Societe Nationale Elf Aquitaine (production)

Societe Nationale Elf Aquitaine

Elf Aquitaine Production

Claude Blanc

Henri Paradowski

Olivier Oliveau

Georges Kvasnikoff

Jean-Yves Chenard

Guy Desgrandchamps

Jacques Batteux

Pierre Grancher

Jean Elgue

Jean-Jacques Delpuech

Daniel Morin

Chantal Pondebat

Henry Galy

Christine Mangin

Process for the purification of a glycol solution

Process for denitrogenation of a feedstock of a liquefied mixture of

Simultaneous decarbonation and gasoline stripping of hydrocarbons

Cryogenic process for desulphurization and gasoline removal of a gaseous

A process to produce sulphur from two acid gases both containing hydrogen sulphide and one of which contains ammonia, using a modified Claus technique. The acid gas containing ammonia is burnt in the presence of air under substoichiometric conditions in a first heat-reaction chamber, while the ammonia-free acid gas is burnt in a second heat-reaction chamber, forming a series with the first chamber, with the right quantity of air to provide a molar ratio of H.sub.2 S to SO.sub.2 of approximately 2/1 at the catalytic reaction stage inlet. The mixed effluents from both heat-reaction chambers may pass through a high-temperature residence chamber before being conveyed to the heat-recovery stage. Gas effluents from the heat-reaction stage contain H.sub.2 S and SO.sub.2 in the right ratio for the catalytic reaction stage, and no hydrocarbons or harmful quantities of NH.sub.3 and NO.

Apparatus for burning hydrogen sulphide

Improvement in the enrichment of a gas in hydrogen sulphide, comprising selective absorption by a liquid in a primary absorption zone, regeneration of the liquid by heating and/or stripping by an inert gas with liberation of the gases absorbed and recovery of a fraction of the liberated gases, the remainder being subjected to a second absorption in a secondary absorption zone by a new or regenerated absorbent liquid identical with that used in the primary absorption zone; in one and the same zone of operation, common to the regeneration and the secondary absorption zones, there occur simultaneously: arrival of the liquid from the first absorption, movement of the gases liberated during regeneration, flow of the liquid derived from the secondary absorption and discharge of a fraction of the liberated gases enriched in H.sub.2 S.

Enrichment in hydrogen sulphide of gases containing it

The present invention relates to a process for the selective extraction treatment of a gaseous hydrocarbon mixture containing 5 to 3000 ppm (parts per million) by volume of hydrogen sulfide and 0.3 to 3% carbon dioxide, in order to obtain a purified gas containing less than 4 ppm by volume hydrogen sulfide and less than 2% carbon dioxide. The gaseous hydrocarbon mixture is submitted to a series of counter-current washings by contact with a tertiary amine aqueous solution in an absorption zone from which is drawn a liquid effluent enriched in hydrogen sulfide.

Process for the selective extraction treatment of gaseous hydrocarbon

Process to produce sulphur from two acid gases, both containing hydrogen

The invention concerns a process for the purification of residual industrial gases containing a small quantity of H.sub.2 S, SO.sub.2, CS.sub.2, COS, or possibly sulfur vapor, as well as large amounts of H.sub.2 O, CO.sub.2 and N.sub.2 in which the residual gases are first subjected to a catalytic reduction in which all the sulfur compounds are transformed into H.sub.2 S, and thereafter washed by an aqueous amine solution before being burnt and discarded into the atmosphere, while the aqueous amine solution is regenerated by heating and the gases given off, comprising H.sub.2 S and CO.sub.2, are returned to the sulfur manufacturing plant. The process is characterized in that the temperature of the gas to be treated is permanently maintained at a level higher than the dew-point of the water contained in the gases at all points of the process, thereby insuring that substantially all H.sub.2 O contained in the residual gases is discarded into the atmosphere.

Process for the purification of residual industrial gases containing

The invention concerns a process for the purification of residual industrial gases containing a small quantity of H.sub.2 S, SO.sub.2, CS.sub.2 COS, or possibly sulfur vapor, as well as large amounts of H.sub.2 O, CO.sub.2 and N.sub.2 in which the residual gases are first subjected to a catalytic reduction in which all the sulfur compounds are transformed into H.sub.2 S, and thereafter washed by an aqueous amine solution before being burnt and discarded into the atmosphere, while the aqueous amine solution is regenerated by heating and the gases given off, comprising H.sub.2 S and CO.sub.2, are returned to the sulfur manufacturing plant. The process is characterized in that the temperature of the gas to be treated is permanently maintained at a level higher than the dew-point of the water contained in the gases at all points of the process, thereby insuring that substantially all H.sub.2 O contained in the residual gases is discarded into the atmosphere.

The present invention is related to a process for absorbing acid gases from industrial gaseous mixtures by washing under pressure with a solvent. The invention is concerned more particularly with the use of hexamethyl phosphorotriamide OP[N(CH.sub.3).sub.2 ].sub.3, pure or mixed with water, as a physical solvent of acid gases. This new physical solvent is of particular interest in the treatment of natural acid gases and refinery gases.

Physical solvent absorption of carbon dioxide and hydrogen sulphide for

H.sub.2 S is removed from gas containing CO.sub.2 by a thioether, thioamide or alkyl thiocarbonate solvent.

Selective absorption process of hydrogen sulphide and sulphur containing

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Pau, France

Claude Blanc