E.i. Dupont De Nemours and Company

The Chemours Company Fc, LLC

Clay Woodward Jones

Robert John Cavanaugh

Theodore Arthur Treat

Richard A Morgan

David William Johnson

Robert Clayton Wheland

Jon Lee Howell

Charles Joseph Noelke

Ralph Munson Aten

Allan Harold Olson

Daniel N Levy

Jeffrey A Hrivnak

Devin Flowers

Michael Gene McClusky

Walter Thomas Krakowiak

Gregory Alan Bell

Kazuo Konabe

Ta-Wei Fu

Philippe Andre Fernand Thomas

Ronald G Egres, Jr

John F Kline, Jr

Walter Krakowiak

Theodore A Treat

Jeffrey Hirvnak

Richard Alan Morgan

Marvin Michael Martens

Gloria Jean Jones

An aqueous fluoropolymer dispersion comprising fluoropolymer particles having an average particle size of about 10 to about 400 nm. The dispersion has a solids content of at least about 35 to about 70 wt % and comprises about 0.03 wt % to about 10 wt % anionic polyelectrolyte dispersing agent based on the weight of fluoropolymer solids. The dispersion has a Gel Time of at least about 100 seconds.

Concentrated fluoropolymer dispersions stabilized with anionic polyelectrolyte dispersing agents

Amorphous hydrofluoroolefin telomers are prepared by a free-radical polymerization process conducted at high temperature and pressure in the presence of non-monomeric chain transfer agent.

Processes for preparing low molecular weight hexafluoropropylene-olefin cotelomers

Liquid hydrofluorocarbons provide low corrosivity lubrication of metallic surfaces especially at elevated temperatures.

Lubricated metal article

An aqueous fluoropolymer dispersion comprising an aqueous medium, fluoropolymer particles, and an amine oxide surfactant. Coagulated fluoropolymer resin is produced from the dispersion by adding an acidic reagent in sufficient amount to cause coagulation and separation of the coagulated fluoropolymer resin from the aqueous medium. Another particulate component such as particular polymer, filler, pigment, solid lubricant, etc., may be added to the dispersion and co-coagulated to form a mixture of coagulated fluoropolymer resin and particulate component.

Aqueous fluoropolymer dispersion stabilized with amine oxide surfactant and process for making coagulated fluoropolymer resin

A process for dispersion spinning non-melt-processible fluoropolymer fiber in which a mixture of an aqueous dispersion of non-melt-processible polytetrafluoroethylene or modified polytetrafluoroethylene fluoropolymer particles and an aqueous solution of matrix polymer is formed. The non melt-processible particles have an SSG of less than about 2.40. The aqueous dispersion contains an aliphatic alcohol ethoxylate nonionic surfactant having a 20% residuals temperature determined by thermogravimetric analysis (TGA) of less than about 290&#xb0; C. and is essentially free of surfactants containing aromatic groups. The dispersion has a fluorinated surfactant content of less than about 300 ppm. The mixture is extruded into a coagulation bath containing a concentration of ions which coagulate the matrix polymer to form an intermediate fiber structure. The intermediate fiber structure is sintered to decompose the matrix polymer and coalesce. The present invention also provides a spinning composition useful for the dispersion spinning of non-melt-processible fluoropolymer fiber.

Spinning low fluorosurfactant fluoropolymer dispersions

The present invention provides a process for making a filled fluoropolymer bearing comprising providing an aqueous fluoropolymer dispersion comprising fluoropolymer particles and anionic polyelectrolyte dispersing agent in an amount sufficient for stabilization. The dispersion contains less than about 300 ppm fluorosurfactant based on the weight of the dispersion. The dispersion is coagulated to make a mush and a bearing filler is added to the dispersion prior to or after making the mush. The mush containing bearing filler is applied onto a bearing substrate to produce a coated substrate which is sintered and formed into a bearing.

Process for forming filled bearings from fluoropolymer dispersions stabilized with anionic polyelectrolyte dispersing agents

Process for forming filled bearings from fluoropolymer dispersions stabilized with anionic polyelectrolyte dispering agents

A process is disclosed for dispersion spinning non-melt-processible fluoropolymer fiber in which a mixture of an aqueous dispersion of non-melt-processible fluoropolymer particles and an aqueous solution of a matrix polymer is formed. The non-melt-processible fluoropolymer particles have an SSG of less than about 2.40 and comprise a core of high molecular weight polytetrafluoroethylene and a shell of lower molecular weight polytetrafluoroethylene or modified polytetrafluoroethylene. The mixture is extruded into a coagulation bath containing a concentration of ions which coagulate the matrix polymer to form an intermediate fiber structure. The intermediate fiber structure is sintered to decompose the matrix polymer and coalesce the non-melt-processible fluoropolymer particles to form the fiber. The present invention also provides a spinning composition useful for the dispersion spinning of non-melt-processible fluoropolymer fiber.

Dispersion spinning core-shell fluoropolymers

A process for reducing the fluorosurfactant content of an aqueous fluoropolymer dispersion by filling a container with fluoropolymer dispersion, inserting into the container a fabric pouch containing a fluorosurfactant sorbent so that the sorbent contacts the fluorosurfactant-containing aqueous fluoropolymer dispersion in the container and retains the fluorosurfactant to reduce fluorosurfactant content of said fluorosurfactant-containing aqueous fluoropolymer dispersion, and removing the fabric pouch from the container.

Process for removing fluorosurfactant from an aqueous fluoropolymer dispersion using sorbent pouches

A process for reducing the fluorosurfactant content of an aqueous fluoropolymer dispersion by filling a shipping container with fluoropolymer dispersion and contacting the dispersion with a fluorosurfactant sorbent in the shipping container.

Removing fluorosurfactant from aqueous fluoropolymer dispersions

An aqueous dispersion of non-melt-processible fluoropolymer, process for making same and concentrated dispersion and powder obtained from the dispersion. The fluoropolymer particles of the dispersion have a standard specific gravity (SSG) of less than 2.225 and comprise a core of high molecular weight polytetrafluoroethylene and a shell of lower molecular weight polytetrafluoroethylene or modified polytetrafluoroethylene. At least about 1.5 weight % of the fluoropolymer particles comprise substantially rod-shaped particles having a length to diameter ratio greater than about 5.

High build dispersions

Growing community of inventors

Washington, WV, United States of America

Clay Woodward Jones