Korea Institute of Science and Technology

Other

Goldstar, Co., Ltd.

Korea Greencross Corporation

Chung Y Kim

Hyun Nam Cho

Dong Young Kim

Jai Kyeong Kim

Young Chul Kim

Hee-Woo Rhee

Inseok Hwang

Hoi Wan Yoo

Hyung Joon Kim

Jae-Min Hong

Young Chun Kim

Sang Shik Park

Jae-Woong Yu

Kyung Sik Min

Hyo Sang Lee

Diacetylene-based polymer containing light emitting group and electroluminescent device using the same

The present invention relates to a fluorene-based alternating polymer having the following formula (I) to be used as light emitting materials of electroluminescent elements, and further relates to electroluminescent elements having an anode/luminescent layer/cathode structure, in which the fluorene-based alternating polymer is used as light emitting materials of the luminescent layer, or having a transporting and/or reflection layer added thereto, if necessary. ##STR1## wherein R, R', X, Ar and n are defined as above.

Fluorene-based alternating polymers containing acetylene group and

The present invention relates to a fluorene-based alternating copolymer to be used as light emitting materials of electroluminescent elements having the following formula (I), and further relates to electroluminescent elements having an anode/luminescent layer/cathode structure, in which the fluorene-based alternating copolymer used as light emitting materials of the luminescent layer, or having a transporting and/or reflection layer added thereto, if necessary, is ##STR1## where R, R', X, Ar and n are defined in the text.

Fluorene-based alternating copolymers for electroluminescence element

Polypyrrole represented as the following structural formula II: ##STR1## wherein A.sup.- = ##STR2## which is synthesized by a method comprising the step of polymerizing pyrrole monomer in an aqueous solution containing dodecylbenzene sulfonic acid as a dopant, in the presence of an oxidant, resulting in polypyrrole which is easily dissolved in organic solvents.

Soluble, electroconductive polypyrrole and method for preparing the same

A fabrication method for a liquid crystal alignment layer which has an excellent liquid crystal orientation efficiency and stability, and which can be mass-produced includes coating a thermoplastic polymer film on a transparent electrode to have a thickness of not less than 500.perp., fabricating a temporary cell with a structure of transparent electrode (ITO glass) / polymer film / liquid crystal / polymer film / transparent electrode (ITO glass) by attaching two transparent electrodes having polymer films coated thereon and infusing liquid crystal, fabricating a stack with a structure of transparent electrode (ITO glass)/polymer film /liquid crystal by contacting liquid crystal on the polymer film, heating the temporary cell or the stack at lower than phase separation temperature of a blend of liquid crystal and the polymer film, while applying a magnetic field exceeding 0.2 tesla, and cooling the temporary cell or the stack in the magnetic field at a cooling rate of not more than 100.degree. C. per minute.

Fabrication method for liquid crystal alignment layer by magnetic field

A method for preparing polyester by use of a catalyst. The method comprises the steps of: esterifying either a terephthalic acid, a dicarboxylic acid containing terephthalic acid or derivatives thereof with either ethylene glycol or a glycol containing ethylene glycol, or derivatives thereof to produce an esterification product containing either bis(.beta.-hydroxyethyl) terephthalate, its low molecular weight polymer, or a combination of .beta.-hydroxyethyl terephthalate and its low molecular weight polymer; and continuously polycondensing the obtained esterification product to prepare a polyester, wherein in the said polycondensing step, a composite polymerization catalyst dissolved in an ethylene glycol or an ethylene glycol-containing solution, consisting of a compound of antimony, a compound of titanium, and a compound of tin is used. The method can considerably reduce both the esterification time and the polycondensation time and provides a good color, reduced content of diethylene glycol and reduced concentration of terminal carboxyl groups in the prepared polyesters.

Method for the preparation of polyester by use of composite catalyst

Asialoglycoprotein - conjugated medicinal agent

A high molecular humidity sensor in which polypyrrole being of conductive high molecule is electrochemically polymerized and then reduced whereby ionic conductive property is given go that humidity sensibility becomes excellent. The sensor is a structure in which polypyrrole doped with dodecylsulfate anion DS.sup.- is stuck in film form on the surface of a fine electrode, and cations Na.sup.+, K.sup.+ are permeated to said polypyrrole whereby salt is formed and humidity sensibility is exhibited in the region of 10.sup.4 -10.sup.6 .OMEGA., and humidity sensing speed becomes within several tens of seconds to several minutes.

High molecular humidity sensor and manufacturing method thereof by

A process for forming polyesters that comprises the steps of esterifying a terephthalic acid and an ethylene glycol to produce an esterification product containing a bis (betahydroxyethyl) terephthalate, and continuously polycondensing the obtained esterification product to form a polyester. In both the esterifying step and the polycondensing step, a reaction catalyst consisting of a compound of antimony and a compound of titanium is used. The weight ratio of the compound of antimony to the compound of titanium is 0.01 to 100. The process of the present invention can considerably reduce both the esterification time and the polycondensation time and provides good color, reduced diethylene glycol content and reduced condensation of terminal carboxyl groups in the resulting polyesters.

Process for forming polyesters

A method for forming polyesters (polyethylene terephthalate, PET) having a high degree of polymerization with improved color and lower diethylene glycol (DEG) content in a shorter period of time than in known methods. The method according to the invention comprises forming oligomers from ethylene glycol and terephthalic acid by esterification, forming prepolymers having a degree of polymerization ranging from 10 to 50 by polycondensing the resulting oligomers for an optimum time, forming polyesters by polycondensing the oligomers and the prepolymers in a weight ratio ranging from 1:0.1 to 1:90, thereby providing polyesters of improved color and low DEG content in a short time.

Method for forming polyesters

This invention relates to processes for the preparation of polybutylene terephthalate based polymer, which processes produce polymer having excellent color, a small amount of side-product and a high degree of polymerization within a short time. Complex catalyst which is employed comprises antimony compounds and titanium compounds, optionally together with phosphorous based compounds and hindered phenolic, and the catalyst decreases the phenomena that conventional catalysts of tin and titanium based compounds have of making the polymer colored by declining hydrolyzation and heat-stability. The catalyst also decreases the amount of side-product, THF sharply. As a result, improved polybutyleneterephthalate can be prepared.

Process for the preparation of polybutylene terephthalate based polymer

A high molecular humidity sensor and manufacturing method thereof in which polypyrrole being of conductive high molecule is electrochemically polymerized and then reduced whereby ionic conductive property is given go that humidity sensibility becomes excellent. The high molecular humidity sensor of the invention is characterized in that it is a structure in which polypyrrole doped with dodecylsulfate anion DS.sup.- is stuck in film form on the surface of fine electrode, and cations Na.sup.+, K.sup.+ are permeated to said polypyrrole whereby salt is formed, and humidity sensibility is exhibited in region of 10.sup.4 -10.sup.6 .OMEGA., and humidity sensing speed becomes within several tens seconds to several minutes.

There is provided a process for preparing five-membered heterocyclic polymers represented by a formula (II) which comprises electrochemically polymerizing five-membered heterocyclic monomers of formula (I) in the presence of tetrabutylammonium alkylsulfate as an electrolyte and an organic solvent, wherein formulas (I) and (II) are represented by the formulas ##STR1## and wherein, M represents nitrogen or sulfur, provided that hydrogen is deleted when M is sulfur;

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Seoul, South Korea

Chung Y Kim