3m Innovative Properties Company

Chunjie Zhang

Thomas P Klun

Richard John Pokorny

Gregg A Ambur

Benjamin R Coonce

Douglas Scott Dunn

Benjamin G Sonnek

Henry A Kostalik, Iv

Christopher S DeGraw

Jung-Sheng Wu

John R Jacobson

Timothy L Wong

Jo Anne Etter

Xuan Jiang

Hongying Jiang

Naiyong Jing

Laurent Froissard

Ta-Hua Yu

Kevin M Casey

Joseph S Warner

Daniel J Richter

Christopher S Degraw

Henry A Iv Kostalik

An optical assembly () including an encapsulated multilayer optical film (). Methods of making and using such optical assemblies also are disclosed.

Optical assembly with encapsulated multilayer optical film and methods of making same

A method of making a shaped abrasion-resistant multilayer optical film includes providing a curable composition comprising, based on the total weight of components a) to d) components: a) 87 to 96 weight percent of urethane (meth)acrylate compound having an average (meth)acrylate functionality of 2 to 4.8; b) 2 to 12.5 weight percent of (meth)acrylate monomer having a (meth)acrylate functionality of 1 to 2, wherein the (meth)acrylate monomer does not comprise a urethane (meth)acrylate compound; optionally c) 0.5 to 2 weight percent of silicone (meth)acrylate; and d) optional effective amount of photoinitiator. The curable composition is coated onto an MOF. Optionally, the curable composition to is at least partially dried. Next, the curable composition or the at least partially dried curable composition is at least partially cured to provide an abrasion-resistant multilayer optical film. Lastly, the abrasion-resistant multilayer optical film is thermoformed using a female mold having a mold surface. At least a portion of the mold surface has a radius of curvature of 58 to 76 mm and a maximum depth of 13 to 20 mm.

Thermoformed abrasion-resistant multilayer optical film and method of making the same

An optical assembly including an optical element insert molded directly onto an optical stack is provided. The optical stack includes an optical film and may include a liner with the optical film being disposed between the optical element and the liner. The liner, if included, is removable from the optical film without substantial damage to the optical film. An outermost layer of the optical film may be diffusion bonded to a major surface of the optical element. The optical film includes a protective coating having an average thickness of no more than 30 micrometers. The protective coating includes an at least partially cured composition. The composition includes 70 to 96 weight percent of urethane (meth)acrylate compound having an average (meth)acrylate functionality of 2 to 9.5, and 2 to 20 weight percent of (meth)acrylate monomer having a (meth)acrylate functionality of 1 to 2.

Optical assembly with protective coating

An optical assembly including an optical element insert molded directly onto an optical stack is provided. The optical stack includes an optical film and may include a liner with the optical film being disposed between the optical element and the liner. The liner, if included, is removable from the optical film without substantial damage to the optical film. An outermost layer of the optical film may be diffusion bonded to a major surface of the optical element.

Optical assembly

A curable composition comprises: a) 91 to 98.2 weight percent of: (i) at least one polymerizable compound containing at least one carbamylene group; or (ii) at least one polyurethane precursor system; and b) 0.2 to 9 weight percent of alpha alumina particles having a particle size distribution with a Dv50 of from 0.1 to 1 micron, wherein the weight percentages of a) and b) are based upon the total amount of a) and b). Cured compositions and their use in thermoforming are also disclosed.

Compositions including alpha-alumina particles and methods of their use

The present disclosure provides a multilayer article. The multilayer article includes a) a microfiltration membrane substrate, the microfiltration membrane substrate having a first major surface; and b) a first layer having a first major surface and a second major surface disposed opposite the first major surface. The first major surface of the first layer is directly attached to the first major surface of the microfiltration membrane substrate. The first layer includes a first polymeric binder and a plurality of acid-sintered interconnected first silica nanoparticles arranged to form a continuous three-dimensional porous network. The multilayer article further includes c) a second layer attached to the second major surface of the first layer. The second layer includes i) a metal coating or ii) a composite coating comprising a second polymeric binder and at least one of metal nanoparticles or metal nanowires.

Multilayer articles including coatings containing metal on microfiltration membrane substrates

A method of making an infrared-reflecting optically transparent assembly comprises: coating a curable composition onto a major surface of an optically transparent thermoplastic polymer film; at least partially curing the curable composition, which may be optionally at least partially dried, to provide a thermoformable composite film; and laminating the thermoformable composite film to an infrared-reflecting multilayer optical film to provide the infrared-reflecting optically transparent assembly. The curable composition comprises urethane (meth)acrylate compound, (meth)acrylate monomer, and silicone (meth)acrylate. The infrared-reflecting optically transparent assembly and methods of including it in an infrared-reflecting lens assembly are also disclosed.

Infrared-reflecting optically transparent assembly and method of making the same

The present disclosure provides a multilayer article. The multilayer article includes a) a microfiltration membrane substrate; b) a first layer directly attached to the first major surface of the microfiltration membrane substrate; and c) a second layer directly attached to the first layer. The first layer includes a first polymeric binder and acid-sintered interconnected first silica nanoparticles arranged to form a continuous three-dimensional porous network. The second layer includes acid-sintered interconnected second silica nanoparticles arranged to form a continuous three-dimensional porous network. The present disclosure also provides a method for forming a multilayer article. The method includes (a) saturating a microfiltration membrane substrate with a liquid; (b) applying a first aqueous coating formulation to at least a portion of a first major surface of the microfiltration membrane substrate to form a coated substrate; (c) sintering the coated substrate, thereby forming a first layer; (d) applying a second aqueous coating formulation to the first major surface of the first layer to form a twice-coated substrate; and (e) sintering the twice-coated substrate.

Multilayer articles including coatings on microfiltration membrane substrates and methods of making same

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Shoreview, MN, United States of America

Chunjie Zhang