Lg Chem, Ltd

Churl-Young Park

Nan-Young Lee

Dong-Gil Lee

Ro-Mi Lee

Hyuck-Ju Kwon

San-Ak Hwang

Yeong-Ah Choi

Dong-Ryul Im

So-young Park

Cheon-Il Park

Yong-jeon Kim

Ro-my Lee

Yi-young Choi

The present invention relates to a method for preparing a supported metallocene catalyst, and a method for preparing polyolefin using the same, in which the supported metallocene catalyst prepared from the simple process according to the method for preparing the supported metallocene catalyst of the present invention can apply to the polymerization of the polyolefin that is polymerized at low pressure or high pressure; the molecular weight distribution of polyolefin prepared can be easily controlled; and there are effects such that its catalyst activity is significantly higher than that of the existed supported metallocene catalyst, and the molecular weight distribution can be easily controlled.

Method for preparing supported metallocene catalyst and method for preparing polyolefin using the same

Disclosed is a metallocene catalyst composition for polyolefin polymerization. The metallocene catalyst composition is in a non-supported, heterogeneous form where an ansa-metallocene is bound to a cocatalyst without a support. Also, a method for preparing the catalyst composition, and a method for preparing polyolefin using the catalyst are disclosed. Capable of readily controlling microstructures of olefin polymers in addition to having high catalytic activity, the non-supported heterogeneous catalyst composition can be applied to the preparation of polyolefin polymers at high yield without altering preexisting processes.

Non-supported heterogeneous polyolefin polymerization catalyst composition and method for preparing same

This disclosure relates to an ansa-metallocene compound of a novel structure that can provide various selectivities and activities to polyolefin copolymers, a preparation method thereof, and a method for preparing polyolefins using the ansa-metallocene compound.

Ansa-metallocene compound and method for preparing supported catalyst using the same

Provided are a supported metallocene catalyst, a method for preparing the same and a method for preparing polyolefin using the same. The supported metallocene catalyst prepared by incorporating a metallocene compound having a ligand substituted with alkoxide or aryloxide into a conventional supported metallocene catalyst and incorporating a borate compound as a second co-catalyst exhibits considerably superior catalyst activity and easily controls molecular weight distribution, as compared to the conventional metallocene-supported catalyst.

Supported metallocene catalyst, method for preparing the same and method for preparing polyolefin using the same

Provided is a polypropylene resin composition having excellent impact resistance, impact strength at low temperature and transparence comprising ethylene-alpha olefin copolymer (c) to a polypropylene resin composition in which the ratio of viscosity is regulated by adjusting molecular weight of propylene-alpha olefin random copolymer (a) and propylene-alpha olefin elastic copolymer (b), thereby regulating impact resistance and flexural modulus of the polypropylene resin composition and improving transparence; therefore, applying as various products including cold-storage containers for freezer and refrigerator, food packaging container, extrusion blow molding material, film, sheet and bottle cap, etc.

Polypropylene resin composition with good transparence and good impact strength

The present invention relates to a catalyst system for olefin polymerization and a method for olefin polymerization using the same. More particularly, the present invention relates to a Ziegler-Natta catalyst system for olefin polymerization comprising a transition metal compound as a main catalyst component, an organic metal compound as a cocatalyst component, and a cyclic organosilane compound, trioxasilocane as an external electron donor, and a method for olefin polymerization using the same. According to the present invention, a polyolefin having improved various properties such as polymerization activity, melt-flow ability, isotacticity, molecular weight distribution and apparent density can be produced.

Catalyst system for olefin polymerization comprising trioxasilocane and method for olefin polymerization using the same

The present invention relates to a prepolymerized catalyst for olefin polymerization, a process for polymerizing an olefin by using the catalyst and a polyolefin produced by the process, in which a Ziegler-Natta catalyst is prepolymerized sequentially using &#x3b1;-olefin and vinyl saturated cyclic hydrocarbon, and then an olefin is polymerized using the prepolymerized Ziegler-Natta catalyst, thereby producing a polyolefin with high yield. Therefore, the polymerized polyolefin has high Isotactic index, bulk density, and crystallinity.

Prepolymerized catalyst for olefin polymerization, process for polymerizing olefin by using the catalyst and polyolefin produced by the process

The present invention relates to a method of polymerizing olefin containing the step of pre-polymerization. More precisely, according to the method of the present invention, the reaction speed and temperature are regulated for pre-polymerization of a catalyst and then the pre-polymerized catalyst is added for the polymerization of propylene. Propylene having an improved molecular weight distribution, hydrogen reactivity and tacticity is produced.

Growing community of inventors

Daejeon, South Korea

Churl-Young Park