Cabot Corporation

Smiths Detection Inc.

Collin P Galloway

James A Belmont

Robert M Amici

Nanying Bian

Joseph E Johnson

Curtis E Adams

Joel M Cooke

Michael C Yu

Meng-Jiao Wang

Agathagelos Kyrlidis

Mark A Bissell

Rosa Casado-Portilla

Khaled Mahmud

Yakov E Kutsovsky

Wayne Devonport

Beth C Munoz

Gregory Mehos

Dennis M Dalton

David A Kinsman

Adam L MacKay

Lynn M Krajkowski

Kenneth J Pierce

Adam L Mackay

Eugene Wu

The present invention discloses printing plates comprising a substrate and a radiation-absorptive layer, wherein the radiation-absorptive layer comprises at least one modified pigment product. The modified pigment product comprises a pigment having attached at least one organic group and at least one amphiphilic counterion. Methods of imaging printing plates are also disclosed.

Printing plates comprising modified pigment products

Various modified pigment products are described which are preferably capable of being dispersed in a variety of materials such as coatings, inks, toners, films, plastics, polymers, elastomers, and the like. The modified pigments are pigments having attached groups, such as polymeric groups, onto the pigment by means other than adsorption. A modified pigment product is described comprising a pigment having attached at least one group comprising the formula:&#x2014;X-[NIon]Rwherein X comprises an aromatic group or an alkyl group, NIon comprises at least one type of non-ionic group, R represents hydrogen or comprises an aromatic group or an alkyl group, and p represents an integer of from 1 to 500. Modified pigment products are also described comprising a pigment having attached at least one alkylene oxide group or at least one polymeric group. In addition, other types of modified pigment products are described as well as their incorporation into inks, coatings, toners, films, plastics, polymers, elastomers, and the like. Methods of making the modified pigment products are also described.

Modified pigments having improved dispersion properties

A sensor or a sensor array connected to an electrical measuring apparatus is disclosed. In one embodiment, at least one sensor contains a layer of conductive modified particles which forms an electrical pathway or electrical circuit between two electrodes which are connected to an electrical measuring apparatus. In another embodiment, the first sensor contains at least one region of a nonconducting material and also a region that contains one or more modified particles. The modified particles are preferably conductive. An electrical path exists though the regions of the nonconducting material and the region containing the modified particles. The modified particles are conductive and more preferably are pigment particles such as modified carbon black, wherein the modified particles have attached at least one organic group. Alternatively, or in addition, the modified particle can be an aggregate having a carbon phase and a silicon-containing species phase and/or a metal-containing species phase wherein the aggregate optionally has attached at least one organic group. A sensor array for detecting an analyte in a fluid is also disclosed wherein each sensor emits a different response signature to an analyte wherein at least one of the sensors contains at least the modified particles as described above. Also, the present invention relates to a method for detecting the presence of an analyte in a fluid. The method involves contacting one or more sensors as described above with the analyte to generate a response and detecting the response with a detector that is operatively associated with each sensor in order to detect the presence of an analyte. Other advantages and embodiments are further described.

Sensors with improved properties

Processes for preparing a carbon black product having an organic group attached to the carbon black. In one process at least one diazonium salt reacts with a carbon black in the absence of an externally applied electric current sufficient to reduce the diazonium salt. In another process at least one diazonium salt reacts with a carbon black in a protic reaction medium. Carbon black products which may be prepared according to process of the invention are described as well as uses of such carbon black products in plastic compositions, rubber compositions, paper compositions, and textile compositions.

Reaction of carbon black with diazonium salts, resultant carbon black products and their uses

Various modified pigment products are described which are preferably capable of being dispersed in a variety of materials such as coatings, inks, toners, films, plastics, polymers, elastomers, and the like. The modified pigments are pigments having attached groups, such as polymeric groups, onto the pigment by means other than adsorption. A modified pigment product is described comprising a pigment having attached at least one group comprising the formula:&#x2014;X&#x2014;[NIon]Rwherein X comprises an aromatic group or an alkyl group, NIon comprises at least one type of non-ionic group, R represents hydrogen or comprises an aromatic group or an alkyl group, and p represents an integer of from 1 to 500. Modified pigment products are also described comprising a pigment having attached at least one alkylene oxide group or at least one polymeric group. In addition, other types of modified pigment products are described as well as their incorporation into inks, coatings, toners, films, plastics, polymers, elastomers, and the like. Methods of making the modified pigment products are also described.

Modified pigments having improved dispersing properties

A gyricon display containing modified particles is disclosed. The gyricon display has an arrangement of bichromal or polychromal elements which are disposed between a first and second electrode. One of the electrodes is substantially visually transparent. The display also has means for creating a potential difference between the two electrodes. Also, each bichromal element has two hemispheres, wherein one of the hemispheres has at least a surface containing at least one modified colored pigment having attached at least one organic group and the other hemisphere has at least a surface with a different color and different electrical property. The organic group preferably includes at least one ionic, ionizable group, or both. Each bichromal or polychromal element is enclosed within a shell wherein a liquid is present between the shell and the element so that the element is free to rotate in response. Methods of making the gyricon display are also disclosed.

Gyricon displays containing modified particles

A variety of methods to prepare a polymer composition containing at least one polymer and at least one modified pigment are described. The methods, in part, involve introducing a slurry containing at least one modified pigment into an emulsion or solution polymer prior to dewatering. Other polymer systems can be used including aqueous based polymerizations and solvent-based polymerizations, which can include free radical polymerizations. Other methods involve the formation of a modified pigment in the presence of an emulsion or solution polymer and then recovering the polymer composition containing the modified pigment. Compositions containing at least one modified pigment and the emulsion or solution polymer are also described as well as uses for the polymer compositions of the present invention.

Polymers containing modified pigments and methods of preparing the same

Various modified carbon products are disclosed which can form a part of a polymeric product containing the modified carbon product and a polymer. One type of modified carbon product disclosed is a carbon product having attached at least one organic group, monomeric group, or polymeric group. Another type of modified carbon product disclosed is a carbon product having attached a group having the formula: &mdash;Ar&mdash;CO &mdash;R or &mdash;C H CO &mdash;R where R is an organic group, monomeric group, or a polymeric group. The third type of modified carbon product contains a) a carbon product having attached at least one organic group directly attached to the carbon product, b) at least one ionic group, ionizable group, or a mixture thereof attached to the organic group, and c) at least one counter-ionic group or counter-ionizable group with at least one organic group, monomeric group, or polymeric group, or mixture thereof, where the counter-ionic or counter-ionizable group is attached to the ionic and/or ionizable group. A method of improving the dispersion of carbon products in polymers is also disclosed which involves dispersing the modified carbon products described above in a polymer to form a polymeric product.

Polymeric products containing modified carbon products and methods of making and using the same

Method of attaching a group to a pigment

Various modified carbon products are disclosed which can form a part of a polymeric product containing the modified carbon product and a polymer. One type of modified carbon product disclosed is a carbon product having attached at least one organic group, monomeric group, or polymeric group. Another type of modified carbon product disclosed is a carbon product having attached a group having the formula: --Ar--CO.sub.2 --R or --(--C.sub.n H.sub.2n --)--CO.sub.2 --R, where R is an organic group, monomeric group, or a polymeric group. The third type of modified carbon product contains a) a carbon product having attached at least one organic group directly attached to the carbon product, b) at least one ionic group, ionizable group, or a mixture thereof attached to the organic group, and c) at least one counter-ionic group or counter-ionizable group with at least one organic group, monomeric group, or polymeric group, or mixture thereof, where the counter-ionic or counter-ionizable group is attached to the ionic and/or ionizable group. A method of improving the dispersion of carbon products in polymers is also disclosed which involves dispersing the modified carbon products described above in a polymer to form a polymeric product.

Polymeric products containing modified carbon products and methods of

Growing community of inventors

Nashua, NH, United States of America

Collin P Galloway