Jiangsu Arit New Materials Co., Ltd.

Chengdu Arit Times New Material Co., Ltd.

Chunyang Zheng

Shanshan Qian

Jiezhong Gan

Haidong Jiang

Chunman Huang

Yangcheng Hu

Wei Li

Xu Zhao

Yi Wang

Pengcheng Yu

Mengting Li

Ying Qiu

Jinying Peng

Zhaolai Guo

Tong Lu

Xuechuan Wang

Gaoming Wang

Haojie Qu

The present invention discloses a multi-arm polycarboxylate water reducer and a preparation method thereof, the preparation method includes the following steps: making a phenolic hydroxyl containing rigid compound and p-nitrobenzonitrile subjected to a nucleophilic substitution reaction in a solvent, then subjected to addition with a sodium azide in a solvent and water mixed solution to obtain a tetrazole derivative; making an unsaturated polyether macromonomer subjected to terminal halogenation and react with the prepared tetrazole derivative to obtain a tetrazole-containing multi-arm unsaturated polyether macromonomer; and subjecting the tetrazole-containing multi-arm unsaturated polyether macromonomer, an unsaturated carboxylic acid small monomer and an unsaturated polyether macromonomer to a free radical polymerization reaction under combined action of an initiator, a reducing agent and a molecular weight regulator to obtain the multi-arm polycarboxylate water reducer integrating shrinkage reducing and antibacterial functions.

Multi-arm polycarboxylate water reducer and preparation method thereof

An early-strength polycarboxylate superplasticizer with an MOF structure and a preparation method thereof are provided. The preparation method includes the following steps: 1) performing an amidation reaction on amine-containing nanocrystalline MOFs and a halogen acyl halide organic molecule to form the halogen-containing ATRP initiator; 2) performing an ATRP reaction on the obtained ATRP initiator, an unsaturated ester monomer, an unsaturated polyether macromonomer and a transition metal complex to obtain the early-strength polycarboxylate superplasticizer with the MOF structure. The present invention regulates the number and length of branch chains and product performance by controlling the number of amine groups contained in the nanocrystalline MOFs and ATRP, and has the advantages of rapid reaction, high efficiency, non-toxic and non-pollution, and simple operation. The prepared early-strength polycarboxylate superplasticizer with the MOF structure has early-strength performance and stable product performance.

Early-strength polycarboxylate superplasticizer with MOF structure and preparation method thereof

A fluorescent polycarboxylate superplasticizer and a preparation method thereof. The preparation process of the polycarboxylate superplasticizer is as follows. Firstly, a redox radical polymerization is performed on a monomer of an unsaturated acid and a derivative thereof, and an unsaturated polyether monomer to form a polycarboxylate superplasticizer pre-product. Then, the polycarboxylate superplasticizer pre-product is subjected to an esterification reaction with an organic molecule having a fluorescent property to obtain the fluorescent polycarboxylate superplasticizer. The method effectively reduces the reaction difficulty and makes the reaction rapid and efficient. The fluorescent polycarboxylate superplasticizer is non-toxic and non-polluting, and has good controllability in the production process and less side reactions. The fluorescent polycarboxylate superplasticizer can be applied to different kinds of cement, having a high water-reducing rate, and a relatively high cost performance and competitive advantage.

Fluorescent polycarboxylate superplasticizer and preparation method thereof

The present invention discloses a preparation method of a polycarboxylate superplasticizer with carbon dioxide, comprising the following steps: (1) preparing a polycarboxylate superplasticizer prepolymer: performing an oxidation-reduction radical polymerization of an unsaturated macromonomer, an unsaturated phenol derivative, a reducing agent, an initiator and a chain transfer agent with different proportions under a nitrogen atmosphere to obtain a novel polycarboxylate superplasticizer prepolymer with different molecular weight; adjusting the pH by adding an alkali; (2) preparing a polycarboxylate superplasticizer: performing a Koble-Schmitt reaction between the polycarboxylate superplasticizer prepolymer and a carbon dioxide for a certain time to obtain the polycarboxylate superplasticizer. The polycarboxylate superplasticizer prepared by the method of the present invention retains the advantages of the existing water-reducing admixture of the polyether monomer compounds, and the production process is simple, safe, controllable, less side effect and has a better cost effective and competitive advantage.

Preparation method of polycarboxylate superplasticizer with carbon dioxide

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Nanjing, China

Chunyang Zheng