Xerox Corporation

Chunliang Lu

Yu Qi

Chieh-Min Cheng

Peter Van Nguyen

Judith M Vandewinckel

John L Pawlak

Shigeng Li

Christopher M Wolfe

Eliud Robles-Flores

John J Ianni

Mark Mercandetti

Yanjia Zuo

Fan Shi

Linda S Schriever

Jaclyn Janis

Valerie Kuykendall

John Ianni

Fluorescent magenta latexes are provided which may comprise water and fluorescent agent-incorporated resin particles, the particles comprising a resin, Solvent Red 49 as a red fluorescent agent, and Solvent Yellow 98 as a yellow fluorescent agent, wherein the fluorescent magenta latex has a weight ratio of the Solvent Red 49 to the Solvent Yellow 98 in a range of from 3:1 to 10:1. Fluorescent magenta toners and methods of making and using the fluorescent magenta toners are also provided.

Fluorescent magenta latex with enhanced brightness and toners made therefrom

Fluorescent orange latexes are provided which comprise water and fluorescent agent-incorporated resin particles, the particles comprising a resin, Solvent Red 49 as a red fluorescent agent, and Solvent Yellow 98 as a yellow fluorescent agent, wherein the fluorescent orange latex has a weight ratio of the Solvent Yellow 98 to the Solvent Red 49 in a range of from 20:1 to 0.5:1. Fluorescent orange toners and methods of making and using the fluorescent orange toners are also provided.

Fluorescent orange latex with enhanced brightness and toners made therefrom

A method for improving z-axis strength of a 3D printed object is disclosed. For example, the method includes printing a three-dimensional (3D) object with a polymer and magnetic particles, heating the 3D object to a temperature at approximately a melting temperature of the polymer, and applying a magnetic field to the 3D object to locally move the magnetic particles in the polymer to generate heat and fuse the polymer around the magnetic particles to improve a z-axis strength of the 3D object.

Utilization of magnetic particles to improve z-axis strength of 3D printed objects

Methods for forming latexes are provided. In embodiments, such a method comprises adding a first portion of a monomer emulsion comprising water, a monomer, an acidic monomer, a multifunctional monomer, and a first reactive surfactant to a reactive surfactant solution comprising water and a second reactive surfactant to form a reaction mixture, wherein the reactive surfactant solution does not comprise monomers other than the second reactive surfactant; adding a first portion of an initiator solution to the reaction mixture so that monomers undergo polymerization reactions to form resin seeds in the reaction mixture; adding a second portion of the monomer emulsion to the reaction mixture comprising the resin seeds; and adding a second portion of the initiator solution to the reaction mixture to form a latex comprising resin particles.

Seeded emulsion polymerization process for latexes and aqueous inkjet ink compositions made therefrom

Fluorescent latexes are provided. In embodiments, a fluorescent latex comprises water and fluorescent agent-incorporated resin particles, the particles comprising a resin and a F&#xf6;rster Resonance Energy Transfer (FRET) pair comprising a fluorescent brightener having a fluorescence emission spectrum and a fluorescent dye having an absorption spectrum that overlaps with the fluorescence emission spectrum of the fluorescent brightener, wherein the fluorescent latex exhibits FRET under illumination with ultraviolet (UV) light. Fluorescent toners made from the fluorescent latexes are provided. Methods of making and using the fluorescent toners are also provided.

Fluorescent latexes with enhanced brightness

Fluorescent green toners are provided. In embodiments, a fluorescent green toner comprises fluorescent agent-incorporated resin particles comprising a resin, a fluorescence brightener, and a yellow fluorescent agent having an absorption spectrum that overlaps with a fluorescence emission spectrum of the fluorescence brightener; and a cyan colorant; blue dye-incorporated resin particles comprising the resin and a blue dye; or both. The fluorescent green toner has a weight ratio of the yellow fluorescent agent to the cyan colorant and, if present, the blue dye, in a range of from 100:1 to 0.2:1, and the fluorescent green toner exhibits F&#xf6;rster Resonance Energy Transfer (FRET) under illumination with UV light. Methods of making and using the fluorescent green toners are also provided.

Fluorescent green toners with enhanced brightness

Methods of making fluorescent pink toners are provided which comprise forming one or more fluorescent latexes which comprise a red fluorescent agent, a yellow fluorescent agent, a first type of amorphous resin, and a second type of amorphous resin, wherein the first and second types of amorphous resins are present at a ratio in a range of from 2:3 to 3:2; forming a mixture comprising the one or more fluorescent latexes; one or more emulsions which comprise a crystalline resin, the first type of amorphous resin, the second type of amorphous resin; and optionally, a wax dispersion; aggregating the mixture to form particles of a predetermined size; forming a shell over the particles of the predetermined size to form core-shell particles; and coalescing the core-shell particles to form a fluorescent pink toner. Fluorescent pink toners and methods of using such toners are also provided.

Fluorescent pink toners and related methods

Methods of making fluorescent metallic toners are provided which comprise forming one or more fluorescent latexes which comprise a fluorescent agent, a first type of amorphous resin, and a second type of amorphous resin, wherein the first and second types of amorphous resins are present at a ratio in a range of from 2:3 to 3:2; forming a mixture comprising the one or more fluorescent latexes; a dispersion comprising aluminum flakes and a surfactant; one or more emulsions which comprise a crystalline resin, the first type of amorphous resin, the second type of amorphous resin; and optionally, a wax dispersion; aggregating the mixture to form particles of a predetermined size; forming a shell over the particles of the predetermined size to form core-shell particles; and coalescing the core-shell particles to form a fluorescent metallic toner. Fluorescent metallic toners and methods of using such toners are also provided.

Fluorescent metallic toners and related methods

Methods of making a fluorescent white toner are provided. In embodiments, such a method comprises forming one or more fluorescent latexes which comprise a fluorescent agent, a first type of amorphous resin, and a second type of amorphous resin, wherein the first and second types of amorphous resins are present at a ratio in a range of from 2:3 to 3:2; forming a mixture comprising the one or more fluorescent latexes; a dispersion comprising a white colorant and a surfactant; one or more emulsions which comprise a crystalline resin, the first type of amorphous resin, the second type of amorphous resin; and optionally, a wax dispersion; aggregating the mixture to form particles of a predetermined size; forming a shell over the particles of the predetermined size to form core-shell particles; and coalescing the core-shell particles to form a fluorescent white toner. The fluorescent white toners and methods of using such toners are also provided.

Fluorescent white toners and related methods

A toner process comprising (a) providing at least one amphiphilic block copolymer prepared by surfactant-free emulsion polymerization comprising: dissolving a hydrophilic monomer in water; adding a hydrophobic monomer; adding a feed initiator to produce a colloidal dispersion of amphiphilic block copolymer; and optionally, discharging the amphiphilic block copolymer; (b) contacting one or more of a latex polymer, a wax; and a colorant with the colloidal dispersion of amphiphilic block copolymer to form a blend; or contacting the discharged amphiphilic block copolymer with one or more of a latex polymer, a wax dispersion, and a colorant dispersion, and forming a further dispersion; (c) heating the blend or further dispersion at a temperature below the glass transition temperature of the latex polymer to form aggregated toner particles; (d) adding a coalescing agent to the toner particles thereby coalescing the toner particles; and (e) recovering the toner particles.

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Webster, NY, United States of America

Chunliang Lu