Lanxess International Sa

The University of Waterloo

Lanxess Corporation

Other

Arlanxeo Deutschland Gmbh

University of Windsor

Arlanxeo Singapore Pte. Ltd.

Lanxess Butyl Pte. Ltd.

Conrad Siegers

Lorenzo Ferrari

Dana K Adkinson

Gregory J E Davidson

Sean Malmberg

Sarah Chadder

Mario Gauthier

Tricia Breen Carmichael

Rayner Krista

Ralf-Ingo Schenkel

Natalie Suhan

Richard Samuel Steevensz

Gregory Davidson

Sarah J Chadder

Sean M Malmberg

Krista Rayner

Richard Steevensz

Gregory Je Davidson

A method of separating a polyisoolefin elastomer from non-polymeric components in an organic solvent involves ultrafiltration of a solution of the polyisoolefin elastomer and non-polymeric components in an organic solvent through a semipermeable membrane to substantially retain the polyisoolefin elastomer in a retentate and provide the non-polymeric components in a permeate. Advantageously, stabilizers for the polyisoolefin elastomer are retained in the retentate along with the polyisoolefin elastomer, permeate flux through the membrane is higher as concentration of the polyisoolefin elastomer in the solution increases up to a concentration limit, the separated polyisoolefin elastomer in the retentate has a molecular weight that can be substantially unchanged even when ultrafiltration is conducted at elevated temperature and the amount of polyisoolefin elastomer in the permeate is unmeasurable providing an oligomer-rich permeate uncontaminated by polyisoolefin elastomer. A process for curing a polyisoolefin copolymer involves reducing content of an oligomer to 900 ppm or less in a mixture of the oligomer and the polyisoolefin copolymer to produce an oligomer-depleted mixture, and adding a resin cure system to the oligomer-depleted mixture to cure the polyisoolefin copolymer.

Ultrafiltration of polyisoolefin copolymers and polyisoolefin copolymers with reduced oligomer content

The present invention relates to ionomers comprising a reaction product of the reaction between a halogenated isoolefin copolymer and at least one phosphorus based nucleophile comprising at least one pendant vinyl group. The present invention also relates to a method of preparing and curing these ionomers.

Phosphonium ionomers comprising pendant vinyl groups and processes for preparing same

The present invention provides an optically transparent peroxide cured article made from a peroxide curable butyl rubber ionomer comprising repeating units derived from the reaction product of one or more multiolefin monomers and at least one nitrogen or phosphorous based nucleophile comprising a pendant vinyl group. A process is also disclosed for making the optically transparent article.

Transparent peroxide curable butyl rubber

The present invention is directed to the functionalization of butyl rubber ionomer and optionally the grafting of polyamide to halobutyl rubber ionomers. Specifically, disclosed are methods and products resulting therefrom for creating functionalized ionomers and grafting polyamide to halobutyl ionomers via reactive extrusion. The process comprises reacting a halobutyl polymer with at least one nitrogen and/or phosphorous based nucleophile to provide a halobutyl ionomer comprising conjugated diene units; grafting of an amine-reactive dienophile to said ionomer to form a functionalized ionomer; and optionally blending the resulting functionalized ionomer with polyamide.

Butyl rubber ionomer-thermoplastic graft copolymers and methods for production thereof

The present invention relates to functionalized copolymers of isoolefins and olefinic monomers, particularly to azidated copolymers. The present invention also relates to methods of preparing such azidated copolymers. The functionalized copolymers are used in various technology areas such as surface modification, adhesion, drug delivery, compatibilization of polymer blends or motor oil and fuel additives, and in providing clean cured products without contaminant leaching and/or side products.

Azidated copolymers and processes for preparing same

The present invention relates to curing of polymers, particularly to self curing of polymers. The present invention provides a process for curing of copolymers of isoolefins and olefinic monomers. The process includes the step of reacting the copolymer with an azidation reagent to form an azidated copolymer and then heating the azidated copolymer at a suitable temperature to cure the polymer.

Process for preparing cured polymers

A continuous process for the production of a dynamically vulcanized thermoplastic elastomer comprising a thermoplastic resin and a non-halogenated elastomer with a multiolefin content of greater than 3.5 mol % that has been modified in situ with a carboxylic anhydride. The process provides materials with improved elongation at break and ultimate tensile strength that can be produced economically and with reduced environmental impact.

Process for continuous production of halogen-free thermoplastic elastomer compositions

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London, Canada

Conrad Siegers