The Boc Group, Inc.

Clair Wheeler

Akhilesh Kapoor

Loc H Dao

Jack Appolonia

Sulfur compounds are removed from gaseous carbon dioxide by contacting the carbon dioxide with water vapor in the presence of a carbonyl sulfide hydrolysis catalyst, thereby converting carbonyl sulfide in the gas stream to hydrogen sulfide, contacting the resulting gas stream with ferric oxide, thereby removing hydrogen sulfide from the gas stream as elemental sulfur, and contacting the remaining gas stream with copper oxide, zinc oxide or mixtures of these, thereby removing any remaining sulfur compounds from the gaseous carbon dioxide.

Process for the purification of carbon dioxide

The present invention provides a cryogenic freezer and method using a freezing chamber within which articles are cooled under the direct application of a cryogen, causing the cryogen to vaporize into a cryogenic vapor. The freezing chamber has inlet and outlet plenums through which articles to be frozen are passed into and from the freezing chamber, respectively. The liquid cryogen is introduced from a make-up tank into the freezing chamber and into direct contact with the articles to be frozen. Conduits connect the inlet and outlet plenums to a blower that draws air from outside the freezing chamber and the cryogenic vapor from inside the freezing chamber to prevent air from entering the freezing chamber. The cryogenic vapor is drawn from an outlet in the freezing chamber to a recovery unit to be compressed, purified and liquefied. The resulting liquid cryogen is then fed back to the make-up tank. In order to prevent air from being processed by the recovery unit along with the cryogenic vapor, the cryogenic vapor is drawn from the freezing chamber at a level thereof that is as low as possible and such that the mass flow rate of the cryogenic vapor drawn from the freezing chamber is equal to that of the liquid cryogen upon its entry into the freezing chamber.

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Basking Ridge, NJ, United States of America

Clair Wheeler