Ifp Energies Nouvelles

Total Research & Technology Feluy

Total Refining & Technology Feluy

Colin Dupont

Vincent Coupard

Nikolai Nesterenko

Sylvie Maury

Thibault Heinz

Delphine Bazer-Bachi

Joseph Lopez

Guillaume Duplan

A method for isomerising dehydration in the presence of a specific catalyst, to produce at least one alkene, carried out on a feedstock containing a non-linear primary monoalcohol, where the catalyst includes a zeolite having a series of 8MR channels and a binder having certain pore volume, which catalyst is multilobe-shaped and has characteristics including certain average mesopore volume Vm, and mesopores having a certain diameter, an average certain macropore volume VM, the macropores having a certain diameter, and certain average micropore volume V&#x3bc;, the micropores having a certain diameter, and the catalyst has a certain exposed geometric area.

Method for isomerising dehydration of a non-linear primary monoalcohol on a quadrilobed iron zeolite catalyst

Process for preparing a catalyst composition containing a modified crystalline aluminosilicate and a binder, wherein the catalyst composition comprises from 5 to 95% by weight of crystalline aluminosilicate as based on the total weight of the catalyst composition, the process being remarkable in that it comprises a step of steaming said crystalline aluminosilicate:

Catalyst composition comprising modified crystalline aluminosilicate for dehydration of alcohols

Catalyst composition comprising modified crystalline aluminosilicate for dehydration

The invention relates to a process for dehydration of a mono-alcohol, or of a mixture of at least two mono-alcohols, having at least 2 carbon atoms and at most 7 carbon atoms into olefins having the same number of carbons, wherein the process uses a catalyst composition that comprises a modified crystalline aluminosilicate has an acidity between 350 and 500 &#x3bc;mol/g that comprises, and further wherein the catalyst composition is obtained by a process comprising the steps of providing a crystalline aluminosilicate having a Si/Al framework molar ratio greater than 10; and steaming said crystalline aluminosilicate, or said shaped and/or calcined crystalline aluminosilicate at a temperature ranging from 100&#xb0; C. to 380&#xb0; C.; and under a gas phase atmosphere, without liquid, containing from 5 wt % to 100 wt % of steam; at a pressure ranging from 2 to 200 bars; at a partial pressure of HO from 2 bars to 200 bars; and said steaming being performed during at least 30 min and up to 144 h.

Process for dehydration of mono-alcohol(s) using a modified crystalline aluminosilicate

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Brussels, Belgium

Colin Dupont