the low-pH controlled-release intelligent corrosion inhibitor are indicated. Therefore, the advantageous effects of this disclosure lies in that: 1) the system enables the releasing speed of the corrosion inhibiting substance to be controlled by pH; 2) the system enables long-lasting effect and high corrosion inhibition efficiency of the corrosion inhibiting substance; and 3) the system has broad applicability.

Preparation method of low-pH controlled-release intelligent corrosion inhibitor

This present invention provides a method for preparing a stainless reinforcing steel bar resistant to corrosion of chloride ions, and belongs to the technical field of corrosion-resistant materials. This method particularly comprises the steps of: selecting a reinforcing steel bar blank, and performing oil removing, rust removing, water washing, and drying treatments on the surface of the reinforcing steel bar blank to be treated, or directly performing sand blasting or shot blasting on a reinforcing steel bar blank whose surface is only slightly rusted; placing the reinforcing steel bar blank in a chromium-containing environment, and keeping at a certain temperature for a certain time such that chromium in the environment is capable of diffusing into the surface of the reinforcing steel bar blank to form a chromium-containing diffusion layer, wherein an area in the diffusion layer where the weight content of Cr exceeds 12% meets the basic component requirements for a stainless steel, and this area is the effective diffusion layer described in this invention; and performing cooling treatment on the heat diffusion treated reinforcing steel bar. In this invention, a reinforcing steel bar blank is pre-formed, a heat diffusion technique is optimized, and the corrosion resistance to chloride ions of the stainless reinforcing steel bar of this invention is superior to that of the 316L stainless reinforcing steel bar.

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Beijing, China

Cuiwei Du