Hewlett-packard Development Company, L.P.

International Business Machines Corporation

Peridot Print LLC

Cory J Ruud

Vladek P Kasperchik

Jayprakash C Bhatt

Sterling Chaffins

Larrie A Deardurff

David Michael Ingle

Vladimir Jakubek

Matthew Thornberry

David John Russell

Sundar Vasudevan

Kevin P Dekam

Heike Appelt

Konstantinos I Papathomas

Robert Maynard Japp

Tienteh Chen

Kristopher J Erickson

Mary E Austin

Natalie Harvey

Natalie Laura Harvey

Jami Ryan Barone

Anthony J Galvan

Ruhua Cai

The present disclosure describes binder agents for printing three-dimensional green body objects, which can include water, an organic co-solvent, a nonionic surfactant, a dihydrazide compound, and latex particles. The nonionic surfactant can include two hydrophilic head groups and two hydrophobic tail groups per molecule.

Binder agents for three-dimensional printing

Described herein are compositions, kits, methods, and systems for printing metal three-dimensional objects. In an example, described is a binding fluid composition for three-dimensional printing, the composition comprising: an aqueous liquid vehicle comprising at least one diol; and latex polymer particles dispersed in the aqueous liquid vehicle.

Three-dimensional printing

Described herein are compositions, methods, and systems for printing metal three-dimensional objects. In an example, described is a method of printing a three-dimensional object comprising: (i) depositing a metal powder build material, wherein the metal powder build material has an average particle size of from about 10 μm to about 250 μm; (ii) selectively applying a binder fluid on at least a portion of the metal powder build material, wherein the binder fluid comprises an aqueous liquid vehicle and latex polymer particles dispersed in the aqueous liquid vehicle; (iii) heating the selectively applied binder fluid on the metal powder build material to a temperature of from about 40° C. to about 180° C.; and (iv) repeating (i), (ii), and (iii) at least one time to form the three-dimensional object.

In an example, a composition for three-dimensional (3D) printing includes a polymer build material and a non-conductive fusing agent dispensable onto the polymer build material to form a polymer-fusing agent composite portion when heated to a sintering temperature, a conductive agent dispensable onto on the polymer build material to form a polymer-conductive agent composite portion when heated at least to the sintering temperature, the conductive agent comprising: at least one conductive particulate present in an amount of from about 10% to about 60% of a total weight of the conductive agent; at least one co-solvent present in an amount of from about 10% to about 50% of a total weight of the conductive agent; and an additive present in an amount of from about 0% to about 10% of a total weight of the conductive agent.

Described herein are compositions, methods, and systems for printing metal three-dimensional objects. In an example, described is a method of printing a three-dimensional object comprising: (i) depositing a metal powder build material, wherein the metal powder build material has an average particle size of from about 10 &#x3bc;m to about 250 &#x3bc;m; (ii) selectively applying a binder fluid on at least a portion of the metal powder build material, wherein the binder fluid comprises an aqueous liquid vehicle and latex polymer particles dispersed in the aqueous liquid vehicle; (iii) heating the selectively applied binder fluid on the metal powder build material to a temperature of from about 40&#xb0; C. to about 180&#xb0; C.; and (iv) repeating (i), (ii), and (iii) at least one time to form the three-dimensional object.

Described herein are compositions, methods, and systems for printing metal three-dimensional objects. In an example, described is a composition for three-dimensional printing comprising: a metal powder build material, wherein the metal powder build material has an average particle size of from about 10 &#x3bc;m to about 250 &#x3bc;m; and a binder fluid comprising: an aqueous liquid vehicle, and latex polymer particles dispersed in the aqueous liquid vehicle, wherein the latex polymer particles have an average particle size of from about 10 nm to about 300 nm.

The present disclosure is drawn to a dispersed magenta pigment blend, including a first pigment including Pigment Violet 19 and Pigment Red 122, or Pigment Red 282; and a second pigment including Pigment Red 150. The weight ratio of the first pigment to the second pigment can be from 50:50 to 80:20 by pigment solids content.

Magenta inks

The present disclosure is drawn to a pigment-based inkjet ink and methods. The inkjet ink includes water; from 2 wt % to 9 wt % pigment solids; from 0.05 wt % to 2 wt % of an acetylenic diol non-ionic surfactant; from 0.05 wt % to 2 wt % of a second surfactant. The second surfactant can be a polysorbate having at least 50% lipophilic oleic acid groups and having an HLB value of less than 15, or a C-Cpolyoxyethylene glycol ether having an ethylene oxide number less than 20, or a perfluoropolyether including a polyethylene glycol primary alcohol or diol. The inkjet ink also includes from 5 wt % to 50 wt % of an organic solvent system comprising triethylene glycol and a cyclic amide.

Pigment-based inkjet inks

The present disclosure is drawn to a magenta pigment blend, a magenta ink, and a method of formulation a magenta pigment blend. The magenta pigment blend can be a first pigment including a solid solution of Pigment Violet 19 and Pigment Red 122, or Pigment Red 282; and a second pigment including Pigment Red 150. The weight ratio of the first pigment to the second pigment can be from 50:50 to 80:20 by pigment solids content.

The present disclosure is drawn to inkjet inks and related methods. The inkjet ink includes water, from 5 wt % to 50 wt % of an organic solvent system, from 2 wt % to 9 wt % pigment solids, from 0.1 wt % to 3 wt % polyurethane binder, and from 0.4 wt % to 1.5 wt % of an oleyl or stearyl type polyoxyethylene glycol ether surfactant.

An inkjet ink includes a pigment incorporated in an aqueous ink vehicle. The pigment includes metal oxide and/or mixed metal oxide particles and a plurality of reacted dispersant molecules attached to the outer surfaces of the particles to form a coating on the outer surfaces. The reacted dispersant molecules are attached to the metal oxide and/or mixed metal oxide particle outer surfaces through a silanol linking group of the reacted dispersant molecules. The coating is present in an amount ranging from about 10 wt % to about 50 wt % with respect to the wt % of the metal oxide and/or mixed metal oxide particles.

Inkjet ink

An ink-jet ink includes a jettable vehicle, a plurality of pigment solids dispersed in the jettable vehicle, and a plurality of structurally related polymers dispersed in the jettable vehicle. Additionally, a system for printing images on a porous photo medium includes a jettable ink and a printhead loaded with the jettable ink.

Pigmented ink-jet inks with quality enhancing polymers

Dye-based gray ink formulations, ink-jet ink sets, and methods of making a dye-based gray ink formulation, are disclosed.

Dye-based gray ink formulations, methods of making dye-based gray ink formulations, and ink-jet ink sets

A composite color includes a first colored ink and a second colored ink. The first colored ink exhibits a color that is different from that exhibited by the second colored ink. The first colored ink includes pigment particles either formulated at a basic pH so that a surface of the pigment particles carries a net negative charge or formulated at an acidic pH so that a surface of the pigment particles carries a net positive charge; and the second colored ink includes pigment particles either formulated at an acidic pH so that a surface of each of the pigment particles carries a net positive charge or formulated at a basic pH so that a surface of the pigment particles carries a net negative charge. The first colored ink and the second colored ink have opposite charges. The composite color exhibits enhanced color richness when printed on a substrate.

Composite color and method of making the same

Photoimagable polymers, as well as dielectric materials and their manufacture and use in the production of printed circuit boards and printed wiring boards are described. The polymers comprise between about 30 and about 70 parts of a polyfunctional resin and between about 70 and about 30 parts of the condensation product of an epihalohydrin and a bisphenol based on 100 parts by weight of resin. The polymer is cured by a photocationic initiator. It is characterized by a glass transition temperature of at least about 140&#xb0; C. and a flex fatigue life of at least about 10,000 cycles at a 3% strain. Optionally, less than 10 parts of a third specified epoxy resin may be added to the mixture to improve flexibility without decreasing the glass transition temperature of the polymer.

Growing community of inventors

Corvallis, OR, United States of America

Cory J Ruud